CAS: 18147-84-7; Trichloro-[2-(Chloromethyl)Prop-2-Enyl]Silane

该化合物是有机硅化合物,其独特结构包括三氯硅烷组和合金.该化合物一般是无色的黄色液体,由于存在氯甲基和三氯硅烷功能组,以其活性闻名.该化合物在有机溶剂中可溶解,但在水分,释放盐酸和形成硅醇化合物时可水解.该化合物主要用于硅酮聚合物的合成,并在各种化学反应中用作联结剂,增强有机材料与无机材料的粘合性与兼容性.在处理该物质时,安全防范至关重要,因为若吸入或接触皮肤,它可能具有腐蚀性,并会构成健康风险.建议在远离湿气的冷干燥地方进行适当储存,以保持其稳定性和再活性.

结构式图片

欧盟法规

ECHA物质C&L通报

上下游产品

trichloro(2-methyl-2-propenyl)silane 2-chloromethyl-3-chloroprop-1-ene trichlorosilane 2-chloromethyl-3-trimethylsilyl-1-propene 3-methylene-1,1-diphenylsilacyclobutane

合成工艺路线路线简述

    📜Trichloro(2-Methyl-2-Propenyl)Silane置于氯体系中,化学反应生成3-氯-2-氯甲基丙烯
    参考文献:Petrow; Nikischin,Izvestiya Akademii Nauk Sssr,Seriya Khimicheskaya,1956,P. 243,245,247; Engl. Ausg. S. 233,235,236
    标题:Petrow; Nikischin,Izvestiya Akademii Nauk Sssr,Seriya Khimicheskaya,1956,P. 243,245,247; Engl. Ausg. S. 233,235,236

    海关参考信息

    专利信息


    专利号:US-11767388-B1
    优先权日:2019-09-18
    标 题 :Silicon-functionalized rubber
    发明人:ENSIGN SETH CODY; VIELHABER MARGARET FLOOK; JOHNGRASS JENA LYNN; MA LIQING
    权利人:GOODYEAR TIRE & RUBBER
    摘要:The compatibility between silica fillers and synthetic rubbers which are synthesized utilizing lanthanide-based catalyst systems, such as neodymium catalyst systems can be improved by terminating the polymerization with a vinyl silane terminating agent. In doing so the vinyl silane is allowed to react with the polymer chain ends of the neodymium rubber to functionalize the chain ends of the polymer chains with silicon containing groups. This results in the rubber having better characteristics for utilization in tire rubber formulations, such a tire tread formulations, that exhibit improved wear characteristics and lower rolling resistance. The process for the synthesis of such functionalized polydiene rubber comprises (1) polymerizing a diene monomer in the presence of a lanthanide-based catalyst system, and (2) terminating the polymerization with a vinyl silane terminator. The functionalized polydiene rubber composition made by this method is comprised of a polydiene rubber which is functionalized at its chain ends with a silicon containing group.

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1055/a-1389-1438
    摘要:Chen M, Liu J. 1,3-Bifunctional Nucleophilic Allylation Reagents: Preparative Methods and Synthetic Applications. Synthesis. 2021 Mar 22;53(13):2167–82. doi: 10.1055/a-1389-1438.
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