CAS: 5598-13-0; Chlorpyrifos Methyl

该化合物是有机磷杀虫剂,主要用于农业用途,以控制各种害虫;无色的黄色液体,具有一种特殊的气味;这种复合功能,抑制了酶乙酰胆碱酯酶,导致昆虫...

结构式图片

相似化合物

55335-06-3 31557-34-3 37439-34-2

欧盟法规

《欧盟PIC法规》统一分类与标签"欧盟管控危险化学品"ECHA物质欧盟农药活性物质工作场所安全标识要求ECHA物质C&L通报OtherREACH预注册废弃物危险特性清单

上下游产品

CAS号6515-38-4 3,5,6-三氯-2-吡啶酚 | CAS号1112-38-5 O,O-二甲基氢硫代磷酸酯 | CAS号6515-38-4 3,5,6-三氯-2-吡啶酚 | CAS号1112-38-5 O,O-二甲基氢硫代磷酸酯 | CAS号5598-52-7 福司吡酯

合成工艺路线路线简述

  • 合成目标产物 Chlorpyrifos-Methyl 主要起始原料 3,5,6-Trichloro-2-Pyridinol And 0,0-Dimethyl Thiophosphate
  • (文献来源)合成步骤主要原料 3,5,6-Trichloro-2-Pyridinol 和 0,0-Dimethyl Thiophosphate
📜二甲基硫代磷酰氯,Sodium 3,5,6-Trichloropyridin-2-Olate置于4-二甲氨基吡啶,苄基三乙基氯化铵,Sodium Dodecyl Sulfate,Potassium Carbonate体系中,用 水 作为反应溶剂,化学反应 2.5H,以93.4%的收率获得产物甲基毒死蜱
参考文献:O,O-二烷基硫代氯代磷酸酯在水溶剂中酰化杂环醇阴离子的研究
标题:O,O-二烷基硫代氯代磷酸酯在水溶剂中酰化杂环醇阴离子的研究
摘要:摘要 研究了一些杂环醇阴离子与 O,O-二烷基硫代磷酸氯酯的酰化反应.通过使用有效的相转移催化剂 (Ptc)(苄基三乙基氯化铵 [bteac]),酰化催化剂 (Ac)(4-二甲氨基吡啶)和表面活性剂(十二烷基硫酸钠),在 50 oc 的水中获得更高的产率和更少的副产物),在弱碱性(ph 9.5∼10)条件下.该反应也可用于合成其他高产率的杀虫剂.图形概要
DOI:10.1080/10426507.2012.702824

海关参考信息

专利信息


专利号:WO-2025056767-A1
优先权日:2023-09-15
标题 :Process for the preparation of enantiomerically enriched aliphatic amines
发明人:BOU HAMDAN FARHAN; GODINEAU EDOUARD; SMEJKAL TOMAS; DUMEUNIER RAPHAEL; BOUSSEMGHOUNE MOHAMED ABDELOUAHAB; BLUM MATHIAS
权利人:SYNGENTA CROP PROTECTION AG
摘要:The present invention relates to a process for the preparation of enantiomerically enriched cyclobutylamines of formula (I) from α-tertiary cyclobutanones and reacting said enantiomerically enriched cyclobutylamines to enantiomerically enriched cyclobutylamides. Such compounds are useful intermediates in the synthesis of microbiocidal thiazole compounds.

专利号:US-9468207-B2
优先权日:2012-04-12
标 题 :Insecticide and acaricide paints that inhibit chitin synthesis, regulate insect juvenile hormone and repel arthropods, for controlling endemic diseases, pests and allergens
发明人:MATEO HERRERO MARIA PILAR
权利人:MATEO HERRERO MARIA PILAR
摘要:The present invention relates to insecticide and acaricide paints that inhibit chitin synthesis, regulate insect juvenile hormone and repel arthropods, for controlling endemic diseases, pests and allergens. The paints comprise at least the following compounds (in any combination): 1%-100% water, 0.0001%-20% insecticides, 0.0001%-20% chitin inhibitor, 0.0001%-20% juvenile hormone regulator, 1%-50% polymers, 0%-40% pigments, 0%-60% fillers, 0%-60% natural repellents, and 0.01%-20% stabilizers. The composition of the paints allows the active ingredients to be encapsulated in an aqueous polymer with or without the incorporation of fillers and pigments, and therefore the range of use thereof is increased.

专利号:US-2007232495-A1
优先权日:2006-03-24
标题:Compositions and methods to add value to plant products, increasing the commercial quality, resistance to external factors and polyphenol content thereof
发明人:NAPPA ALVARO O; LORENZINI FELIPE C; SANHUEZA ANDRES L
权利人:NAPPA ALVARO O; LORENZINI FELIPE C; SANHUEZA ANDRES L
摘要:The invention is related to compositions and methods that naturally protect plant tissues against ultraviolet radiation and temperature, thus giving protection against sunburn to plants, plant parts, fruits and/or flowers during their development. The invention is also related to compositions and methods to naturally improve the color of plants, plant parts, fruits and/or flowers by inducing the natural synthesis of flavonoids and anthocyanins present in plants. Likewise, the present invention is directed to improving the nutritional value of plants, plant parts, fruits and/or flowers by increasing the normal levels of polyphenolic compounds, especially flavonoids, present therein. Additionally, the present invention is related to compositions and methods that give more resistance to plants, plant parts, fruits and/or flowers against pathogens as bacteria and fungi. Finally, the present invention is related to plants, plant parts, fruits, flowers and/or propagating material treated with the compositions described in the present document.

专利号:US-2011230343-A1
优先权日:2008-10-24
标题 :Method for the Manufacture of Microparticles Comprising an Effect Substance
发明人:SCHROERS MICHAEL; DYLLICK-BRENZINGER RAINER; MERK MICHAEL; BARG HEIKO
权利人:BASF SE
摘要:A subject matter of the present invention is a process for the preparation of effect compound-comprising microparticles M comprising A) the formation of a crude suspension of microparticles A by means of enzymatic polyester synthesis in an inverse miniemulsion comprising enzyme, effect compound and polyester monomers; and B) the polymerization of wall monomers from the group consisting of ethylenically unsaturated monomers, polyisocyanates and polyepoxides in the crude suspension of microparticles A. Furthermore, the present invention relates to microparticles M which can be obtained by means of the process according to the invention and also to an agrochemical formulation comprising microparticles M. In addition, the present invention relates to the use of microparticles M prepared according to the invention as component in colorants, cosmetics, drugs, biocides, plant protection agents, fertilizers, additives for food or animal fodder, or auxiliaries for polymers, paper, textiles, leather, detergents or cleaners. Finally, the invention also relates to a method for combating undesirable plant growth, to a method for combating undesirable insect or acarid infestation on plants and/or for combating phytopathogenic fungi, and to seeds treated with the agrochemical formulation.

专利号:US-8937089-B2
优先权日:2004-07-01
标 题:Synergistic mixtures of anthranilamide invertebrate pest control agents
发明人:ANNAN ISAAC BILLY; FLEXNER JOHN LINDSEY; PORTILLO HECTOR EDUARDO; LAHM GEORGE PHILIP; SELBY THOMAS PAUL; STEVENSON THOMAS MARTIN
权利人:ANNAN ISAAC BILLY; FLEXNER JOHN LINDSEY; PORTILLO HECTOR EDUARDO; LAHM GEORGE PHILIP; SELBY THOMAS PAUL; STEVENSON THOMAS MARTIN; DU PONT
摘要:Disclosed are mixtures and compositions for controlling invertebrate pests relating to combinations comprising (a) 3-bromo-N-[4-chloro-2-methyl-6-[(methylamino)carbonyl]phenyl]-1-(3-chloro-2-pyridinyl)-1H-pyrazole-5-carboxamide, and its N-oxides, and suitable salts thereof n n n n n n n n n n n n andn na component (b) wherein the component (b) is at least one compound or agent selected from neonicotinoids, cholinesterase inhibitors, sodium channel modulators, chitin synthesis inhibitors, ecdysone agonists, lipid biosynthesis inhibitors, macrocyclic lactones, GABA-regulated chloride channel blockers, juvenile hormone mimics, ryanodine receptor ligands, octopamine receptor ligands, mitochondrial electron transport inhibitors, nereistoxin analogs, pyridalyl, flonicamid, pymetrozine, dieldrin, metaflumizone, biological agents, and suitable salts of the foregoing.n n n n n n Also disclosed are methods for controlling an invertebrate pest comprising contacting the invertebrate pest or its environment with a biologically effective amount of a mixture or composition of the invention.

专利号:US-11213031-B2
优先权日:2017-11-13
标 题:Tetrazolylpropyl derivatives and their use as fungicides
发明人:SUDAU ALEXANDER; HOFFMANN SEBASTIAN; DAHMEN PETER; WEBSTER ROBERT ALAN; MEISSNER RUTH; GOERTZ ANDREAS; MILLER RICARDA; COQUERON PIERRE-YVES; BERNIER DAVID; NICOLAS LIONEL; BRUNET STEPHANE; KENNEL PHILIPPE; TOQUIN VALERIE; GOURGUES MATHIEU; LOQUE DOMINIQUE; THOMAS VINCENT
权利人:BAYER AG; BAYER CROPSCIENCE AG
摘要:The present invention relates to tetrazolylpropyl derivatives of formula (I) n nwherein one of V 1 and V 2 represents CR 3 and the other one of V 1 and V 2 represents N, Q represents a 6-membered aromatic cycle as defined in the specification, and R 1 , R 2 , R 3 , R 4 , and R 5 are defined as disclosed in the specification, to compositions comprising such compounds, to the use of said compounds as fungicides, as well as to particular intermediates useful in the synthesis of said tetrazolylpropyl derivatives.

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

主要参考文献


1: Ma JK, Huang XC, Wei SL. Preparation and application of chlorpyrifos molecularly imprinted solid-phase microextraction probes for the residual determination of organophosphorous pesticides in fresh and dry foods. J Sep Sci. 2018 Aug;41(15):3152-3162. doi: 10.1002/jssc.201800385. Epub 2018 Jul 3. doi: 10.1007/s00216-018-0986-x. Epub 2018 Mar 17. doi: 10.1002/ps.4881. Epub 2018 Mar 7. doi: 10.1016/j.legalmed.2017.10.002. Epub 2017 Oct 4. doi: 10.1016/j.saa.2017.10.030. Epub 2017 Oct 10. doi: 10.1016/j.fct.2017.07.060. Epub 2017 Aug 2. pii: E833. doi: 10.3390/ijerph14080833.
8: Portolés T, Ibáñez M, Garlito B, Nácher-Mestre J, Karalazos V, Silva J, Alm M, Serrano R, Pérez-Sánchez J, Hernández F, Berntssen MHG. Comprehensive strategy for pesticide residue analysis through the production cycle of gilthead sea bream and Atlantic salmon. Chemosphere. 2017 Jul;179:242-253. doi: 10.1016/j.chemosphere.2017.03.099. Epub 2017 Mar 27. doi: 10.1007/s11356-017-8821-z. Epub 2017 Mar 27.
10: Purschke B, Scheibelberger R, Axmann S, Adler A, Jäger H. Impact of substrate contamination with mycotoxins, heavy metals and pesticides on the growth performance and composition of black soldier fly larvae (Hermetia illucens) for use in the feed and food value chain. Food Addit Contam Part A Chem Anal Control Expo Risk Assess. 2017 Aug;34(8):1410-1420. doi: 10.1080/19440049.2017.1299946. doi: 10.1007/s13197-016-2408-4. Epub 2016 Dec 8.

合成参考文献


摘要:Hokkaidoritsu Eisei Kenkyushoho. Report of the Hokkaido Institute of Public Health., 23(57), 1973
摘要:Bulletin of the Entomological Society of America., 15(123), 1969
摘要:Pesticide Manual., 9(168), 1991
摘要:Zhongguo Yaolixue Yu Dulixue Zazhi., 9(57), 1995
摘要:Yakkyoku. Pharmacy., 30(409), 1979
📝 需求与反馈
尽可能描述清楚需求与问题信息
×

通知