CAS: 60132-35-6; (1S,4As,7R,8As)-7-(2-Hydroxypropan-2-yl)-1,4A-Dimethyldecahydronaphthalen-1-Ol

该化合物是一种属于有机分子类别的化学化合物,其特点是独特的分子结构,包括多种功能组,有助于化学反应和物理特性.Pterodondiol一般没有色状,可粉黄液,在有机溶剂中表现出中等溶解性,但水溶解性较低.其分子式表明存在可参与氢结合,影响其沸点和粘度的氢化氢基化合物.该化合物因其潜在的生物活动,对各个领域,包括有机合成和药用化学具有兴趣.此外,Pterodondi可能表现出特定的光学特性,使其在药物或农用化学等应用中有用.与许多有机化合物一样,应参考安全数据,以了解其处理,储存和潜在危害.

英文名称(1S,4As,7R,8As)-7-(2-Hydroxypropan-2-yl)-1,4A-Dimethyldecahydronaphthalen-1-Ol
中文名称臭灵丹二醇
IUPAC名称(1S,4aS,7R,8aS)-7-(2-hydroxypropan-2-yl)-1,4a-dimethyldecahydronaphthalen-1-ol
其它别名Pterodondiol; 2-Naphthalenemethanol, Decahydro-8-Hydroxy-α,α,4A,8-Tetramethyl-, (2R,4As,8S,8As)-
CAS编号60132-35-6
MFCD编号:MFCD17214855
分子式:C15H28O2分子量:240.39
产品CID: 1578028
产品分类天然产物 → 倍半萜

相似结构搜索
InChIKey: LKKDASYGWYYFIK-DHMWGJHJSA-N
InChI=1S/C15H28O2/c1-13(2,16)11-6-9-14(3)7-5-8-15(4,17)12(14)10-11/h11-12,16-17H,5-10H2,1-4H3/t11-,12+,14+,15+/m1/s1
计算化学: 氢键受体数2.0氢键供体数2.0可旋转键数1.0

MSDS等安全信息

危险描述H303May be harmful if swallowed+H313Skin contact may be harmful+H333Inhalation may be harmful to the body
防范说明P264+P280+P305+P351+P338+P337+P313
危险品标志Xi
安全声明H303+H313+H333

上下游产品

elemol eudesmagnolol eudeshonokiol A 2-[(2R,4aR,8R,8aR)-8-(3,5'-Diallyl-2'-methoxy-biphenyl-4-yloxy)-4a,8-dimethyl-decahydro-naphthalen-2-yl]-propan-2-olintermedeol

合成工艺路线路线简述

📜(1R,4Ar,7R,8Ar)-8A-Hydroxy-1,4A-Dimethyl-7-(Prop-1-En-2-yl)-octahydronaphthalen-2(1H)-One置于pd/srco3 盐酸,叔丁基过氧化氢,Sodium Tetrahydroborate,Lithium Aluminium Tetrahydride,Bis(Acetylacetonate)Oxovanadium,乙醇,氨,氢气,Aluminum Isopropoxide,Lithium,Lithium Carbonate,间氯过氧苯甲酸,Lithium Bromide体系中,用吡啶,甲醇,乙醚,乙醇,氯仿,乙酸乙酯,N,N-二甲基甲酰胺,甲苯,苯作为反应溶剂,-65.0~150.0 °C,101.33 Kpa 条件下,反应 50.33H,反应生成臭灵丹二醇
参考文献:Enantioselective Total Syntheses Of (−)-7βh-Eudesmane-4α,11-Diol And (+)-Ent-7βh-Eudesmane-4α,11-Diol
标题:Enantioselective Total Syntheses Of (−)-7βh-Eudesmane-4α,11-Diol And (+)-Ent-7βh-Eudesmane-4α,11-Diol
摘要:The Syntheses Of (-)-7 Beta H-Eudesmane-4 Alpha,11-Diol (2) And (+)-Ent-7 Beta H-Eudesmane-4 Alpha,11-Diol (Ent-2) Were Carried Out Starting From (-)-And (+)-Dihydrocarvones. As A Result,The Structure,Including Absolute Configuration,Of The Naturally occurring Eudesmane-4,11-Diol Isolated From Pluchea Arguta Was Determined To Be (+)-Ent-7 Beta H-Eudesmane-4 Alpha,11-Diol (Ent-2).
DOI:10.1021/np9702906