专利号:US-6512081-B1 优先权日:1997-07-21 标题:Synthesis of dithioester chain transfer agents and use of bis(thioacyl) disulfides or dithioesters as chain transfer agents 发明人:RIZZARDO ENZIO; THANG SAN HOA; MOAD GRAEME 权利人:E I DUPONT NEMOURS AND COMPANY; COMMW SCIENT IND RES ORG 摘要:This invention relates to the synthesis of dithiocarboxylic acid esters by reaction of bis(thioacyl) disulphides, thioacetals or vinylidane bis(thioether) with free-radicals (optionally in the presence of monomers). The invention also relates to processes for the synthesis of polymers utilising these dithioesters as polymerisation regulators (chain transfer agents) or to the use of bis(thioacyl) disulphides to generate dithioester chain transfer agents in situ.
专利号:US-2019055337-A1 优先权日:2016-02-02 标题 :Low-cost synthesis of macromonomers 发明人:MAYS JIMMY W; KANG NAM-GOO; WANG WEIYU; WANG HUIQUN 权利人:UNIV TENNESSEE RES FOUND 摘要:Methods of preparing macromonomers, e.g., single- or double-tailed macromonomers, using radical polymerization of a first monomer in solution or in an emulsion are described. Methods of using the macromonomers in the preparation of multigraft copolymers are also described. For instance, the macromonomer prepared by radical polymerization can be used in an emulsion copolymerization with a second monomer to form a random multigraft copolymer. The random multigraft co-polymers can be superelastomers.
专利号:EP-1699833-B1 优先权日:2003-12-31 标题:Oligomers containing n-acetyl glucosamine 发明人:KULKARNI MOHAN GOPALKRISHNA; KHANDARE JAYANT JAGANNATH 权利人:COUNCIL SCIENT IND RES 摘要:Functional polyvalent oligomer for applications in medicine and biotechnology are disclosed. These oligomers have the formula (1) wherein R is H, CH3, C2H5, RI, is H, NH2, OH, COOH, X is N-Acetyl Glucosamine, mannose, galactose and sialic acid, fructose, ribulose, erythrolose, xylulose, psicose, sorbose, tagatose, glucopyranose, fructofuranose, deoxyribose, galactosamine, sucrose, lactose, isomaltose, maltose, cellobiose, cellulose and amylose, Y is H, COOH, OH or NH2., and n is from 3 to 50. The present invention also relates to synthesis of such oligomeric ligands. The method of synthesis of the present invention for oligomerization can be - applied to other ligands such as sialic acid, mannose and galactose and can -be used for the prevention of infections,
专利号:US-6977285-B2 优先权日:2004-03-30 标题:Oligomers containing N-acetyl glucosamine (NAG) 发明人:KULKARNI MOHAN GOPALKRISHNA; KHANDARE JAYANT JAGANNATH 权利人:COUNCIL SCIENT IND RES 摘要:Functional polyvalent oligomer for applications in medicine and biotechnology are disclosed. These oligomers have the formula (1) n nwherein R is H, CH 3 , C 2 H 5 , R1, is H, NH2, OH, COOH, X is N-Acetyl Glucosamine, mannose, galactose and sialic acid, fructose, ribulose, erythrolose, xylulose, psicose, sorbose, tagatose, glucopyranose, fructofuranose, deoxyribose, galactosamine, sucrose, lactose, isomaltose, maltose, cellobiose, cellulose and amylose, Y is H, COOH, OH or NH2, and n is from 3 to 50. The present invention also relates to synthesis of such oligomeric ligands. The method of synthesis of the present invention for oligomerization can be—applied to other ligands such as sialic acid, mannose and galactose and can -be used for the prevention of infections.
专利号:WO-2017136565-A1 优先权日:2016-02-02 标 题 :Low-cost synthesis of macromonomers
专利号:WO-9905099-A1 优先权日:1997-07-21 标题:Synthesis of dithioester chain transfer agents and use of bis(thioacyl) disulfides or dithioesters as chain transfer agents
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