CAS: 60532-63-0; 4,4',4'',4'''-Methanetetrayltetraaniline

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60532-62-9 22948-06-7 630-76-2

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CAS号60532-62-9 四(4-硝基苯基)甲烷 | CAS号630-76-2 四苯甲烷 | CAS号76-83-5 三苯基氯甲烷 | CAS号205105-80-2 1-(2-phenylethe... | CAS号53184-78-4 四(4-羟基苯基)甲烷

三苯基甲醇置于盐酸,硫酸,硝酸,乙酸酐,一水合肼,溶剂黄146,亚硝酸异戊酯体系中,用 四氢呋喃,水,N,N-二甲基甲酰胺 作为反应溶剂,化学反应 61.5H,反应生成 4,4,4,4-甲乙烷四基四苯胺
参考文献:锌(II)和镉(II)非晶金属有机框架(amof):温室气体的活化过程和高压吸附研究
标题:锌(II)和镉(II)非晶金属有机框架(amof):温室气体的活化过程和高压吸附研究
摘要:两种新型非晶金属有机框架(amof),其化学成分为{[zn 2 (Mta)].4H2O.3Dmf} N (Upjs-13) 和{[cd 2 (Mta)].5H2O.4Dmf}制备并表征了由 Zn(Ii) 和 Cd(Ii) 离子构建的n (Upjs-14)和延长的四面体四偶氮四甲酸 (H 4 Mta) 作为连接体.在 60,80,100,120,150 和 200 oc 的不同活化温度下对合成态 (As),乙醇交换 (Ex) 和冷冻干燥 (Fd) 材料进行氮吸附测量,以获得最佳质地特性.根据在温和活化温度下活化的冻干材料的氮吸附等温线计算出upjs-13 (Fd)的最大表面积为 830 M 2 G-1,Upjs-14 (Fd)的最大表面积为 1057 M 2 G-1 (80oc).随后,所制备的化合物作为温室气体,二氧化碳和甲烷的吸附剂进行了测试,并在高压下进行了测量.
DOI:10.1039/d1Ra02938J

专利信息

专利号:US-9090742-B2
优先权日:2013-06-28
标 题 :Facile synthesis of metalloporphyrin polymers
发明人：VAIL SEAN; EVANS DAVID
权利人:SHARP LAB OF AMERICA INC
摘要:A method is provided for synthesizing a metal (M) meso-tetraphenylporphyrin polymer. The method begins with the provision of a free-base (H 2 )-meso-tetra-4-(trialkylsilyl)ethynylphenylporphyrin (H 2 -tetra-C≡C-TriAS-TPP) including a trialkylsilyl (TriAS) moiety attached to an ethynyl termini. In response to a reaction with a metal (M)-containing material, the H 2 -tetra-C≡C-TriAS-TPP is converted to a metal (M)-tetra-4-(trialkylsilyl)ethynylphenylporphyrin (M-tetra-C≡C-TriAS-TPP). Then, the M-tetra-C≡C-TriAS-TPP is converted to a M-tetra-4-ethynylphenylporphyrin (M-tetra-C≡C-TPP) monomer by removing the trialkylsilyl (TriAS) moiety from the ethynyl termini. Finally, a plurality of M-tetra-C≡C-TPP monomers are coupled together to supply a metal (M)-meso-tetraphenylporphyrin polymer (M-poly-meso-TPP), whereby meso-phenyl groups of adjacent M-tetra-C≡C-TPP monomers in the M-poly-meso-TPP are connected through a butadiyne linking moiety. In one aspect, the metal is zinc.

专利号:US-2015005463-A1
优先权日:2013-06-28
标 题 :Facile Synthesis of Metalloporphyrin Polymers

专利号:US-11359224-B2
优先权日:2015-10-07
标 题 :Enzyme-immobilized porous membrane and preparation method of antibiotics using the same
发明人：PARK JI-WOONG; SHIN SUNOH
权利人:GWANGJU INST SCIENCE & TECH
摘要:The present disclosure relates to an enzyme-immobilized porous membrane and a preparation method of antibiotics using the same, and more specifically, to an enzyme-immobilized porous membrane prepared by immobilizing a specific enzyme through dead-end filtration, and a preparation method of antibiotics with a high yield using the enzyme-immobilized porous membrane. n According to various exemplary embodiments of the present disclosure, the enzyme capable of promoting the synthesis reaction of the antibiotic substance is able to be stably immobilized in the porous membrane by passing the solution of enzyme through the membrane. n In addition, it is possible to provide antibiotics with a high yield by preparing the antibiotics by passing the reactant solution through the enzyme-immobilized porous membrane.

专利号:WO-2014208407-A1
优先权日:2013-06-28
标题 :Facile synthesis of metalloporphyrin polymers

专利号:CN-104478838-A
优先权日:2014-11-28
标题:A kind of phenylethynyl-containing dianhydride monomer and its synthesis method and application

专利号:CN-108586403-A
优先权日:2018-04-19
标 题:A kind of side chain containing phenylacetylene dianhydride monomer and its synthesis method and application