CAS: 33636-93-0; Triphenylphosphine Copper(I) Hydride Hexamer

该化合物是一个协调化合物,由多根协调的铜中心组成.该化合物的特征是其八合体几何学,这是过渡金属复合体的典型特征,允许在中央金属原子周围稳定地安排离心,三联苯磷酸酯的存在有助于其在有机溶剂中的稳定性和溶解性,而水合体可能会影响其再活性和与其他化学物种的相互作用.水合体的三环形性质表明它们连接三个铜中心,可以带来有趣的电子和磁性特性.这些综合体常常被研究其在催化学,材料科学方面的潜在应用,以及作为了解生物系统中金属-丁基相互作用的模型.

结构式图片

物理性质

MSDS等安全信息

欧盟法规

C&L通报

上下游产品

tert-butylatepotassium tert-butylate

合成工艺路线路线简述

    📜Sodium T-Butanolate,三苯基膦,氯化亚铜 以1%的收率获得产物
    参考文献:Brestensky,Donna M.;Huseland,Dave E.;Mcgettigan,Colleen;Stryker,Jeffr+,Tetrahedron Lett.,29,(1988) N 31,C. 3749-3752
    标题:Brestensky,Donna M.;Huseland,Dave E.;Mcgettigan,Colleen;Stryker,Jeffr+,Tetrahedron Lett.,29,(1988) N 31,C. 3749-3752

    专利信息


    专利号:US-10328141-B2
    优先权日:2013-07-07
    标题:Synthetic vaccines against Streptococcus pneumoniae type 1
    发明人：SEEBERGER PETER H; PEREIRA CLANEY LEBEV; ANISH CHAKKUMKAL; SCHUMANN BENJAMIN
    权利人:MAX PLANCK GESELLSCHAFT
    摘要:The present invention relates to the total synthesis of saccharide structures contained in the capsular polysaccharide of Streptococcus pneumoniae type 1, to glycoconjugates containing said saccharide structures obtained by total synthesis and to use of such glycoconjugates and pharmaceutical compositions thereof in the immunization against diseases associated with bacteria containing said saccharide structures in their capsular polysaccharide, and more specifically associated with Streptococcus pneumoniae.

    专利号:US-2019144463-A1
    优先权日:2013-11-04
    标题:Macrocyclization reactions and intermediates and other fragments useful in the synthesis of analogs of halichondrin b

    专利号:RU-2739034-C2
    优先权日:2015-05-07
    标 题 :Macrocyclisation reaction and intermediate compound and other fragments, useful in synthesis of macrolides of halichondrins

    专利号:EP-3292130-B1
    优先权日:2015-05-07
    标题:Macrocyclization reactions and intermediates and other fragments useful in the synthesis of halichondrin macrolides

    专利号:ES-2787603-T3
    优先权日:2013-11-04
    标题 :Macrocyclization Reactions and Useful Intermediates in the Synthesis of Halichondrine B Analogs

    专利号:US-2018118755-A1
    优先权日:2015-05-07
    标题:Macrocyclization reactions and intermediates and other fragments useful in the synthesis of halichondrin macrolides

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Trofimova, A.; Sirvinskas, M.; Yudin, A. K., Science of Synthesis Knowledge Updates, (2021) 2, 93.
    摘要:Vaultier, M.; Pucheault, M., Science of Synthesis Knowledge Updates, (2012) 4, 310.
    摘要:Trofimova, A.; Sirvinskas, M.; Yudin, A. K., Science of Synthesis Knowledge Updates, (2021) 2, 102.
    摘要:Denmark, S.; Chang, W.-T. T., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 1, 488.
    摘要:Llopis, Q.; Ayad, T.; Phansavath, P.; Ratovelomanana-Vidal, V., Science of Synthesis: Catalytic Reduction in Organic Synthesis, (2018) 2, 100.
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