CAS: 35344-11-7; Carbon Monoxide,Iron,1,2,3,4,5-Pentamethylcyclopentane

📜{(η-Pentamethylcyclopentadienyl)Fe(Co)2}(1-)置于trichlorotris(Tetrahydrofuran)Chromium(Iii)体系中,用 乙腈 作为反应溶剂,化学反应生成 五甲基环戊二烯基二羰基铁二聚物
参考文献:Kinetics And Mechanism Of The Outer-Sphere Oxidation Of Metal Carbonyl Anions With Coordination Complexes Containing Chloride
标题:Kinetics And Mechanism Of The Outer-Sphere Oxidation Of Metal Carbonyl Anions With Coordination Complexes Containing Chloride
摘要:Reactions Of Metal Carbonyl Anions,Cpfe(Co)2-,Re(Co)5-,Mn(Co)5-,Cpmo(Co)3-,Cpcr(Co)3-,And Co(Co)4-,With Crcl3.3S (S = Thf,Ch3Cn) And Reactions Of Mn(Co)5-And Re(Co)5-With [co(O-Phen)2Cl2]Clo4 Are Reported. Net Oxidation/reduction Chemistry Is Observed With Formation Of Metal Carbonyl Dimers And Crcl2.4S Or Co(O-Phen)2Cl2. Metal Carbonyl Halides Are Also Observed And Shown To Arise From A Second Reaction Of The Metal Carbonyl Dimer With The Oxidant. The Products And Rates Are Most Consistent With Outer-Sphere Electron-Transfer Reactions. Reactions Of Cpfe(Co)2-With Cpfe(Co)2X (X = Cl,Br,I) Are Also Reported. The Rate Dependence On X Is Very Small And In The Order Expected For Nucleophilic Substitution.
DOI:10.1021/om00038A013