CAS: 1535-65-5; ((Difluoromethyl)Sulfonyl)Benzene

相似化合物

426-58-4 153698-38-5 20808-12-2

上下游产品

CAS号1535-67-7 二氟甲基苯基硫 | CAS号1073-67-2 对氯苯乙烯 | CAS号1042681-48-0 (3E)-1,1-difluo... | CAS号536975-50-5 [difluoro(pheny... | CAS号115262-01-6 (溴二氟甲基)三甲基硅烷 | CAS号873-55-2 苯亚磺酸钠 | CAS号536975-49-2 [[difluoro(trim... | CAS号108-98-5 硫酚 | CAS号1717-59-5 2,2-二氟-2-(氟磺酰基)乙酸 | CAS号458-92-4 二氟甲氧基苯 | CAS号359-15-9 1,1-DIFLUORODIM... | CAS号1535-67-7 二氟甲基苯基硫 | CAS号618-41-7 苯亚磺酸 | CAS号24906-73-8 1-(difluorometh... | CAS号98-00-0 糠醇 | CAS号122590-90-3 α-(difluoro[phe... | CAS号65864-64-4 (二氟甲基)三甲基硅烷 | CAS号122590-93-6 [benzenesulfony...

[二氟(苯基磺酰基)甲基](三甲基)硅烷置于silica Gel体系中,用 四氢呋喃 用作溶剂,以78%的收率获得二氟甲基苯砜
参考文献:一氟,二氟和三氟苯乙烯单体的合成
标题:一氟,二氟和三氟苯乙烯单体的合成
摘要:公开了适用于聚合研究的克量的三种氟化α-甲基苯乙烯单体的精确合成方法,所有方法均基于使用价格合理的市售起始原料和试剂. 氟化-亲核性氟烷基化-钯催化-单体合成-功能性含氟聚合物
Doi:10.1055/s-0029-1218785

专利信息

专利号:US-5175302-A
优先权日:1987-07-13
标 题 :Nucleophilic fluoroalkylation of aldehydes
发明人：STAHLY G PATRICK
权利人:ETHYL CORP
摘要:Aryl difluoromethyl sulfone adds to aldehydes under phase transfer conditions to give novel substituted alcohols of the general formula n n RCH(OH)CF.sub.2 SO.sub.2 Ar (I) n n wherein R is an aryl, cycloaliphatic, sec- or tert-aliphatic, or heterocyclic group and Ar is an aryl group. The substituted alcohols of formula I are of particular utility as intermediates in the synthesis of a variety of useful end products. For example, the products of formula I may be utilized in desulfonylation reactions, oxidation reactions and fluorination reactions.

专利号:US-4837327-A
优先权日:1987-07-13
标 题 :Process for nucleophilic fluoroalkylation of aldehydes
发明人：STAHLY G PATRICK
权利人:ETHYL CORP
摘要:Aryl difluoromethyl sulfone adds to alkehydes under phase transfer conditions to give novel substituted alcohols of the general formula n n RCH(OH)CF.sub.2 SO.sub.2 Ar (I) n n wherein R is an aryl, cycloaliphatic, sec- or tert-aliphatic, or heterocyclic group and Ar is an aryl group. The substituted alcohols of formula I are of particular utility as intermediates in the synthesis of a variety of useful end products. For example, the products of formula I may be utilized in desulfonylation reactions, oxidation reactions and fluorination reactions.

专利号:US-4999429-A
优先权日:1989-01-09
标 题 :Process for the preparation of α,α,β-1-trifluoro-1-olefinic derivatives
发明人：STAHLY G PATRICK
权利人:ETHYL CORP
摘要:Aryl difluoromethyl sulfone adds to aldehydes under phase transfer conditions to give novel substituted alcohols of the general formula n n RCH(OH)CF.sub.2 SO.sub.2 Ar (I) n n wherein R is an aryl, cycloaliphatic, sec- or tert-aliphatic, or heterocyclic group and Ar is an aryl group. The substituted alcohols of formula I are of particular utility as intermediates in the synthesis of a variety of useful end products. For example, the products of formula I may be utilized in desulfonylation reactions, oxidation reactions and fluorination reactions.

专利号:US-7119232-B2
优先权日:2004-03-26
标题 :Nucleophilic substitution reactions of difluorormethyl phenyl sulfone with alkyl halides leading to the facile synthesis of terminal 1,1-difluoro-1-alkenes and difluoromethylalkanes
发明人：PRAKASH G K SURYA; HU JINBO; OLAH GEORGE A; WANG YING
权利人:UNIV SOUTHERN CALIFORNIA
摘要:(Benzenesulfonyl)difluoromethyl anion, in situ generated from difluoromethyl phenyl sulfone and a base, was found to easily undergo nucleophilic substitution reactions (S N 2) with primary alkyl halides, elemental halogens, and perfluoroalkyl halides with good selectivity. The formed (benzenesufonyl)difluoromethylalkanes are useful intermediates for the facile preparation of 1,1-difluoro-1-alkenes and difluoromethylalkanes. Thus, difluoromethyl phenyl sulfone acts as both “CF 2 â•?â€? and “CF 2 H − â€? synthons

专利号:US-2006052643-A1
优先权日:2004-03-26
标题:Nucleophilic substitution reactions of difluorormethyl phenyl sulfone with alkyl halides leading to the facile synthesis of terminal 1,1-difluoro-1-alkenes and difluoromethylalkanes

专利号:WO-2005097739-A2
优先权日:2004-03-26
标 题 :Nucleophilic substitution reactions of difluoromethyl phenyl sulfone with alkyl halides leading to the facile synthesis of terminal 1,1-difluoro-1-alkenes and difluoromethylalkanes