叔丁基苯置于正丁基锂,溴,碘体系中,用 四氢呋喃 用作溶剂,化学反应 3.0H,反应生成4-叔丁基苯硼酸 参考文献:Synthesis Of T-Butylated Diphenylanthracene Derivatives As Blue Host Materials For Oled Applications 标题:Synthesis Of T-Butylated Diphenylanthracene Derivatives As Blue Host Materials For Oled Applications 摘要:This Paper Describes The Cost-Effective Synthesis And The Photoluminescence Of Diphenylanthracene Derivatives,Which Are Found To Be Potential Blue Host Materials For Organic Light Emitting Diode (Oled) Technology. (C) 2003 Elsevier Ltd. All Rights Reserved. Doi:10.1016/s0040-4039(03)01300-5
专利号:US-7115737-B2 优先权日:2003-05-05 标题:Solid phase synthesis of novel biaryl triazine library by suzuki cross coupling 发明人:CHANG YOUNG-TAE 权利人:UNIV NEW YORK 摘要:Two methods are used to produce diaryl trisubstituted triazines. In the first method, cyanuric chloride is first reacted with a 4-alkoxybenzylamine. The product of this reaction is then reacted with a resin-bound amine, such as 4-alkoxybenzylamine, to ensure that the final compound will be bound to a resin. The product of this reaction is then reacted with boronic acid to produce a trisubstituted diaryl triazine. In the second method, cyanuric chloride is reacted with a benzenealkanethiol. The product of this reaction is then reacted with a resin-bound amine, such as 4-alkoxybenzylamine, to ensure that the final compound will be bound to a resin. The product of this reaction is then reacted with m-CPBA to form a sulfone, which is then reacted with a 4-alkoxybenzylamine to form the desired trisubstituted biaryltriazine.
专利号:US-2010261860-A1 优先权日:2007-10-25 标题:Racemoselective synthesis of ansa-metallocene compounds, ansa-metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers
专利号:US-10273339-B2 优先权日:2006-02-24 标题 :Synthesis of a highly crystalline, covalently linked porous network
专利号:CN-110698399-A 优先权日:2019-10-24 标题 :A kind of palladium-catalyzed synthesis of aryl acridine derivative and preparation method thereof
专利号:US-7781470-B2 优先权日:1999-09-13 标题:Aminodicarboxylic acid derivatives having pharmaceutical properties 发明人:ALONSO-ALIJA CRISTINA; HEIL MARKUS; FLUBACHER DIETMAR; NAAB PAUL; PERNERSTORFER JOSEF; STASCH JOHANNES-PETER; WUNDER FRANK; DEMBOWSKY KLAUS; PERZBORN ELIZABETH; STAHL ELKE 权利人:BAYER SCHERING PHARMA AG 摘要:The invention relates to compounds of formulae (II), (IV), and (VI) as shown below, n nwherein the several variable groups are as defined in the specification and claims. Processes for making these materials, and methods for using them in the synthesis of compounds for treatment of cardiovascular disorders and fibrotic disorders are also disclosed.
专利号:US-2004225125-A1 优先权日:2003-05-05 标 题 :Solid phase synthesis of novel biaryl triazine library by suzuki cross coupling
参考标题:Synthesis Of Ortho-Phenolic Sulfilimines Via An Intermolecular Sulfur Atom Transfer Cascade Reaction 作者:Feng Xiong,Yingying Zuo,Yinan Song,Linxing Zhang,Xinhao Zhang,Shaojian Xu,Yan Ren |发布日期:2020.5.15 摘要:To Expand The Toolbox For The Synthesis Of Ortho-Phenolic Sulfilimines, Sigmatropic Rearrangements Were Introduced To The Field Of Sulfilimine Chemistry. Herein We Report A N-H Sulfenylation/[2,3]-Sigmatropic Rearrangement Cascade Reaction. This Mild Reaction Enables Commercially Available Thiols To Serve As The Sulfenylation Reagent And Generates Water As The Sole Byproduct. Moreover, The Reaction
合成参考文献
摘要:Black, D. A.; Fagnou, K., Science of Synthesis, (2010) 45, 571. 摘要:Tomé, A. C., Science of Synthesis Knowledge Updates, (2015) 2, 89. 摘要:Aggarwal, P.; Bebbington, M. W. P., Science of Synthesis Knowledge Updates, (2012) 2, 457. 摘要:Kleoff, M.; Omoregbee, K.; Zimmer, R., Science of Synthesis Knowledge Updates, (2018) 4, 226. 摘要:González-Bello, C., Science of Synthesis Knowledge Updates, (2018) 1, 233.