CAS: 89488-57-3; 1,4-Diiodo-2-Nitrobenzene

该化合物是一种有机化合物,其特点是存在两个碘原子和一个与苯环相连的硝基化合物,该化合物的特点是在香味环1和4位置的2位置和碘替代物上有一个硝基化合物(-NO2),该化合物对其化学特性和反应作用有重大影响.该化合物在室内温度下一般是固体,可能表现出黄色到褐色的颜色.碘原子的存在会增强它的电子生物特性,使它在各种有机合成反应中成为有用的中间体,特别是在其他功能化芳香化合物的准备中.此外,该硝基化合物会助长该化合物的电阻燃性,影响其在核分裂替代反应中的再活动.1,4-Diodo-2-nitrobenzene由于该物质在染料,药品和农用化学品开发中的潜在用途,对材料科学和药用化学也感兴趣.在处理该化合物时,应当采取安全防范措施,因为接触时可能会对健康造成风险.

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上下游产品

2-nitro-1,4-phenylenediamine 3-nitro-4-iodoaniline 4-iodo-2-nitroaniline 2-nitro-aniline 2-nitro-1,4-bis(trimethylsilanylethynyl)benzene 1-nitro-2,5-diethynylbenzene thioacetic acid S-{4-[4-(4-acetylsulfanylphenylethynyl)-2-nitrophenylethynyl]phenyl} ester

合成工艺路线路线简述

  • 20691-72-9 = 89488-57-3
    反应条件:1.1 Reagents: Sulfuric Acid,Potassium Iodide,Nitric Acid Solvents: Water
    标题:New Functionalized Grignard Reagents And Their Applications In Amination Reactions
    作者:Sapountzis,Ioannis
    参考文献:2004]

    20691-72-9 = 89488-57-3
    反应条件:1.1 Reagents: Acetic Acid,Sulfuric Acid Solvents: Water; 0 °C1.2 Reagents: Sodium Nitrite Solvents: Water; 1 H; 0.5 H1.3 Reagents: Potassium Iodide Solvents: Water; 1 H,60 °C; 60 °C -> 0 °C
    标题:Synthesis Of Functionalized Nitroarylmagnesium Halides Via An Iodine-Magnesium Exchange
    作者:Sapountzis,Ioannis; Dube,Henry; Lewis,Robert; Gommermann,Nina; Knochel,Paul
    参考文献:Journal Of Organic Chemistry 日期:2005 卷标:70(7) 页码:2445-2454]

    20691-72-9 = 89488-57-3
    反应条件:1.1 Reagents: Acetic Acid,Sulfuric Acid,Nano 2 Solvents: Water; 1 H,0 °C; 30 Min,0 °C1.2 Reagents: Potassium Iodide Solvents: Water; 0 °C; 1 H,0 °C -> 60 °C; 60 °C -> 0 °C
    标题:Regioselective Iodine/zinc Exchange For The Selective Functionalization Of Polyiodinated Arenes And Heterocycles In Toluene
    作者:Sanchez,Florian; Desaintjean,Alexandre; Danton,Fanny; Knochel,Paul
    参考文献:Synthesis 日期:2021 卷标:53(24) 页码:4662-4671]

    20691-72-9 = 89488-57-3
    反应条件:1.1 Reagents: Nitrosonium Tetrafluoroborate Solvents: Acetonitrile; 30 Min,-40 °C; -40 °C -> 0 °C; 0 °C -> -40 °C1.2 Reagents: Iodine,Sodium Iodide; 30 Min,-40 °C
    标题:Synthesis Of Terphenyl Oligomers As Molecular Electronic Device Candidates
    作者:Maya,Francisco; Tour,James M.
    参考文献:Tetrahedron 日期:2004 卷标:60(1) 页码:81-92
📜4-碘-3-硝基苯胺 反应生成 1,4-二碘-2-硝基苯
参考文献:Koerner; Belasio,Atti Della Accademia Nazionale Dei Lincei,Classe Di Scienze Fisiche,Matematiche E Naturali,Rendiconti,1908,Vol. <5> 17 I,P. 688
标题:Koerner; Belasio,Atti Della Accademia Nazionale Dei Lincei,Classe Di Scienze Fisiche,Matematiche E Naturali,Rendiconti,1908,Vol. <5> 17 I,P. 688

专利信息


专利号:US-8975418-B2
优先权日:2012-09-04
标 题 :Process for preparing 6-iodo-2-oxindole
发明人：SHI WENJIAN; SONG YANLI; BAO YUHUI; LU JUN; HUANG YAO; WEBER DIRK
权利人:SHI WENJIAN; SONG YANLI; BAO YUHUI; LU JUN; HUANG YAO; WEBER DIRK; BOEHRINGER INGELHEIM INT
摘要:Disclosed is a method for the synthesis of 6-iodo-2-oxindole useful as intermediate in the manufacture of pharmaceutically active ingredients. Also disclosed is a novel intermediate used in the synthesis of this compound.

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合成参考文献


参考文献:10.1055/a-1559-3384
摘要:Sanchez F, Desaintjean A, Knochel P, Danton F. Regioselective Iodine/Zinc Exchange for the Selective Functionalization of Polyiodinated Arenes and Heterocycles in Toluene. Synthesis. 2021 Aug 24;53(24):4662–71. doi: 10.1055/a-1559-3384.
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