CAS: 22499-12-3; 2-Isobutoxy-1,2-Diphenylethanone

该化合物是紫外线可保证涂层,墨水和粘合剂中常用的光聚合剂,在紫外线-A射程(320-390纳米)中表现出很强的吸收作用,使其对需要长波启动的应用具有效力;该化合物在有机溶剂和单体中提供极好的溶解性,确保同质配方融合;其光分解分解能高效生成自由基质,促进快速治愈和增强胶片特性;Benzoin异丁基醚因其在储存条件下的稳定性和低挥发性而得到估价,从而尽量减少配方的不一致性;该化合物特别适合由于其有利的渗透特性而需要深固化或厚层应用的系统;该产品需要在适当的光度条件下进行处理,以防止过早引爆.

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CAS号27962-50-1 2-(2-methylprop...

合成工艺路线路线简述

    Isobutylmagnesium Bromide,联苯甲酰,氯化铵,水 以30%的收率获得
    参考文献:Holm T.,Acta Chem. Scand.,41,(1987) N 4,278-284
    标题:Holm T.,Acta Chem. Scand.,41,(1987) N 4,278-284

    海关参考信息

    专利信息


    专利号:US-9969823-B1
    优先权日:2011-09-01
    标题 :Synthesis and polymerization of vinyl triazolium ionic liquids
    发明人:LUEBKE DAVID; NULWALA HUNAID; MATYJASZEWSKI KRZYSZTOF; ADZIMA BRIAN
    权利人:US ENERGY; THE US DEPARTMENT OF ENERGY
    摘要:Herein, we describe polymerized ionic liquids, demonstrate the synthesis of polymerized ionic liquids, and demonstrate the polymerization of triazolium monomers. One embodiment shows the polymeriazation of the triazolium monomers with bis(trifluoromethanesulfonyl)imide anions. In another embodiment we show the feasibility of copolymerizing with commodity monomers such as styrene using free radical polymerization techniques.

    专利号:EP-4428168-A1
    优先权日:2023-03-08
    标 题 :Polyurethane/oligomeric urethane synthesis method by radiation
    发明人:AKBULUT HÜSEYIN; ÇEL KBA SENA; ENADA SEHER; U AKLI MÜGE; DEM RBAY DUYGU
    权利人:CHT TURKEY KIMYA SANAYI VE TICARET A S
    摘要:In particular, the invention relates to the synthesis of radiation-curable polyurethane/oligomeric urethane dispersions of anionic and cationic characters, containing neutralization techniques characterized by the selection of counter ions as monomers and/or agents which can be polymers acting as promoters under radiation, to a radiation polyurethane/oligomeric urethane synthesis method that enables the creation of radiation curable binder systems without using cosolvents, surfactants, emulsifiers, defoamers, stabilizers and additives, wherein all components of the radiation-curable binder systems can be polymerized.

    专利号:US-9175026-B2
    优先权日:2011-03-23
    标题:Synthesis of thioether containing trialkoxysilanes
    发明人:GARRELL ROBIN L; TUCKER-SCHWARTZ ALEXANDER K
    权利人:GARRELL ROBIN L; TUCKER-SCHWARTZ ALEXANDER K; UNIV CALIFORNIA
    摘要:The invention relates to a radical-initiated thiol-ene or thiol-yne “clickâ€? reaction that provides a simple and efficient route to diverse trialkoxysilanes. Trialkoxysilanes made in this way are obtained in quantitative to near-quantitative yields with high purity without any or minimal purification. A wide range of functional groups is tolerated in this approach, and even complex alkenes click with the silane precursors. The modular nature of these radical-based thiol-ene or thiol-yne “clickâ€? reactions allows a wide variety of pendant groups to be coupled to silane compounds that can then be coupled to a wide variety surfaces in order to modify their material properties. Consequently, such radical initiated thiol-ene and thiol-yne reactions provide facile and efficient methods for preparing an enormous number of surface-active functional trialkoxysilanes.

    专利号:US-12220860-B2
    优先权日:2019-03-25
    标题 :Synthesis and 3D printing of photocurable colloids
    发明人:LONG TIMOTHY E; MEENAKSHISUNDARAM VISWANATH; SCOTT PHILIP J; WILLIAMS CHRISTOPHER B
    权利人:VIRGINIA TECH INTELLECTUAL PROPERTIES INC
    摘要:Photocurable colloid binders are provided that overcome deficiencies associated with 3D printing of high molecular weight polymers via VAT photopolymerization. Methods of additive manufacturing are also provided using the binders. The approaches described herein effectively decouple the viscosity-molecular weight relationship by synthesizing and processing photo-reactive aqueous colloids that are sequestered within a photocrosslinkable scaffold. Sequestering polymers within discrete internal phases prevents inter-particle entanglement of the polymer chains, thus ensuring low viscosity. VP of polymer colloids results in a solid green body embedded with high molecular weight polymer particles. A post-processing heated drying step allows the polymers to coalesce and further entangle, forming a semi-interpenetrating network with mechanical performance of the high molecular weight material. The resins can further include inorganic particles such as silica and other ceramics, metal particles, and the like. The coalescence can result in the particles being encapsulated in polymer, yielding unique hybrid materials with tunable properties.

    专利号:US-2009227701-A1
    优先权日:2004-08-19
    标题:Water-soluble, radiation-curable products and use thereof
    发明人:KRUEGER CHRISTIAN; BRUCHMANN BERND; HEES ULRIKE; KLUGE MICHAEL; DIELEMAN CEDRIC; WEISER JUERGEN
    权利人:BASF AG
    摘要:Water soluble radiation curable products (A) obtainable by mixingn mixing with or without reaction of at least one hyperbranched polyurethane (a) with at least one photoinitiator (b) or by synthesis of at least one hyperbranched polyurethane (a) in the presence of at least one photoinitiator (b),n nare used to produce aqueous inks for the ink jet process.

    专利号:WO-9325300-A1
    优先权日:1992-06-05
    标 题:Ultrathin composite membranes
    发明人:MARTIN CHARLES R; LIU CHAO
    权利人:RES CORP TECHNOLOGIES INC; MARTIN CHARLES R; LIU CHAO
    摘要:The present invention relates to a method of forming defect-free ultrathin film composite membranes by the photochemical synthesis of an ultrathin polymer film on the surface of a microporous support membrane. In one particular embodiment, the method entails placing a support membrane on a filter paper which is saturated with a solution of the desired monomer(s). The solution then wicks to the top of the membrane, covering the surface with a thin solution film, where it is subjected to irradiation by ultraviolet (UV) light to initiate the polymerization of the ultrathin polymer film. The rate of polymerization can be enhanced by adding a photoinitiator to the gas phase above the membrane or into solution with the monomer or monomers to induce radical polymerization. The method results in a defect-free ultrathin composite membrane. In addition, to minimize photon penetration depth and confine the polymerization predominantly to the membrane surface, the incident at which the UV light strikes the membrane surface is kept at an acute angle. The ultrathin film composite membranes can be used in a vast number of chemical separation processes, bioreactors and sensors, energy conversion and drug delivery systems.
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    合成参考文献


    参考文献:10.1007/bf02542557
    摘要:Fukui S. Conversions of lipophilic substances by encapsulated biocatalysts. J Americ Oil Chem Soc. 1988 Jan;65(1):96–100. doi: 10.1007/bf02542557.
    参考文献:10.1007/s12034-023-02991-7
    摘要:LI P, ZOU G, CHANG L, GUO W, TIAN K, LI X, WANG H. UV-stimulated self-healing SiO2/CeO2 microcapsule with excellent UV-blocking capability in epoxy coating. Bull Mater Sci. 2023 Jul 27;46(3). doi: 10.1007/s12034-023-02991-7.
    参考文献:10.1007/978-981-19-9048-9_6
    摘要:Sharma BK, Singh M, Lokhandwala S, Wagh S, Chowdhury SR, Ray S. Radiation Processed Emerging Materials for Biomedical Applications. 2023. In: Materials Horizons: From Nature to Nanomaterials.
    参考文献:10.1007/s10965-023-03590-0
    摘要:Parihar S, Gaur B. Self healing approaches in polymeric materials-an overview. J Polym Res. 2023 May 20;30(6). doi: 10.1007/s10965-023-03590-0.
    参考文献:10.1007/978-981-99-8826-6_6
    摘要:Bhattacharjee S, Harithasree V, Mourya A, Babu CK, Bahuguna D, Devangan P, Sainaga Jyothi VGS, Shetiya A, Jain AK, Singh SB, Madan J. Hyaluronic Acid Hydrogel in Therapeutics Delivery and Biomedical Applications. 2024. In: Biomaterial-based Hydrogels.
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