86134-26-1 + 15155-41-6 = 15155-41-6 + 86134-26-1 反应条件:1.1 Catalysts: Dichlorobis(Triphenylphosphine)Palladium 标题:Low Band Gap Polymers For Organic Solar Cells 作者:Bundgaard,Eva; Et Al 参考文献:Proceedings Of Spie-The International Society For Optical Engineering 日期:2006 卷标:6334
专利号:US-9328109-B2 优先权日:2013-01-14 标 题:Process for the preparation of benzohetero [1, 3] diazole compounds disubstituted with heteroaryl groups 发明人:BIANCHI GABRIELE; PO' RICCARDO 权利人:ENI SPA 摘要:Process for the preparation of a benzohetero-[1,3]diazole compound disubstituted with brominated heteroaryl groups which comprises reacting at least one dihalogenated benzohetero[1,3]diazole compound with at least one brominated heteroaryl compound. Said benzohetero[1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used in the synthesis of compounds useful in the construction of solar concentrators (LSCs—“Luminescent Solar Concentratorsâ€?). Furthermore, said benzohetero[1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used in the synthesis of photoactive polymers useful in the construction of photovoltaic devices (or solar devices) such as, for example, photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), on both rigid or flexible supports. Furthermore, said benzohetero[1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used as precursor of monomeric units in the synthesis of semiconductr polymers.
专利号:US-9440965-B2 优先权日:2010-07-16 标 题 :Process for the synthesis of benzothiadiazole compounds 发明人:SANTARELLI SAMUELE; RICCI MARCO; FUSCO ROBERTO 权利人:SANTARELLI SAMUELE; RICCI MARCO; FUSCO ROBERTO; ENI SPA 摘要:The invention relates to a significantly improved process for the preparation of benzothiadxazole compounds which can be used in the production of Luminescent Solar Concentrators, (LSC). In particular, the synthesis process of the present invention is oriented towards the preparation of 4,-di-2-thienyl-2,1,3-benzo-thiadiazole.
专利号:WO-2009126118-A1 优先权日:2008-04-10 标题:Unique processable green polymer with a transmissive oxidized state for realization of commerical rgb based electrochromic device applications 发明人:TOPPARE LEVENT KAMIL; GUNBAS GORKEM EMRULLAH; DURMUS ASUMAN 权利人:TOPPARE LEVENT KAMIL; GUNBAS GORKEM EMRULLAH; DURMUS ASUMAN 摘要:In the present invention a method for synthesis of neutral state green polymer PDOPEQ) is developed. The method developed in this invention is characterized by; a) obtaining 2,3-bis(3,4-bis(decyloxy)phenyl)-5,8-dibromoquinoxaline, b) b) obtaining tributyl (2,3-dihydrothieno[3,4-b][l,4]dioxin-5-yl)stannane c) c) Using coupling to attach donor EDOT moieties to the acceptor quinoxaline unit to give the title compound (DOPEQ) in satisfactory yields; d) obtaining neutral state green polymer (PDOPEQ) by using either electrochemical or chemical methods. The polymers synthesized up to date mainly absorb/reflect blue and red colors in the reduced state. Conversely, to obtain a green colored polymer in the reduced state, one should have two absorption bands centered at the blue and red regions of the visible spectrum and moreover, these absorption bands should be manipulated in the same manner at applied potentials.
专利号:US-8809487-B2 优先权日:2012-09-10 标 题 :Process for manufacture of conjugated polymer compositions for solar cell applications 发明人:SEFEROS DWIGHT; DJUKIC BRANDON 权利人:SEFEROS DWIGHT; DJUKIC BRANDON; SAUDI BASIC IND CORP 摘要:The present disclosure relates to a process for the synthesis of a conducting polymer comprising a benzothiadiazole acceptor and indeno-fluorene donor of formula [IV].
专利号:US-11476422-B2 优先权日:2018-03-15 标 题:Anthradithiophene derivatives, process for the preparation thereof and polymers that contain them 发明人:BIANCHI GABRIELE; PASINI DARIO; NITTI ANDREA 权利人:ENI SPA 摘要:An Anthradithiophene derivative having general formula (I): n ncan be advantageously used in the synthesis of electron donor polymers These polymers can be advantageously used in the construction of photovoltaic devices (or solar devices) such as, for example, photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), either on a rigid support or on a flexible support. Furthermore, these polymers can be advantageously used in the construction of Organic Thin Film Transistors (OTFTs), or Organic Field Effect Transistors (OFETs), or Organic Light-Emitting Diodes (OLEDs).
专利号:WO-2017174619-A1 优先权日:2016-04-08 标题 :Intermediates and procedures for the synthesis of functional materials
[参考文献]: Zi Jun Wang, Et Al. Conjugated Microporous Poly(Benzochalcogenadiazole)S For Photocatalytic Oxidative Coupling Of Amines Under Visible Light. Chemsuschem. 2015 Oct 26;8(20):3459-64.
合成参考文献
参考文献:10.1007/s00604-019-3608-1 摘要:Ding Z, Wang C, Wang S, Wu L, Zhang X. Light-harvesting metal-organic framework nanoprobes for ratiometric fluorescence energy transfer-based determination of pH values and temperature. Mikrochim Acta. 2019 Jun 27;186(7):476. doi: 10.1007/s00604-019-3608-1.