📜2-乙基己醇置于tetrabutoxytitanium,硅酸四乙酯体系中,化学反应 24.0H,以95%的收率获得四(2-乙基己氧基)硅烷 参考文献:Process For Preparing A Composition Containing 2-Ethylhexyl Silicate 标题:Process For Preparing A Composition Containing 2-Ethylhexyl Silicate 摘要:包含2-乙基己基硅酸酯的组合物是通过在存在四丁酸钛作为催化剂的情况下,加热乙硅酸酯与过量的2-乙基己醇的反应混合物至低于2-乙基己醇沸点的温度,并在搅拌的同时使反应混合物发生反应而制得的,然后通过蒸馏从反应混合物中去除乙醇和过量的2-乙基己醇,从而获得含有2-乙基己基硅酸酯的组合物.
专利号:US-6495208-B1 优先权日:1999-09-09 标 题 :Near-room temperature CVD synthesis of organic polymer/oxide dielectric nanocomposites 发明人:DESU SESHU B; SENKEVICH JOHN J 权利人:VIRGINIA TECH INTELL PROP 摘要:Nanocomposite thin films with low dielectric constants are made by the simultaneous deposition of an oxide dielectric and an organic polymer at near room temperatures. Suitable oxides include SiO 2 , and suitable organic polymers include poly(chloro-para-xylylene). The two dielectric materials, when deposited, form nanocomposites characterized by nanometer-sized domains of dielectric material. The nanocomposite thin films of this invention are useful as dielectric layers for interlevel dielectric (ILD) and intermetal dielectric (IMD) dielectrics in the manufacture of semiconductor devices as well as for thin films for flat panel displays, food wraps, hybrid ceramics, glass, hard disk drives, and optical disk drives. Additionally, the invention comprises semiconductor devices and semiconductor chips made incorporating nanocomposites deposited by chemical vapor deposition.
专利号:US-7309799-B2 优先权日:2004-06-01 标 题:Methods for the synthesis of milnacipran and congeners thereof 发明人:BUCHWALD STEPHEN L; SWAGER TIMOTHY M; RARIY ROMAN V 权利人:COLLEGIUM PHARMACEUTICAL INC 摘要:One aspect of the present invention relates to methods for synthesizing milnacipran or congeners thereof. Another aspect of the present invention relates to asymmetric methods for synthesizing enantiomerically enriched milnacipran or congeners thereof. The present invention also relates to methods for synthesizing intermediates useful in the non-asymmetric or asymmetric methods for synthesizing enantiomerically enriched milnacipran or congeners thereof.
专利号:US-5629394-A 优先权日:1992-12-17 标 题 :Direct synthesis by living cationic polymerization of nitrogen-containing polymers 发明人:CHERADAME HERVE M; CHEN FRANK J; STANAT JON E R; NGUYEN HUNG A; TABAR BEHROOZ R 权利人:EXXON CHEMICAL PATENTS INC 摘要:A method is provided for the direct synthesis by living cationic polymerization of novel polymeric materials functionalized with desirable nitrogen-containing functional groups such as terminal azido, cyano, carbonylamino, cyanato, thiocyanato or thiocarbonylamino groups. Polymerization and functionalization occur in a substantially simultaneous manner. All necessary reactants for the functionalization are present when polymerization is initiated. The nitrogen-containing functional group is provided as a part of a molecule having a release moiety which is preferably resonance stabilized or a tertiary alkyl type and which acts to aid the nitrogen-containing species in functioning as a leaving group.
专利号:US-2003072716-A1 优先权日:2001-06-22 标 题:Renewable, carbohydrate based CO2-philes 发明人:POOVATHINTHODIYIL RAVEENDRAN; WALLEN SCOTT L 摘要:A composition is disclosed comprising a carbohydrate-based material a dispersed in carbon dioxide. A general method for synthesizing inexpensive, renewable, non-toxic, non-fluorous, carbohydrate based CO 2 -philes is disclosed. These CO 2 -philes are soluble in carbon dioxide. Methods of making the composition are also disclosed. The methods and composition are useful in a variety of applications and can utilize gaseous, liquid and supercritical carbon dioxide. The methods and compositions are useful in the synthesis of surfactants and metal chelates for CO 2 , as a sizing substrate, in CO 2 -based coating processes, for impregnation and plasticizing cellulosic and non-cellulosic materials, in pharmaceutical applications, such as crystallization, dispersion and encapsulation of bioactive molecules in solid systems, in the densification of CO 2 , in the synthesis of biodegradable polymers in CO 2 , and for carbon dioxide removal, to name just a few.
专利号:US-2005282898-A1 优先权日:2004-06-01 标 题 :Methods for the synthesis of milnacipran and congeners thereof
专利号:WO-2005118564-A2 优先权日:2004-06-01 标 题:Methods for the synthesis of milnacipran and congeners thereof
参考文献:10.1103/physreve.77.030601 摘要:Lee DR, Dutta P, Yu CJ. Observation of a liquid-to-layered transition in thin liquid films when surface and interface regions overlap. Phys Rev E Stat Nonlin Soft Matter Phys. 2008 Mar;77(3 Pt 1):030601. doi: 10.1103/physreve.77.030601.