CAS: 65039-05-6; 1-Butyl-3-Methylimidazolium Iodide

该化合物是一种属于族的离子液体,其特点是熔点低,热稳定性高,该化合物由于极好的离子传导性和金枪鱼物理化学特性,广泛用作各种化学工艺的溶剂,电解剂或催化剂,其碘化阴离子在电化学应用方面提高了其效用,例如染色敏化太阳能电池和电池系统,在这种应用中,有效的电荷转移至关重要.该化合物的疏水性以及与有机和无机材料的兼容性使其成为合成和分析应用的多种选择.由于它的湿质和潜在腐蚀性,建议适当处理.

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174501-64-5 79917-90-1 85100-77-2

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CAS号79917-90-1 氯化(1-丁基-3-甲基咪唑) | CAS号4316-42-1 N-正丁基咪唑 | CAS号74-88-4 碘甲烷 | CAS号616-47-7 N-甲基咪唑 | CAS号542-69-8 碘代正丁烷 | CAS号344790-87-0 1-丁基-3-甲基咪唑硫氰酸盐 | CAS号342789-81-5 1-丁基-3-甲基咪唑甲磺酸盐 | CAS号174501-64-5 1-丁基-3-甲基咪唑六氟磷酸盐 | CAS号174501-65-6 1-丁基-3-甲基咪唑四氟硼酸盐 | CAS号878132-20-8 1-丁基-3-甲基咪唑乳酸盐 | CAS号79917-90-1 氯化(1-丁基-3-甲基咪唑) | CAS号179075-88-8 1-甲基-3-丁基咪唑硝酸盐 | CAS号174899-83-3 1-丁基-3-甲基咪唑鎓双(三... | CAS号262297-13-2 1-甲基-3-丁基咪唑硫酸氢盐 | CAS号284049-75-8 1-丁基-3-甲基咪唑醋酸盐

合成工艺路线路线简述

  • 合成目标产物 1-Butyl-3-Methylimidazolium Iodide 主要起始原料 1-Butylimidazole And Trimethoxymethane
  • (文献来源)合成步骤主要原料 1-Butylimidazole 和 Trimethoxymethane
📜氯化(1-丁基-3-甲基咪唑)置于sodium Iodide体系中,用 乙腈 作为反应溶剂,化学反应 48.0H,以90%的收率获得产物1-丁基-3-甲基碘化咪唑
参考文献:Effects Of Halide Anions To Absorb So2In Ionic Liquids
标题:Effects Of Halide Anions To Absorb So2In Ionic Liquids
摘要:制备了含有卤化物阴离子的离子液体,并研究了卤化物阴离子对离子液体$so_2$溶解度的影响.研究表明,离子液体的$so_2$溶解度在$so_2$/ils 摩尔比 1.91~2.22 之间.$so_2$ 在不同卤化物阴离子的离子液体中的溶解度遵循 Br > Cl > I 的顺序.通过对 $so_2$ 和 [emim]X(其中 X = Cl,Br 和 I)之间相互作用的理论研究,提出了卤化物的主要相互作用发生在咪唑鎓的 $c_2$-H 和 $so_2$ 的 S 上.实验结果进一步表明,$50^{\circ}C$的吸收和$140^{\circ}C$的解吸是可逆的.傅立叶变换红外研究证实了 $so_2$ 吸收的可逆性.
DOI:10.5012/bkcs.2010.31.7.1937

海关参考信息

专利信息


专利号:US-2010191010-A1
优先权日:2007-07-02
标题 :Process for the synthesis of carbamates using co2
发明人:BOSMAN JORIS KAREL PETER; CARR ROBERT HENRY
权利人:HUNTSMAN INT LLC
摘要:Process for the synthesis of non cyclic carbamate derivatives from amine compounds, alcohols and CO 2 in the presence of ionic liquids and optionally in the presence of a base.

专利号:US-9512080-B2
优先权日:2012-07-10
标 题:Synthesis of acridinium compounds by N-alkylation of acridans
发明人:NATRAJAN ANAND; WEN DAVID
权利人:SIEMENS HEALTHCARE DIAGNOSTICS INC
摘要:A method is provided for N-alkylation of acridine compounds by reduction of acridines to corresponding acridans to improve the reactivity of the acridine nitrogen, and subsequent N-alkylation of the acridans in ionic liquid solvents to provide the corresponding acridinium compounds in high yield. This inventive process improves chemical conversion, and does not require the use of highly toxic alkylating agents, such as 1,3-propane sultone.

专利号:US-11053439-B2
优先权日:2019-02-05
标题:Methods for synthesis of inorganic nanostructures using molten salt chemistry
发明人:CURLEY JOHN J; TU ALEXANDER; GUO WENZHOU; WANG CHUNMING; IPPEN CHRISTIAN; HOTZ CHARLES
权利人:NANOSYS INC
摘要:The invention relates to highly luminescent nanostructures with strong blue light absorbance, particularly core/shell nanostructures comprising an In(1-x)GaxP core and ZnSe and/or ZnS shell layers, wherein 0
专利号:WO-2023287345-A1
优先权日:2021-07-16
标 题 :Aqueous solid phase peptide synthesis
发明人:PAWLAS JAN; LUDEMANN-HOMBOURGER OLIVIER
权利人:POLYPEPTIDE LABORATORIES HOLDING PPL AB
摘要:The present invention relates to a solid phase peptide synthesis (SPPS) where the coupling of amino acids is performed in an aqueous solution comprising at least one organic co-solvent miscible with water. The aqueous solution is capable of sufficiently solubilize the activated Fmoc-α-amine protected amino acid or activated Fmoc-α-amine protected peptide fragment, and where the resin is capable of swelling in the presence of the aqueous solution above about 4 mLg-1. The invention also encompasses a method for regeneration of spent aqueous solution from the SPPS.

专利号:US-2008214386-A1
优先权日:2004-03-01
标题:Catalyst for Cyclic Carbonate Synthesis
发明人:TAKAHASHI TOSHIKAZU; WATAHIKI TSUTOMU; YASUDA HIROYUKI; SAKAKURA TOSHIYASU
权利人:TAKAHASHI TOSHIKAZU; WATAHIKI TSUTOMU; YASUDA HIROYUKI; SAKAKURA TOSHIYASU
摘要:Provided are a solid catalyst which gives a cyclic carbonate at a high yield and a high selectivity, which is stable and which may be readily separated after reaction; and a method of industrially advantageous, inexpensive and safe production of a cyclic carbonate by the use of the catalyst. The catalyst contains an inorganic solid substance having a surface modified with an ionic substance containing a Group 15 element; or contains an ionic substance containing a Group 15 element, and an inorganic solid substance. The modifying group for surface modification of an inorganic solid substance is an ionic substance containing a Group 15 element. The ionic substance containing a Group 15 element is at least one substance selected from organic phosphonium salts, organic ammonium salts, organic arsonium salts and organic antimonium salts.

专利号:US-2020325395-A1
优先权日:2019-02-05
标 题 :Methods for synthesis of inorganic nanostructures using molten salt chemistry

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✅ COA系统入驻 | 共享模式

合成参考文献


摘要:Xu, C.; Shao, X.; Shen, Q., Science of Synthesis: Modern Strategies in Organofluorine Chemistry , (2024) 1, 3.
参考文献:10.1007/s11356-019-05684-z
摘要:Guo Y, Lay C, Zhou D, Dong S, Zhang J, Ren N. Enhanced photocatalytic performance of metal silver and carbon dots co-doped BiOI photocatalysts and mechanism investigation. Environmental Science and Pollution Research. 2019 Jun 25;27(15):17516–29. doi: 10.1007/s11356-019-05684-z.
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