CAS: 10088-95-6; Radicinin
该化合物是一种自然形成的化合物,被归类为二代代谢物,主要以它存在于某些真菌中,特别是五氯硝基苯;Radicin展示抗风素特性,使其在药理学和农业应用中都感兴趣;该化合物具有复杂的分子结构,有助于其生物活动;其特点是它能够抑制各种真菌种的生长,有可能成为开发新的抗菌剂的铅化合物;此外,还研究了对其他生物系统的影响,包括它对某些癌症细胞线的潜在细胞毒性;它在不同溶剂中的溶性性和稳定性可以变化,影响其在研究和工业中的应用;
- 英文名称Radicinin
- 中文名称根匍柄菌素
- IUPAC名称(2S,3S)-3-hydroxy-2-methyl-7-((E)-prop-1-en-1-yl)-2,3-dihydro-4H,5H-pyrano[4,3-b]pyran-4,5-dione
- 其它别名Radicinin From Alternaria Chrysanthemi; 2,3-Dihydro-3-Alpha-Hydroxy-2-Beta-Methyl-7-Propenyl-4H,5H-Pyrano(4,3-B)Pyra; 4H,5H-Pyrano(4,3-B)Pyran-4,5-Dione,2,3-Dihydro-3-Alpha-Hydroxy-2-Beta-Methyl-7; N-4,5-Dione; -Propenyl-; Radicinin; Stemphylone; (2S)-2,3-Dihydro-3α-Hydroxy-2β-Methyl-7-[(E)-1-Propenyl]-4H,5H-Pyrano[4,3-B]Pyran-4,5-Dione
- CAS编号10088-95-6
- MFCD编号:MFCD00079543
- FDA UNII编号:G01Z2N575M
- 分子式:C12H12O5分子量:236.22
- 产品CID: 19828
- 产品分类有机原料 → 有机氧化合物
物理性质
MSDS等安全信息
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专利信息
专利号:WO-2024126813-A1
优先权日:2022-12-16
标题:Chitinopeptins, their use and recombinant synthesis in organisms for plant protection
发明人：MARNER MICHAEL; SPOHN MARIUS; SCHÄBERLE TILL; PATRAS MARIA; MIHAJLOVIC SANJA
权利人:FRAUNHOFER GES FORSCHUNG
摘要:The invention is based on an unexpected antimicrobial effect of Chitinopeptin A and its iron(III) complex against the Gram-negative bacterium Xylella fastidiosa. In a first aspect, the invention pertains to a peptide comprising a chain of amino acids as shown in this document, and in a second aspect to a complex of said peptide. In further aspects, the invention pertains to a nucleic acid encoding for the peptide, a non-ribosomal peptide synthetase (NRPS), a vector and a cell comprising the previously mentioned subject matter. Additionally, the invention pertains to a plant protection agent and a method of manufacturing the aforementioned subject matter. Based on the unexpected antimicrobial effect of Chitinopeptin A, furthermore a use of the peptide, a plant protection agent, a plant protection composition and a method for the treatment of a disease and/or increasing resistance against infection in a plant is disclosed.
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主要参考文献
1: Suzuki M, Sakuno E, Ishihara A, Tamura J, Nakajima H. Conversions of deoxyradicinin to radicinin and of radicinin to 3-epi-radicinin in the phytopathogenic fungus Bipolaris coicis. Phytochemistry. 2012 Mar;75:14-20. doi: 10.1016/j.phytochem.2011.11.010. Epub 2011 Dec 16. doi: 10.1016/j.phytochem.2015.03.015. Epub 2015 Apr 16. doi: 10.1016/j.biortech.2010.10.028. Epub 2010 Oct 13. Italian. Italian. Italian. Italian. Italian. doi: 10.1016/S1995-7645(14)60236-4. doi: 10.1021/jf502484n. Epub 2014 Aug 28.
合成参考文献
摘要:U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals., NX#00964
参考文献:10.1021/jf035254t
摘要:Solfrizzo M, Vitti C, De Girolamo A, Visconti A, Logrieco A, Fanizzi FP. Radicinols and radicinin phytotoxins produced by Alternaria radicina on carrots. J Agric Food Chem. 2004 Jun 02;52(11):3655–60. doi: 10.1021/jf035254t.
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