CAS: 3954-13-0; Pentyl Isocyanate

上下游产品

CAS号628-02-4 己酰胺 | CAS号110-58-7 1-氨基戊烷 | CAS号503-38-8 氯甲酸三氯甲酯 | CAS号75-44-5 光气 | CAS号142-61-0 己酰氯 | CAS号32315-10-9 三光气 | CAS号2443-62-1 己酰肼 | CAS号17228-07-8 hexanoyl azide | CAS号91907-79-8 1-pentyl-3-phen... | CAS号2524-60-9 Acetamide, N-pentyl | CAS号61357-27-5 methyl N-pentyl... | CAS号64098-83-5 5-fluoro-2,4-di... | CAS号38869-91-9 pentylurea

己酰胺置于[(N-Tosylimino)Iodo]Benzene体系中,用 二氯甲烷 用作溶剂,化学反应 1.0H,反应生成异氰酸戊酯
参考文献:(tosylimino)苯基λ 3-Iodane作为试剂用于通过芳香族和脂肪族甲酰胺的霍夫曼重排甲基氨基甲酸酯的合成
标题:(tosylimino)苯基λ 3-Iodane作为试剂用于通过芳香族和脂肪族甲酰胺的霍夫曼重排甲基氨基甲酸酯的合成
摘要:一种新的,温和的程序使用(tosylimino)苯基-λ芳香族和脂肪族羧酰胺的霍夫曼重排3-Iodane,Phints,作为试剂被报告.由于反应条件温和,该方法对于取代的苯甲酰胺的霍夫曼重排特别有用,该苯甲酰胺通常会提供与其他高价碘氧化剂的复杂反应混合物.羧酰胺与phints反应的温和反应条件和高选择性可以分离最初形成的不稳定异氰酸酯,或通过用醇处理将其随后转化为稳定的氨基甲酸酯.
Doi:10.1021/jo300007C

专利信息

专利号:US-4749806-A
优先权日:1984-12-28
标题:Process for the synthesis of isocyanates and of isocyanate derivatives
发明人：TKATCHENKO IGOR; JAOUHARI RABIH; BONNET MICHEL; DAWKINS GORDON; LECOLIER SERGE
权利人:POUDRES & EXPLOSIFS STE NALE
摘要:The present invention relates to a process for the synthesis of isocyanates and of isocyanate derivatives. Isocyanates are obtained by reacting an organic halide with a metal cyanate in an organic medium in the presence of a catalyst consisting of a complex of nickel with at least one organic ligand, in which complex the nickel is in the zero oxidation state. A carbamate or a urea, respectively, are obtained by a subsequent reaction with a hydroxy compound or a primary or secondary amine. Isocyanates and their derivatives are used especially either as refined synthesis agents for the production of pesticides and medications, or as monomers or comonomers for the preparation of many macromolecular compounds.

专利号:US-4140708-A
优先权日:1975-10-16
标 题 :Asymmetric synthesis of optically active prostaglandins
发明人：CHADHA NARESH K; PARTRIDGE JR JOHN J; USKOKOVIC MILAN R
权利人:HOFFMANN LA ROCHE
摘要:An asymmetric synthesis of optically active prostaglandin F 2 α from cyclopentadiene including intermediates in this synthesis.

专利号:US-3933892-A
优先权日:1973-02-12
标题 :Asymmetric synthesis of optically active prostaglandins
发明人：CHADHA NARESH KUMAR; PARTRIDGE JR JOHN JOSEPH; USKOKOVIC MILAN RADOJE
权利人:HOFFMANN LA ROCHE
摘要:An asymmetric synthesis of optically active prostaglandin F 2 .sub.α from cyclopentadiene including intermediates in this synthesis.

专利号:US-5696290-A
优先权日:1994-09-12
标 题:Synthesis of penta-substituted guanidines
发明人：RUETTIMANN KENNETH W; MCGHEE WILLIAM D; SOLODAR A JOHN
权利人:MONSANTO CO
摘要:The present invention is the novel synthesis of sterically hindered penta-substituted guanidines by a process in which (1a) an isocyanate is reacted first with a di-substituted amine or (1b) a urea is reacted with two moles of a mono-substituted amine to form a tri-substituted urea followed by (2) treatment of the tri-substituted urea with an activating agent before reacting with a second di-substituted amine in the presence of a base.

专利号:US-2009306400-A1
优先权日:2006-03-27
标 题:Convergent process for the synthesis of taxane derivatives.
发明人：HENRI JOHN T; MCCHESNEY JAMES D; VENKATARAMAN SYLESH K; LAMB RODGER L; FOSTER JONATHAN E; SUMNER CHRISTIAN M; YE SHANGPING
权利人:HENRI JOHN T; MCCHESNEY JAMES D; VENKATARAMAN SYLESH K; LAMB RODGER L; FOSTER JONATHAN E; SUMNER CHRISTIAN M; YE SHANGPING
摘要:The present invention is broadly directed to novel compounds useful for the synthesis of biologically active compounds, including taxane derivatives, and convergent processes for the preparation of these taxane derivatives and their intermediates.

专利号:US-9428524-B2
优先权日:2010-05-25
标 题:Synthetic process for the manufacture of ecteinascidin compounds
发明人：MARTIN LÓPEZ MA JESÚS; FRANCESCH SOLLOSO ANDRÉS; CUEVAS MARCHANTE MARIA DEL CARMEN
权利人:MARTIN LÓPEZ MA JESÚS; FRANCESCH SOLLOSO ANDRÉS; CUEVAS MARCHANTE MARIA DEL CARMEN; PHARMA MAR SA
摘要:This invention relates to compounds of formula II: wherein R 1 , R 2 , Prot SH , and Prot NH are as defined, to processes for the synthesis of ecteinascidins of formula I from compounds of formula II, and to processes for the synthesis of compounds of formula II.