CAS: 96-19-5; 1,2,3-Trichloroprop-1-Ene

该化合物是一种氯化有机化合物,其分子式为C3H3Cl3.它是化学合成中的一种多用途中间体,特别是在农用化学品,药品和特殊化学品的生产中.该化合物因其三氯化结构而具有高度的反应性,因此具有选择性功能反应的价值.由于其稳定性和溶解性,它也被用作溶剂和聚合物的应用.由于其潜在的毒性和易燃性,适当处理是必不可少的.其明确界定的化学特性和持续的纯度确保了工业过程的可靠性能.储存应处于冷,干燥和通风良好的地区,以保持稳定.

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CAS号2303-16-4 燕麦敌 | CAS号13116-53-5 1,2,2,3-四氯丙烷 | CAS号16714-68-4 五氯丙烷 | CAS号7126-16-1 1,2,3-trichloro...

合成工艺路线路线简述

  • 合成目标产物 1,2,3-Trichloropropene 主要起始原料 Propyne
  • 13116-53-5 = 96-19-5
    反应条件:1.1 Reagents: Sodium Hydroxide Catalysts: 1-Piperazineethanamine,N,N,4-Triethyl-,Compd. With (Chloromethyl)Benzene (1:1) Solvents: Water
    标题:Catalytic Action Of Polybasic Tertiary Polyamines In Dehydrochlorination Of Tetrachloropropane
    作者:Zagudullin,R. N.; Kurgaeva,S. N.
    参考文献:Khimicheskaya Promyshlennost Segodnya 日期:2004 卷标:(4) 页码:18-21]

    13116-53-5 = 96-19-5
    反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Water; 1.5 H,75 - 80 °C; 1 H,75 - 80 °C
    标题:Production Process Of 1,1,2,3-Tetrachloropropene
    参考文献:China]

    = 96-19-5 [标题:Reaction Conditions
    标题:Preparation Of 1,2,3-Trichloropropylene
    参考文献:Ussr]

    = 96-19-5 [标题:Reaction Conditions
    标题:Selective Halogenation Of 1,2-Dihalopropenes
    参考文献:United States]

    = 96-19-5 [标题:Reaction Conditions
    标题:Polyhaloalkenes
    参考文献:France]

    13116-53-5 = 96-19-5 + 78-88-6
    反应条件:1.1 Reagents: Sodium Hydroxide Catalysts: Tetrabutylammonium Chloride Solvents: Water; > 1 Min,Rt -> 80 °C; 180 Min,80 °C
    标题:Process For The Production Of Chlorinated Propenes
    参考文献:World Intellectual Property Organization]

    13116-53-5 = 96-19-5
    反应条件:1.1 Rt -> 120 °C
    标题:Process For The Production Of Chlorinated Propanes And/or Propenes
    参考文献:World Intellectual Property Organization]

    3175-26-6 = 96-19-5
    反应条件:1.1 Catalysts: Carbon,Iron Chloride (Fecl3); Rt -> 200 °C
    标题:Method For Producing 2,3,3,3-Tetrafluoropropene From 2-Fluoro-1,1,3-Trichloro-1-Propene
    参考文献:United States]

    78-88-6 = 96-19-5 [标题:Reaction Conditions
    标题:Chlorination Of 2,3-Dichloropropylene
    作者:Revyakina,N. V.; Zabrodina,T. I.; Rodova,R. M.; Evstigneev,O. V.; Levanova,I. B.; Et Al
    参考文献:Khimicheskaya Promyshlennost (Moscow 日期:1989 卷标:(6) 页码:421-3]

    13116-53-5 = 96-19-5 [标题:Reaction Conditions
    标题:Manufacture Of 1,1,2,3-Tetrachloropropene As A Starting Material For The Production Of Triallate Herbicide
    作者:Treger,Yu. A.; Sirovskii,F. S.; Berlin,E. R.; Velichko,S. M.; Zanaveskin,L. N.
    参考文献:Khimicheskaya Promyshlennost (Moscow 日期:1987 卷标:(7) 页码:393-7]

    = 96-19-5 [标题:Reaction Conditions
    标题:Studies On The Elimination Reactions Of Polyhalopropanes Under Microwave Irradiation Conditions
    作者:Li,Wenbo; Bai,Lin; Wang,Jinxian
    参考文献:Xibei Shifan Daxue Xuebao 日期:1999 卷标:35(1) 页码:94-95]

    = 96-19-5 [标题:Reaction Conditions
    标题:Study Of The Mixed Herbicide Of Diallate And Triallate. Part Ii. A New Synthesis Of 1,2,3-Trichloropropene And 1,1,2,3-Tetrachloropropene
    作者:Wang,Jinxian
    参考文献:Gansu Shida Xuebao 日期:1981 卷标:(1) 页码:20-9]

    = 96-19-5 [标题:Reaction Conditions
    标题:Elimination Reactions Of Polyhalopropanes Under Emulsion Catalytic Conditions To Give Halopropenes
    作者:Wang,Chin Hsien
    参考文献:Synthesis 日期:1982 卷标:(6) 页码:494-6]

    = 96-19-5 [标题:Reaction Conditions
    标题:Herbicidal Diallate-Triallate Mixtures. Part Ii. A New Syhthesis Of 1,2,3-Trichloropropene And 1,1,2,3-Tetrachloropropene
    作者:Wang,Jin-Xian
    参考文献:Gaodeng Xuexiao Huaxue Xuebao 日期:1981 卷标:2(1) 页码:127-30]

    = 96-19-5 [标题:Reaction Conditions
    标题:1,1,2,3-Tetrachloropropene From 1,2,3-Trichloropropane
    参考文献:United States]

    = 96-19-5 [标题:Reaction Conditions
    标题:Nitromethane As An Outer Nucleophile In Reactions Of Haloalkenes With Chlorine
    作者:Bodrikov,I. V.; Rabinovich,M. I.; Korchagina,G. A.; Smolyan,Z. S.
    参考文献:Zhurnal Organicheskoi Khimii 日期:1973 卷标:9(5)]

    = 96-19-5 [标题:Reaction Conditions
    标题:Selective Chlorination Of 2,3-Dichloropropene With Tert-Butyl Hypochlorite
    作者:Roberts,Reginald Francis Jr.
    参考文献:Industrial & Engineering Chemistry Product Research And Development 日期:1969 卷标:8(4) 页码:460-2]

    = 96-19-5 [标题:Reaction Conditions
    标题:Chlorinated Hydrocarbons And Olefins
    参考文献:Federal Republic Of Germany]

    78-88-6 = 96-19-5 + 13116-53-5
    反应条件:1.1 Reagents: Chlorine; 313 - 323 K
    标题:Liquid-Phase Chlorination Of Chloro Olefins
    作者:Levanova,S. V.; Strizhakova,Yu. A.; Sokolov,A. B.; Aseev,E. V.; Lapidus,A. L.
    参考文献:Khimicheskaya Tekhnologiya (Moscow 日期:2003 卷标:(1) 页码:11-16
📜1,2,3-Trichlor-2-Brom-Propan置于sodium Hydroxide体系中,化学反应生成 1,2,3-三氯丙烯
参考文献:Kirrmann; Kremer,Bulletin De La Societe Chimique De France,1948,P. 168
标题:Kirrmann; Kremer,Bulletin De La Societe Chimique De France,1948,P. 168

海关参考信息

专利信息


专利号:WO-2009049476-A1
优先权日:2007-09-20
标题 :Process for the manufacture of (+)-biotin
发明人:CHEN FEN-ER; DAI HUI-FANG; HUANG JIAN; XIONG FEI; JING SHU-PING
权利人:DSM IP ASSETS BV; UNIV FUDAN; CHEN FEN-ER; DAI HUI-FANG; HUANG JIAN; XIONG FEI; JING SHU-PING
摘要:Disclosed are processes for preparing synthetic biotin intermediates and a process for preparing biotin using said intermediates. In particular, disclosed is a process for the stereoselective total synthesis of the natural product (+)-biotin of formula (I).

专利号:US-4000358-A
优先权日:1968-12-19
标题:Unsaturated ester-amides of halogenated alkenes
发明人:D ALELIO GAETANO F
权利人:ALELIO GAETANO F D
摘要:This invention deals with new unsaturated esteramides of alpha , beta -unsaturated polycarboxylic acids derived from halogenated alcohols of the formula wherein R is a divalent hydrocarbon moiety having at least one and no more than 10 carbon atoms, X is a member selected from the class of bromine and chlorine, and R' is a member selected from the class of hydrogen, X and a monovalent hydrocarbon containing at least one and no more than 20 carbon atoms. Typical esteramides are the maleates, fumarates, itaconates and citraconates. These monomers possess fire-retardant properties and are useful for the synthesis of polymers and copolymers.

专利号:US-3950457-A
优先权日:1973-07-30
标 题:Polymers of halogenated esters of phosphorus-containing acids
发明人:D ALELIO GAETANO F
权利人:ALELIO GAETANO F D
摘要:This invention deals with new phosphorus-containing esters having the formulas ##EQU1## wherein Y represents H, CH 3 or Cl; n R represents a divalent hydrocarbon radical containing 1 to 20 carbon atoms; n Q represents >P-- or ##EQU2## ; R' represents X, hydrogen or R'; n R' represents a monovalent hydrocarbon radical containing 1 to 20 carbon atoms; and n X represents chlorine or bromine. n These new esters are useful particularly as fire retardants, agricultural chemicals, fuel additives, plasticizers, monomers and intermediates for the synthesis of other useful derivatives.

专利号:US-3950392-A
优先权日:1968-12-19
标题:Unsaturated ester-amides of halogenated alkenes
发明人:D ALELIO GAETANO F
权利人:ALELIO GAETANO F D
摘要:This invention deals with new unsaturated ester-amides of alpha , beta -unsaturated polycarboxylic acids derived from halogenated alcohols of the formula XX ¦¦ HO-R-C=C-R' wherein R is a divalent hydrocarbon moiety having at least one and no more than 10 carbon atoms, X is a member selected from the class of bromine and chlorine, and R' is a member selected from the class of hydrogen and a monovalent hydrocarbon containing at least one and no more than 20 carbon atoms. Typical ester-amides are the maleates, fumarates, itaconates and citraconates. These monomers possess fire-retardant properties and are useful for the synthesis of polymers and copolymers.

专利号:US-3980737-A
优先权日:1973-07-30
标题:Halogenated esters of phosphorus-containing acids
发明人:D ALELIO GAETANO F
权利人:ALELIO GAETANO F D
摘要:This invention deals with new phosphorus-containing esters having the formulas ##EQU1## and ##EQU2## wherein Y represents H, CH 3 or Cl; n R repesents a divalent hydrocarbon radical containing one to twenty carbon atoms; n Q represents >P- or -P<; n R' repesents X, hydrogen or R'; n R' represents a monovalent hydrocarbon radical containing one to twenty carbon atoms; and n X represents chlorine or bromine. n These new esters are useful particularly as fire retardants, agricultural chemicals, fuel additives, plasticizers, monomers and intermediates for the synthesis of other useful derivatives.

专利号:US-4016224-A
优先权日:1974-11-18
标 题:Halogenated esters of phosphorus-containing acids
发明人:D ALELIO GAETANO F
权利人:ALELIO GAETANO F D
摘要:This invention deals with new phosphorus-containing esters having the formulas and wherein Y represents H, CH3 or Cl; R represents a divalent hydrocarbon radical containing one to twenty carbon atoms; Q represents R' represents X, hydrogen or R''; R'' represents a monovalent hydrocarbon radical containing one to twenty carbon atoms; and X represents chlorine or bromine. These new esters are useful particularly as fire retardants, agricultural chemicals, fuel additives, plasticizers, monomers and intermediates for the synthesis of other useful derivatives.

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品牌试剂参考报价(招募中)

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合成参考文献


摘要:Meylan WM et al; Environ Sci Technol 28: 459-65 (1992)
摘要:Franke C et al; Chemosphere 29: 1501-14 (1994)
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