📜甘油,己酸置于glucose-Diphenylaminium Tosylate-Derived Carbon Solid Acid (Gdtcsa)体系中,用 正庚烷 作为反应溶剂,化学反应 18.0H,以93%的收率获得产物三己精 参考文献:The Carbon Material Functionalized With Nh2+ And So3H Groups Catalyzed Esterification With High Activity And Selectivity 标题:The Carbon Material Functionalized With Nh2+ And So3H Groups Catalyzed Esterification With High Activity And Selectivity 摘要:一个新型碳材料被方便地制备出来,可以催化酯化反应,具有高反应活性和选择性. DOI:10.1039/c4Gc01395F
专利号:US-5434278-A 优先权日:1989-09-20 标题:Synthesis of acetoglyceride fats 发明人:PELLOSO TURIDDU A; RODEN ALLAN D; BOLDT GILBERT L 权利人:NABISCO INC 摘要:Acetoglycerides are prepared in a solventless, single phase interesterification between triacetin and triglycerides bearing long C 16 to C 22 fatty acid residues by adding triglycerides bearing saturated C 3 to C 10 acid residues to the reaction mixture. The long acid residues may be hydrogenated before or after interesterification. In one embodiment, the C 3 to C 10 triglycerides are tripropionin, tributyrin, or mixtures of these; in another, these are triglycerides bearing C 8 to C 10 acid residues; and in a third, these are a mixture of tripropionin and/or tributyrin and C 8 to C 10 triglycerides. In preferred embodiments, the molar ratio of C 16 to C 22 triglycerides to triacetin and C 3 to C 10 triglycerides varies between 1:1 and 1:15, more narrowly between 1:3 and 1:12, and high temperatures are employed. The process diminishes catalyst use, obviates the need for high shear mixing, shortens reaction times, and simplifies purification steps.
专利号:EP-0682689-A4 优先权日:1993-02-03 标 题 :SYNTHESIS OF ACETOGLYCERIDE FATS.
专利号:EP-0682689-A1 优先权日:1993-02-03 标 题 :Synthesis of acetoglyceride fats
专利号:WO-9418290-A1 优先权日:1993-02-03 标 题:Synthesis of acetoglyceride fats
专利号:US-5391494-A 优先权日:1988-12-09 标题 :Process for selectively producing optically active 1-derivatized-2-diol using lipase CES and triglyceride 发明人:MIYAZAWA KAZUTOSHI; YOSHIDA NAOYUKI 权利人:CHISSO CORP 摘要:This invention provides optically active compounds which are starting materials of physiologically active substances, functional materials and the like, and the compounds are represented by the general formula (I): (I) wherein R1 is hydrogen or alkanoyl of 2-20 carbon atoms, R2 is alkyl of 1-40 carbon atoms, alkenyl of 1-40 carbon atoms, or alkynyl of 1-40 carbon atoms in which the alkyl, alkenyl or alkynyl moiety is possible to have phenyl, cyclohexyl, pyridyl, pyrimidyl, pyridadyl, pyrazyl, dioxyl, bicyclooctyl, or a substituent thereof, or halogen, cyanogen, oxygen, nitrogen, silicon or sulfur, and X is a protective group removable by a chemical method of organic synthesis and C* is an asymmetric carbon.
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合成参考文献
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