CAS: 921619-89-8; [1,1':4',1''-Terphenyl]-3,3'',5,5''-Tetracarboxylic Acid

结构式图片

相似化合物

2380275-62-5 1637760-07-6 1119195-98-0

物理性质

MSDS等安全信息

欧盟法规

C&L通报

合成工艺路线路线简述

  • 1415325-73-3 = 921619-89-8
    反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Methanol,Tetrahydrofuran,Water; Overnight,60 °C1.2 Reagents: Hydrochloric Acid Solvents: Water; Acidified
    标题:Functionalized Mesopores To Metal Organic Frameworks Via Metal Ligand Fragment Coassembly
    作者:Park,Jinhee; Wang,Zhiyong U.; Sun,Lin-Bing; Chen,Ying-Pin; Zhou,Hong-Cai
    参考文献:Journal Of The American Chemical Society 日期:2012 卷标:134(49) 页码:20110-20116]

    106-37-6 + 177735-55-6 = 921619-89-8
    反应条件:1.1 Reagents: Tripotassium Phosphate Catalysts: Tetrakis(Triphenylphosphine)Palladium Solvents: 1,4-Dioxane; Rt -> 80 °C; 48 H,80 °C
    标题:Method For Preparing Novel Stable Metal Organic Framework Material And Application
    参考文献:China]

    921619-89-8 + 127-19-5 = 921619-89-8
    反应条件:1.1 Reagents: Nitric Acid,Water,Cerium Trichloride Solvents: Dimethylacetamide (Complex With Cerium Terphenylmulticarboxylate),Water; 1 D,180 °C
    标题:Rare Earth Organic Framework Material For Detecting Vitamin C And Its Preparation Method
    参考文献:China]

    110655-53-3 = 921619-89-8
    反应条件:1.1 Reagents: Sodium Hydroxide,Permanganic Acid (Hmno4),Potassium Salt (1:1) Solvents: Tert-Butanol,Water; 2 D,55 °C1.2 Reagents: Ethanol; 55 °C; 55 °C -> 90 °C1.3 Reagents: Hydrochloric Acid Solvents: Water; Ph 2,Rt
    标题:Guest-Induced Growth Of A Surface-Based Supramolecular Bilayer
    作者:Blunt,Matthew O.; Russell,James C.; Gimenez-Lopez,Maria Del Carmen; Taleb,Nassiba; Lin,Xiang; Et Al
    参考文献:Nature Chemistry 日期:2010 卷标:3(1) 页码:74-78]

    921619-89-8 = 921619-89-8
    反应条件:1.1 Reagents: Manganese (Mofs With Polycarboxylate) Solvents: Dimethylformamide,Water; 4 D,80 °C
    标题:Manganese-Based Metal-Organic Framework Material And Preparation Method And Application Thereof In Preparing Chemodynamic Therapy Drugs
    参考文献:China]

    921619-89-8 = 921619-89-8
    反应条件:1.1 Reagents: Nitric Acid,Terbium Nitrate Pentahydrate Solvents: Dimethylformamide,Water; 72 H,100 °C
    标题:Terbium-Based Metal Organic Framework Material And Preparation Method And Application Thereof
    参考文献:China]

    = 921619-89-8 [标题:Reaction Conditions
    标题:Preparation Of Biphenyl Aromatic Conjugated Polycarboxylic Acid By Using Aryl Diboronic Acid And Halogenated Phenyl Carboxylates
    参考文献:China]

    110655-53-3 = 921619-89-8
    反应条件:1.1 Reagents: Permanganic Acid (Hmno4),Potassium Salt (1:1) Solvents: Pyridine,Water; 3 D,100 °C1.2 Reagents: Hydrochloric Acid Solvents: Water; Ph 2
    标题:Metal-Hydrogen-Pi-Bonded Organic Frameworks
    作者:Zhu,Jie; Samperisi,Laura; Kalaj,Mark; Chiong,Jerika A.; Bailey,Jake B.; Et Al
    参考文献:Dalton Transactions 日期:2022 卷标:51(5) 页码:1927-1935]

    110655-53-3 = 921619-89-8
    反应条件:1.1 Reagents: Permanganic Acid (Hmno4),Potassium Salt (1:1) Solvents: Pyridine,Water; 3 D,100 °C
    标题:Metal-Hydrogen-Pi-Bonded Organic Frameworks
    作者:Zhu,Jie; Samperisi,Laura; Kalaj,Mark; Chiong,Jerika A.; Bailey,Jake B.; Et Al
    参考文献:Chemrxiv 日期:2021 卷标:1 页码:1-27]

    26249-12-7 + 932378-94-4 = 921619-89-8
    反应条件:1.1 Reagents: Tripotassium Phosphate Catalysts: Tetrakis(Triphenylphosphine)Palladium Solvents: 1,4-Dioxane; 3 D,80 °C1.2 Reagents: Sodium Hydroxide Solvents: Water; Reflux1.3 Reagents: Hydrochloric Acid Solvents: Water; Acidified
    标题:High H2 Adsorption By Coordination-Framework Materials
    作者:Lin,Xiang; Jia,Junhua; Zhao,Xuebo; Thomas,K. Mark; Blake,Alexander J.; Et Al
    参考文献:Angewandte Chemie 日期:2006 卷标:45(44) 页码:7358-7364]

    110655-53-3 = 921619-89-8
    反应条件:1.1 Reagents: Sodium Hydroxide,Permanganic Acid (Hmno4),Potassium Salt (1:1) Solvents: Tert-Butanol,Water; 2 D,55 °C; 2 W,55 °C1.2 Reagents: Ethanol
    标题:Random Tiling And Topological Defects In A Two-Dimensional Molecular Network
    作者:Blunt,Matthew O.; Russell,James C.; Gimenez-Lopez,Maria Del Carmen; Garrahan,Juan P.; Lin,Xiang; Et Al
    参考文献:Science (Washington 日期:2008 卷标:322(5904) 页码:1077-1081]

    1415325-73-3 = 921619-89-8
    反应条件:1.1 Reagents: Hydrochloric Acid Solvents: Water1.2 Reagents: Sodium Hydroxide Solvents: Water
    标题:808 Nm-Light-Excited Near-Infrared Luminescent Lanthanide Metal-Organic Frameworks For Highly Sensitive Physiological Temperature Sensing
    作者:Zhao,Dian; Han,Xue; Wang,Shuo; Liu,Jingwen; Lu,Yantong; Et Al
    参考文献:Chemistry - A European Journal 日期:2020 卷标:26(14) 页码:3145-3151]

    106-37-6 + 944392-68-1 = 921619-89-8 [标题:Reaction Conditions
    标题:Fluorescent Selectivity For Small Molecules Of Three Zn-Mofs With Different Topologies Based On A Tetracarboxylate Ligand
    作者:Yang,Jie; Zhang,Liangliang; Wang,Xiaoqing; Wang,Rongming; Dai,Fangna; Et Al
    参考文献:Rsc Advances 日期:2015 卷标:5(77) 页码:62982-62988]

    106-37-6 + 932378-94-4 = 921619-89-8
    反应条件:1.1 Reagents: Tripotassium Phosphate Catalysts: Tetrakis(Triphenylphosphine)Palladium Solvents: 1,4-Dioxane; Rt -> 80 °C; 3 D,80 °C1.2 Reagents: Sodium Hydroxide Solvents: Water; Reflux1.3 Reagents: Hydrochloric Acid Solvents: Water; Acidified
    标题:High Capacity Hydrogen Adsorption In Cu(Ii) Tetracarboxylate Framework Materials: The Role Of Pore Size,Ligand Functionalization,And Exposed Metal Sites
    作者:Lin,Xiang; Telepeni,Irvin; Blake,Alexander J.; Dailly,Anne; Brown,Craig M.; Et Al
    参考文献:Journal Of The American Chemical Society 日期:2009 卷标:131(6) 页码:2159-2171
📜5-氨基间苯二甲酸二甲酯置于盐酸,四(三苯基膦)钯,Potassium Acetate,Palladium Diacetate,Cesium Fluoride,Sodium Hydroxide,Sodium Nitrite体系中,用 四氢呋喃,甲醇,乙二醇二甲醚,水,N,N-二甲基甲酰胺 作为反应溶剂,化学反应 73.0H,反应生成 [1,1':4',1'']三联苯-3,3'',5,5''-四甲酸
参考文献:Introduction Of Functionalized Mesopores To Metal-organic Frameworks Via Metal-ligand-fragment Coassembly
标题:Introduction Of Functionalized Mesopores To Metal-organic Frameworks Via Metal-ligand-fragment Coassembly
摘要:Introduction Of Functionalized Mesopores Into Microporous Metal-Organic Frameworks (Mofs) Can Endow Them With Suitable Properties For Applications In Gas Storage,Separation,Catalysis,And Drug Delivery. However,Common Methods For Functionalization (Including Pre-And Post-Synthetic Modifications) Of The Internal Surface Of A Mof Reduce The Pore Size Of The Mof Because The Additional Functional Groups Fill Up The Pores. We Present A Metal-Ligand-Fragment Coassembly Strategy For The Introduction Of (Meso)Pores Functionalized With Various Substituent Groups On The Ligand Fragments. Astonishingly,This New Functionalization Strategy Increases The Pore Volume Of A Mof Instead Of Reducing It. Since The Ligand Fragments Are Often Readily Available Or Easily Prepared,The New Procedure For Synthesis Of The Modified Mofs Becomes Much Easier And More Applicable Than Existing Approaches. Remarkably,Mesopores Can Be Generated Conveniently And Controllably By The Coassembly Of A Ligand And Its Fragment Containing The Desired Functional Groups. The Fragment/ligand Ratio Has Been Optimized To Preserve The Parent Structure And To Promote Maximum Mesopore Introduction,Which Has Led To A Systematic Evaluation Of The Effectiveness Of A Series Of Functional Groups For The Adsorption Of Guest Molecules.
DOI:10.1021/ja3085884

海关参考信息

专利信息


专利号:US-2022297083-A1
优先权日:2019-08-27
标 题 :Continuous Synthesis Of Porous Coordination Polymers In Supercritical Carbon Dioxide
发明人：RASMUSSEN ELIZABETH G; KRAMLICH JOHN C; NOVOSSELOV IGOR V
权利人:UNIV WASHINGTON
摘要:This disclosure relates generally relates to methods and systems useful for continuous synthesis of materials in super-critical carbon dioxide (sCO 2 ). More particularly, this disclosure relates to methods and systems useful for continuous synthesis of coordination polymers, such as metal-organic frameworks (MOFs) and/or covalent organic frameworks (COFs), in sCO 2 .

其他信息查阅

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

实用工具

⚠️全国化工行业净网倡议书
📋制造商识别码
📖 海关编码查询
📝MSDS生成器

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

合成参考文献


参考文献:10.1038/s42004-023-00981-8
摘要:Son FA, Fahy KM, Gaidimas MA, Smoljan CS, Wasson MC, Farha OK. Investigating the mechanical stability of flexible metal-organic frameworks. Commun Chem. 2023 Sep 05;6(1):185.
📝 需求与反馈
尽可能描述清楚需求与问题信息
×

通知