CAS: 683224-96-6; 1-(3-Cyanopropyl)-3-Methyl-1H-Imidazol-3-Ium Chloride

该化合物是一种离子体液体,属于族,其特点是有环烷基侧链,具有很高的热稳定性和低挥发性,适合催化,电化学系统和绿色化学的应用.硝基子的存在增强了其溶解特性,从而改善了极地和非极地基体的溶解性.它具有金枪鱼质物理化学特性,包括粘附性和导性,使它在先进的材料合成中成为多功能溶剂和电解解剂.氯化物还有助于其在有机转化中的再活动.这种离子液体因其在专门化学工艺中的稳定性和适应性而特别受到重视.

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合成工艺路线路线简述

    📜N-甲基咪唑,4-氯丁腈 反应 48.0H,反应生成 1-(3-氰丙基)-3-甲基氯化咪唑鎓
    参考文献:气相色谱法无限稀释的新型室温离子液体中气态和液态溶质的溶解度及其溶解的热力学
    标题:气相色谱法无限稀释的新型室温离子液体中气态和液态溶质的溶解度及其溶解的热力学
    摘要:C 2 H 4和co 2的溶解度以及极性和非极性溶质与新型离子液体(ils)1-丁腈-3-甲基咪唑双(三氟甲基磺酰基)亚氨酸酯(cpmim [ntf 2]),1-丁腈-的相互作用亚甲基2,3-二甲基咪唑鎓双(三氟甲基磺酰基)亚氨酸酯(cpmmim [ntf 2]),1-丁腈-3-甲基咪唑鎓二氰胺(cpmim [n(cn)2]),1-丁腈-2,3-二甲基咪唑鎓二氰胺(cpmmim [N(cn)2]),3-甲基咪唑鎓硬脂酸1-丁酯(bmim [N-C 16 H 33 Coo])和3-甲基咪唑鎓硬脂酸1-丁酯(bmim [N-C 18通过气相色谱法在t =(303.15,313.15,323.15和333.15)k处无限稀释下研究h 35 Coo]).c 2 H 4和co 2气体的亨利定律常数k H,无限稀释活度系数γ∞,溶液δ的摩尔焓溶胶ħ ∞,和溶液δ的偏摩尔焓过量ħ E∞
    DOI:10.1021/je700297C

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    专利信息


    专利号:US-8637695-B2
    优先权日:2011-12-30
    标 题:Synthesis of organohalosilane monomers from conventionally uncleavable Direct Process Residue
    发明人:LEWIS KENRICK MARTIN; NEELY JOHN DAVID
    权利人:LEWIS KENRICK MARTIN; NEELY JOHN DAVID; MOMENTIVE PERFORMANCE MAT INC
    摘要:Disclosed herein is a catalytic process for the synthesis of organohalosilane monomers from tetraorganodihalodisilanes and other compounds that are not cleaved during the conventional hydrochlorination of Direct Process Residue. The process is characterized by the use of a catalyst containing (1) one or more heterocyclic amines and/or one or more heterocyclic ammonium halides, and (2) one or more quaternary Group 15 onium compounds.

    专利号:US-8697901-B2
    优先权日:2011-12-30
    标题 :Synthesis of organohalosilane monomers via enhanced cleavage of direct process residue
    发明人:LEWIS KENRICK MARTIN; NEELY JOHN DAVID
    权利人:LEWIS KENRICK MARTIN; NEELY JOHN DAVID; MOMENTIVE PERFORMANCE MAT INC
    摘要:Discloses herein is a catalytic process for producing organohalosilane monomers from a high-boiling residue resulting from the Direct Reaction of an organohalide with silicon. The high-boiling residue contains more conventionally cleavable compounds than conventionally uncleavable compounds. The process includes heating the residue in the presence of a catalyst comprising (1) one or more heterocyclic amines and/or one or more heterocyclic ammonium halides, and (2) one or more quaternary Group 15 onium compounds.

    专利号:US-2013172593-A1
    优先权日:2011-12-30
    标 题 :Synthesis of Organohalosilane Monomers From Conventionally Uncleavable Direct Process Residue

    专利号:JP-6242343-B2
    优先权日:2011-12-30
    标题 :Synthesis of organohalosilane monomers via enhanced cleavage of direct process residues

    专利号:CN-104144934-B
    优先权日:2011-12-30
    标题:Synthesis of organohalosilane monomers from conventional non-crackable direct process residues

    专利号:EP-2797935-B1
    优先权日:2011-12-30
    标题:Synthesis of organohalosilane monomers via enhanced cleavage of direct process residue

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1021/jp053817t
    摘要:Saha S, Hamaguchi HO. Effect of water on the molecular structure and arrangement of nitrile-functionalized ionic liquids. J Phys Chem B. 2006 Feb 16;110(6):2777–81. doi: 10.1021/jp053817t.
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