专利号:EP-2467369-A1 优先权日:2009-08-19 标题 :Synthesis of c-3 coupled biflavonoids and c-3 coupled biflavonoid analogues
专利号:CN-103360352-A 优先权日:2013-08-05 标 题 :Total Synthesis of 4-methoxy-2,6-dihydroxy-2-benzyl-3(2H)-benzofuranone
专利号:CN-109320488-A 优先权日:2018-11-30 标题 :A kind of water phase one-pot synthesis method of 3-hydroxyflavone and its derivative
专利号:CN-104892388-A 优先权日:2015-06-10 标题:Synthesis method and use of 3-(2,4-dihydroxy-phenyl)-1,5-bis-(2-hydroxy-phenyl)-pentane-1,5-dione
专利号:CN-109320488-B 优先权日:2018-11-30 标题 :A kind of aqueous one-pot synthesis method of 3-hydroxyflavone and derivatives thereof
专利号:US-11358945-B2 优先权日:2018-07-30 标题:Method for preparing cyclopenta[c]chromium compound 发明人:XU FAN; LI DANDAN; DING XIAOYOU; ZHU YANAN; YAO ZHIGANG 权利人:UNIV SOOCHOW 摘要:The present invention discloses a method for preparing a cyclopenta[c]chromene compound. A cationic rare earth compound [Ln(CH)3CN)9]3+[(AlCl4)3]3−.CH3CN is used as a catalyst, and p-methyl thiophenol is used as an accelerator for a catalytic reaction of a chalcone compound so as to prepare a product; and Ln, contained in the catalyst, represents a positive trivalent rare earth metal ion and is selected from one of La, Nd, Sm, Gd and Yb. According to the method, the starting materials are easy to obtain, the reaction process is simple, the catalyst usage is low, the catalyst is universally applicable to various substituted 2-hydroxy chalcones, and the obtained cyclopenta[c]chromene compound has not been reported. The catalyst synthesis method is simple and easy to obtain, and the yield of the target product is high.
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