CAS: 7205-98-3; ((Chloromethyl)Sulfonyl)Benzene

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CAS号7205-94-9 氯甲基苯亚砜 | CAS号7205-91-6 氯甲基苯硫醚 | CAS号74-97-5 溴氯甲烷 | CAS号873-55-2 苯亚磺酸钠 | CAS号195371-23-4 p-Tolyl-chlorbr... | CAS号38009-92-6 2-chloro-1-phen... | CAS号565446-69-7 (E)-4-(3-(2-ben... | CAS号3406-03-9 2-苯磺酰基苯乙酮 | CAS号100-68-5 茴香硫醚 | CAS号108-98-5 硫酚 | CAS号107267-01-6 2-methyl-3-(phe... | CAS号105285-61-8 2-[1-(benzenesu... | CAS号89303-10-6 2-(benzenesulfo... | CAS号1865-13-0 methyl 3-(benze... | CAS号618-41-7 苯亚磺酸 | CAS号24437-60-3 1-bromo-4-(chlo... | CAS号5535-48-8 苯基乙烯基砜 | CAS号599-94-0 1,2-双(苯磺酰基)乙烷 | CAS号3112-85-4 甲基苯基砜

📜氯甲基苯硫醚置于间氯过氧苯甲酸体系中,化学反应生成 氯甲基苯砜
参考文献:用氟化砜对环氧树脂进行亲核性氟烷基化
标题:用氟化砜对环氧树脂进行亲核性氟烷基化
摘要:简单的环氧化物与氟化砜的前所未有的亲核性氟代烷基化反应,一步一步即可制得β-氟代烷基醇.在用氟化碳负离子环氧化物的亲核氟烷基化的负"氟效果"是由碳负离子phso之间的反应性的比较探测2 Cf 2-(3)和phso 2的ccl 2-(4)和负碳离子之间phso 2 Chf-(7)和phso 2三氯甲烷-(13).发现通过引入另一个吸电子的苯磺酰基来介导这种氟效应是一种有效增加氟化碳负离子亲核性的有效方法,其反应顺序为[(phso 2)2 Cf-](16)> Phso 2 Cfh-(7)»phso 2 Cf 2-(3).
DOI:10.1021/jo060955L

专利信息

专利号:US-9969685-B2
优先权日:2016-09-28
标 题 :Enantioselective synthesis of pyrroloindole compounds
发明人：SCHMIDT MICHAEL ANTHONY
权利人:BRISTOL MYERS SQUIBB CO
摘要:Compounds according to formula (I) or (II), wherein R 1 , R 2 , and R 3 are as defined in the specification, are versatile intermediates for the synthesis of DNA minor groove binder-alkylators having a cyclopropapyrroloindole (CPI) or seco-CPI alkylating subunit.

专利号:US-5202444-A
优先权日:1990-11-27
标题:Optically isomeric inositol and process for making optically active compound
发明人：OZAKI SHOICHIRO; AKIYAMA TAKAHIKO; KAGEYAMA KUNIO; MACHIDA MORIHISA
权利人:YOKOHAMA RUBBER CO LTD
摘要:Optically active diols and hydroxycarboxylic acids and their esters are produced by deriving 1L-1,2:5,6-di-O-cyclohexylidene-chiro-inositol from 1L-chiro-inositol as an asymmetric source, followed by introduction of a selected class of sterically hindering and asymmetrically reactive groups into the first-mentioned compound and by subsequent reduction of the resulting compound. Seven specific inositols are also derivable from synthesis of those ultimate compounds.

专利号:US-2018086701-A1
优先权日:2016-09-28
标 题:Enantioselective synthesis of pyrroloindole compounds