CAS: 81446-29-9; 4,4'-((1R,3As,4R,6As)-Tetrahydro-1H,3H-Furo[3,4-C]Furan-1,4-Diyl)Bis(2-Methoxyphenol)

该化合物是各种植物种中自然产生的离子体,包括福赛西亚苏斯本萨和芝麻种子,它显示出显著的生物活动,如抗氧化剂,抗炎和潜在的抗癌特性,使它成为药物和营养学研究的复合体,它的体质结构和立体特性有助于它与生物目标有选择地相互作用. (-)-聚氨酯醇也是其他褐色生物合成的先兆,强调它在合成化学和药用化学中的重要性. 高纯度(-)聚氨醇可用于研究应用,确保研究其机制和治疗潜力的再生性,其稳定性和特性有助于它在分析和生物化学实验中使用.

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上下游产品

Diacetate of (+)-epipinoresinol Versicoside pinoresinol (1R,2R,5R,6S)-2-(4-methanesulfonyloxy-3-methoxy)phenyl-6-(4-methanesulfonyloxy-3-methoxy)phenyl-3,7-dioxabicyclo[3.3.0]°Ctane R)-4c-(4-hydroxy-3-methoxy-phenyl)-(3ar,6ac)-tetrahydro-furo[3,4-c]furan-1c-yl]-3,3'-dimethoxy-biphenyl-2,2'-diol5,5'-Bis-[(3aR)-4c-(4-hydroxy-3-methoxy-phenyl)-(3ar,6ac)-tetrahydro-furo[3,4-c]furan-1c-yl]-3,3'-dimethoxy-biphenyl-2,2'-diol Diacetate of (+)-epipinoresinol (+)-eudesmin eudesmin

合成工艺路线路线简述

  • 32811-40-8 = 81446-29-9
    反应条件:1.1 Reagents: Oxygen Catalysts: Laccase Solvents: Ethanol,Water; Ph 5,Rt; 1 H,Rt1.2 Reagents: Hydrochloric Acid Solvents: Water; Acidified
    标题:An Enantiocomplementary Dirigent Protein For The Enantioselective Laccase-Catalyzed Oxidative Coupling Of Phenols
    作者:Pickel,Benjamin; Et Al
    参考文献:Angewandte Chemie 日期:2010 卷标:49(1) 页码:202-204]

    38759-91-0 = 81446-29-9 + 95404-51-6
    反应条件:1.1 Reagents: Glucose,Sucrose,Potassium Chloride,Sulfuric Acid Magnesium Salt (1:1),Ferrous Sulfate,Dipotassium Phosphate Solvents: Dimethyl Sulfoxide,Water; 72 H,25 °C
    标题:Enantioselective Accumulation Of (-)-Pinoresinol Through O-Demethylation Of (+/-)-Eudesmin By Aspergillus Niger
    作者:Kasahara,Hiroyuki; Et Al
    参考文献:Phytochemistry 日期:1997 卷标:44(8) 页码:1479-1482]

    487-36-5 = 81446-29-9 + 95404-51-6
    反应条件:1.1 24 H,Rt2.1 Reagents: Glucose,Sucrose,Potassium Chloride,Sulfuric Acid Magnesium Salt (1:1),Ferrous Sulfate,Dipotassium Phosphate Solvents: Dimethyl Sulfoxide,Water; 72 H,25 °C
    标题:Enantioselective Accumulation Of (-)-Pinoresinol Through O-Demethylation Of (+/-)-Eudesmin By Aspergillus Niger
    作者:Kasahara,Hiroyuki; Et Al
    参考文献:Phytochemistry 日期:1997 卷标:44(8) 页码:1479-1482]

    458-35-5 = 81446-29-9 + 27003-73-2 + 83327-19-9 + 29388-59-8 + 487-36-5
    反应条件:1.1 Reagents: Nadph,Hydrogen Peroxide Solvents: Water; 1 H,Ph 7,30 °C
    标题:Enantioselective Lignan Synthesis By Cell-Free Extracts Of Forsythia Koreana
    作者:Umezawa,Toshiaki; Et Al
    参考文献:Bioscience 日期:1994 卷标:58(2) 页码:230-4]

    526-06-7 = 81446-29-9
    反应条件:1.1 Reagents: Glucose,Sucrose,Potassium Chloride,Sulfuric Acid Magnesium Salt (1:1),Ferrous Sulfate,Dipotassium Phosphate Solvents: Dimethyl Sulfoxide,Water; 72 H,25 °C
    标题:Enantioselective Accumulation Of (-)-Pinoresinol Through O-Demethylation Of (+/-)-Eudesmin By Aspergillus Niger
    作者:Kasahara,Hiroyuki; Et Al
    参考文献:Phytochemistry 日期:1997 卷标:44(8) 页码:1479-1482]

    28028-62-8 = 81446-29-9
    反应条件:1.1 Reagents: Diisobutylaluminum Hydride Solvents: Toluene; 40 Min,0 °C; 1 H,0 °C2.1 Reagents: Oxygen Catalysts: Laccase Solvents: Ethanol,Water; Ph 5,Rt; 1 H,Rt2.2 Reagents: Hydrochloric Acid Solvents: Water; Acidified
    标题:An Enantiocomplementary Dirigent Protein For The Enantioselective Laccase-Catalyzed Oxidative Coupling Of Phenols
    作者:Pickel,Benjamin; Et Al
    参考文献:Angewandte Chemie 日期:2010 卷标:49(1) 页码:202-204]

    537-98-4 = 81446-29-9
    反应条件:1.1 Reagents: Acetyl Chloride Solvents: Ethanol; 0 °C; 2 D,Rt2.1 Reagents: Diisobutylaluminum Hydride Solvents: Toluene; 40 Min,0 °C; 1 H,0 °C3.1 Reagents: Oxygen Catalysts: Laccase Solvents: Ethanol,Water; Ph 5,Rt; 1 H,Rt3.2 Reagents: Hydrochloric Acid Solvents: Water; Acidified
    标题:An Enantiocomplementary Dirigent Protein For The Enantioselective Laccase-Catalyzed Oxidative Coupling Of Phenols
    作者:Pickel,Benjamin; Et Al
    参考文献:Angewandte Chemie 日期:2010 卷标:49(1) 页码:202-204]

    23397-46-8 = 81446-29-9 + 95404-51-6
    反应条件:1.1 Reagents: Glucose,Sucrose,Potassium Chloride,Sulfuric Acid Magnesium Salt (1:1),Ferrous Sulfate,Dipotassium Phosphate Solvents: Dimethyl Sulfoxide,Water; 72 H,25 °C
    标题:Enantioselective Accumulation Of (-)-Pinoresinol Through O-Demethylation Of (+/-)-Eudesmin By Aspergillus Niger
    作者:Kasahara,Hiroyuki; Et Al
    参考文献:Phytochemistry 日期:1997 卷标:44(8) 页码:1479-1482]

    32811-40-8 = 81446-29-9 + 487-36-5
    反应条件:1.1 Reagents: Oxygen; 2 H,Ph 4.5,45 °C
    标题:Laccase Catalyses Phytophenol Furanocyclic Dimerization: Substrate Specificity And Diastereoselective Process
    作者:Li,Xican; Et Al
    参考文献:Journal Of Molecular Structure 日期:2023 卷标:1274]

    = 81446-29-9 + 95404-51-6
    反应条件:1.1 Reagents: Hydrochloric Acid Solvents: Diethyl Ether; 3 H,Rt2.1 Reagents: Glucose,Sucrose,Potassium Chloride,Sulfuric Acid Magnesium Salt (1:1),Ferrous Sulfate,Dipotassium Phosphate Solvents: Dimethyl Sulfoxide,Water; 72 H,25 °C
    标题:Enantioselective Accumulation Of (-)-Pinoresinol Through O-Demethylation Of (+/-)-Eudesmin By Aspergillus Niger
    作者:Kasahara,Hiroyuki; Et Al
    参考文献:Phytochemistry 日期:1997 卷标:44(8) 页码:1479-1482
📜松柏醇置于双氧水,Horseradish Peroxidase体系中,用 甲醇 作为反应溶剂,化学反应 1.0H,反应生成 (-)-松脂酚
参考文献:植物酚二聚反应:从基本规则到非对映选择性及其他
标题:植物酚二聚反应:从基本规则到非对映选择性及其他
摘要:植物酚二聚化是一种自由基介导的偶联反应,在包括木质素生物合成在内的许多领域发挥着关键作用.为了了解该反应,使用 2,2-二苯基-1-苦基肼自由基在甲醇中引发一系列植物酚二聚反应.使用超高效液相色谱结合电喷雾四极杆飞行时间串联质谱 (UHPLC-Esi-Q-Tof-Ms/ms) 原位分析对产物进行鉴定.鉴定出的产品主要有联苯酚,厚朴酚,和厚朴酚,姜酚6,6'-二聚体,3,6-二甲氧基儿茶酚β,β'二聚体,大戟红素,双丁香酚,脱氢二异丁香酚,反式-ε-葡萄素,(+)松脂醇,(-) 松脂醇.结构-功能关系分析允许定义四个基本规则:间位排除,C-C 键合优势,邻-Dioh 共激活和环外 C=c 参与.然而,环外 C=c 的参与需要与酚核心和对位共轭.-Oh 基团的-位点,产生具有两个手性中心的呋喃稠合二聚体.计算化学表明,整个过程是通过自由基偶联反应和分子内共轭加成反应完成的.对于辣根过氧化物酶
DOI:10.3390/molecules27154842

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参考文献:10.1080/14786410802253197
摘要:Dong L, Chen C, Ni W, Xie B, Li J, Liu H. A new dinorclerone diterpenoid glycoside fromTinospora sinensis. Natural Product Research. 2010 Jan 10;24(1):13–7. doi: 10.1080/14786410802253197.
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