CAS: 24463-19-2; 9-(Chloromethyl)Anthracene

相似化合物

10387-13-0 2417-77-8 779-02-2

上下游产品

9-hydroxymethylanthracene 9-(phenoxymethyl)anthracene 9-methylanthracene anthracen-9-ylmethylene-hydrazone anthracen-9-yl-acetonitrile Triphenyl-(9-anthracenylmethyl)phosphonium chloride 9-(1',4'-diazacyclohexyl)methylanthracene 9-methylanthracene

📜9-蒽甲醛置于甲醇,Sodium Tetrahydroborate,氯化亚砜体系中,用 二氯甲烷 用作溶剂,化学反应生成9-氯甲基蒽
参考文献:包含高效光诱导电子转移的双荧光基团分子探针,用于通过荧光在部分水介质和生物介质中"关断"响应选择性检测cr 3+和po 4 3-离子:活细胞成像和逻辑应用
标题:包含高效光诱导电子转移的双荧光基团分子探针,用于通过荧光在部分水介质和生物介质中"关断"响应选择性检测cr 3+和po 4 3-离子:活细胞成像和逻辑应用
摘要:本工作描述了一种新的基于光致电子转移(pet)的分子探针,其中萘二甲酰亚胺(npi)和蒽(an)发色团通过点击反应通过哌嗪和三唑单元的分子桥连接在一起.典型的有意义的结构变化使本探针对cr 3+离子具有高度选择性(检测限(lod),5.567x10-8 M),显示出增强的"开启"发射(由于pet-关闭)在tris-Hcl缓冲液中,在干扰和竞争离子的环境中,肉眼可见的亮绿色荧光.通过理论计算(密度泛函理论(dft)和时变(td)-Dft)获得的最小能量结构显示了探针10的"桶"形结构.络合后,哌嗪片段的构象从椅子到船都改变,其中三唑和哌嗪单元形成了一个连接cr 3+的空腔.此外,该探针还具有出色的生物相容性和细胞通透性,可感知cr 3+敏感地存在于活细胞中,因此在生物和环境科学中具有广阔的应用前景.另外,提供两个化学输入(cr 3+和po 4 3-)的探针10灵敏的" Off-On-Off
Doi:10.1021/acs.Analchem.8B02570

专利信息

专利号:US-5434152-A
优先权日:1993-11-08
标题:Asymmetric synthesis of (S)-(-)-6-chloro-4- cyclopropyl-3,4-dihydro-4-[(2-pyridyl)ethynyl]-2(1H)-quinazolinone
发明人：HUFFMAN MARK A; YASUDA NOBUYOSHI; DECAMP ANN E; GRABOWSKI EDWARD J J
权利人:MERCK & CO INC
摘要:An asymmetric synthesis of (S)-(-)-6-chloro-4-cyclopropyl-3,4-dihydro-4-[(2-pyridyl)ethynyl]-2(1H)-quinazolinone comprises the chiral addition of 2-pyridylacetylide to N 1 -protected 6-chloro-4-cyclopropyl-2-quinazolinone followed by removal of the protecting group.

专利号:US-2023220381-A1
优先权日:2020-06-30
标 题 :Dna-encoded functionalized aptamers
发明人：SLEIMAN HANADI; LACROIX DE VIMEUR DE ROCHAME DONATIEN PHILIPPE MARIE; MCKEAGUE MAUREEN; HIRKA SERHII; SALIBA DANIEL; ANDERSON SHAUN IAN
权利人:THE ROYAL INSTITUTION FOR THE ADVANCEMENT OF LEARNING / MCGILL UNIV
摘要:It is provided the synthesis of an aptamer-like encoded oligomer (ALEnOmer), method of producing same and method of preparing a library of ALEnOmes. More particularly, the method of preparing ALEnOmer comprises coupling at least one phosphoramidite monomer with an orthogonal protecting group, and the ALEnOmer produces comprises a DNA coding strand covalently attached to an oligomer through a branching unit, wherein the oligomer has a degree of polymerization at least 5 and is an aptamer.

专利号:US-8193392-B2
优先权日:2005-07-29
标 题:Method for enantioselective synthesis of phosphorus-stereogenic phosphines
发明人：SCRIBAN CORINA; GLUECK DAVID S
权利人:SCRIBAN CORINA; GLUECK DAVID S; DARTMOUTH COLLEGE
摘要:The present invention relates to a process for preparing an enantioenriched phosphorus-stereogenic, tertiary phosphine. Secondary phosphines are contacted with an alkyl halide and base in the presence of a chiral metal catalyst thereby producing the enantioenriched phosphorus-stereogenic, tertiary phosphine for subsequent use in homogeneous catalysis reactions.

专利号:US-2004082796-A1
优先权日:2002-05-15
标 题 :Synthesis of substituted thiazoline carboxylic acids

专利号:US-2003236404-A1
优先权日:2002-05-15
标题 :Synthesis of 2-alkylcysteine via phase transfer catalysis

专利号:US-2006281926-A1
优先权日:2002-05-15
标 题:Synthesis of 2-alkylcysteine via phase transfer catalysis