CAS: 1836-77-7; Chlornitrofen

该化合物是一种氯化芳香化合物,具有亚硝基氧替代成分,其分子结构,结合电子提纯氯和硝基化合物,在合成有机化学中具有实用性,特别是作为生产农用化学品或特殊化学品的中间体.该化合物在标准条件下的稳定性和在电益替代或核循环迁移反应中的反应性能,使它成为进一步功能化的多功能构件.其独特的替代模式允许有选择地进行修改,使复杂的衍生物能够有针对性地合成.由于与氯化和硝酸化合物有关的潜在危险,需要适当处理.

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CAS号350-46-9 对氟硝基苯 | CAS号88-06-2 2,4,6-三氯苯酚 | CAS号100-00-5 对硝基氯苯 | CAS号71861-68-2 N-[4-(2,4,6-tri... | CAS号98911-09-2 N-hydroxy-N-[4-... | CAS号99226-42-3 N-[4-(2,4,6-tri...

合成工艺路线路线简述

    📜对氟硝基苯,2,4,6-三氯苯酚置于potassium Fluoride Supported On Clinoptilolite体系中,用 二甲基亚砜 用作溶剂,化学反应 5.67H,以85%的收率获得草枯醚
    参考文献:天然纳米多孔沸石负载氟化钾:合成二芳基醚的新固体基础
    标题:天然纳米多孔沸石负载氟化钾:合成二芳基醚的新固体基础
    摘要:已开发出一种高效且廉价的二芳基醚合成方法.该过程涉及缺电子芳基卤化物和酚的亲核芳香取代,并由二甲基亚砜 (Dmso) 中的氟化钾/斜发沸石 (Kf/cp) 介导.该方法在不需要额外的阳离子捕获的情况下提供了非常好到极好的芳基化产物的收率.固体碱在乌尔曼醚合成中也是有效的.
    Doi:10.1002/ejoc.201001447

    海关参考信息

    专利信息


    专利号:WO-2024256370-A1
    优先权日:2023-06-13
    标 题 :Synthesis of glufosinate using an amidase-based process
    发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

    专利号:US-2025120400-A1
    优先权日:2021-12-10
    标题:Synthesis of glufosinate using a hydantoinase-based process
    发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

    专利号:US-2021352899-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

    专利号:TW-I655905-B
    优先权日:2012-07-24
    标题 :Contains 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid or a derivative thereof and very long chain fatty acid (VLCFA) Synthesis of herbicidal compositions with fatty acid/fat synthesis inhibiting herbicides

    专利号:US-9644469-B2
    优先权日:2012-07-24
    标题 :Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and VLCFA and lipid synthesis inhibiting herbicides
    发明人:YERKES CARLA N; MANN RICHARD K; SHIRAISHI IKUO; YANAGIYAMA SHINGO; SATCHIVI NORBERT M
    权利人:DOW AGROSCIENCES LLC
    摘要:A synergistic herbicidal composition containing (a) a compound of formula (I): n nor an agriculturally acceptable salt or ester thereof and (b) VLCFA and fatty acid/lipid synthesis inhibiting herbicides, including but not limited to, acetochlor, alachlor, anilofos, benfuresate, cafenstrole, dimethenamid-P, fentrazamide, indanofan, flufenacet, mefenacet, s-metolachlor, molinate, pethoxamid, pretilachlor, prosulfocarb, pyroxasulfone, thenylchlor and thiobencarb, or a salt or ester thereof, provide synergistic weed control of undesirable vegetation in direct-seeded, water-seeded and transplanted rice, cereals, wheat, barley, oats, rye, sorghum, corn or maize, sugarcane, sunflower, oilseed rape, canola, sugar beet, soybean, cotton, pineapple, pastures, grasslands, rangelands, fallowland, turf, tree and vine orchards, aquatics, plantation crops, vegetables, industrial vegetation management (IVM) or rights-of-way (ROW).

    专利号:US-9999223-B2
    优先权日:2008-05-21
    标 题 :Herbicidal composition comprising glyphosate, glufosinate or their salts
    发明人:SIEVERNICH BERND; MOBERG WILLIAM KARL; SIMON ANJA; WALTER HELMUT; EVANS RICHARD R
    权利人:BASF SE
    摘要:The present invention relates to a herbicidal composition which comprises:n a) at least one herbicide A selected from glyphosate, glufosinate and their salts, and b) a herbicide B which is 3-[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)pyrazol-4-ylmethylsulfonyl]-4,5-dihydro-5,5-dimethyl-1,2-oxazole [common name: pyroxasulfone]. nn The present invention relates in particular to a herbicidal composition comprising:n a) at least one herbicide A selected from glyphosate, glufosinate and their salts, b) a herbicide B which is 3-[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)pyrazol-4-ylmethylsulfonyl]-4,5-dihydro-5,5-dimethyl-1,2-oxazole [common name: pyroxasulfone], and c) at least one further herbicide C, which is selected from the herbicide groups C.1 to C.8:n C.1 herbicides of the group of acetolactate synthase inhibitors (ALS inhibitors), C.2 herbicides of the group of protoporphyrinogen oxidase inhibitors (PPO inhibitors), C.3 herbicides of the group of auxines, C.4 herbicides of the group of 4-hydroxyphenyl-pyruvate-dioxygenase inhibitors (HPPD inhibitors), C.5 herbicides of the group of phytoene desaturase inhibitors (PDS inhibitors), C.6 herbicides of the group of photosystem II inhibitors (PSII inhibitors), C.7 herbicides of the group of microtubulin inhibitors, and C.8 herbicides of the group of inhibitors of the synthesis of very long chain fatty acids (VLCFA inhibitors).

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    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: A Oguri, Et Al. Detection Of Mutagenicity Of Diphenyl Ether Herbicides In Salmonella Typhimurium Yg1026 And Yg1021. Mutat Res. 1995 Jan;346(1):57-60.
    [参考文献]: H Jinno, Et Al. Cytotoxic And Porphyrinogenic Effects Of Diphenyl Ethers In Cultured Rat Hepatocytes: Chlornitrofen (Cnp), Cnp-Amino, Chlomethoxyfen And Bifenox. Food Chem Toxicol. 1999 Jan;37(1):69-74.
    [参考文献]: H Nakanishi, Et Al. Comparative Studies On Additive Effects Of Sodium Dodecylbenzensulfonate And Sodium Stearate On Uptake Of Chemicals By Willow Shiner (Gnathopogon Caerulescens). Comp Biochem Physiol C Comp Pharmacol Toxicol. 1987;86(2):361-4.
    [参考文献]: Kotaro Minomo, Et Al. Seasonal Change Of Pcdds/pcdfs/dl-Pcbs In The Water Of Ayase River, Japan: Pollution Sources And Their Contributions To Teq. Chemosphere. 2011 Sep;85(2):188-94.
    [参考文献]: Reiko Teshima, Et Al. Effect Of Two Nitrogenous Diphenyl Ether Pesticides On Mast Cell Activation. Toxicol Lett. 2004 May 2;150(3):277-83.

    合成参考文献


    摘要:Pesticide Manual., 9(151), 1991
    摘要:Agricultural Chemicals, Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revision, 2(195), 1977
    参考文献:10.1016/0165-7992(95)90069-1
    摘要:Oguri A, Karakama K, Arakawa N, Sugimura T, Wakabayashi K. Detection of mutagenicity of diphenyl ether herbicides in Salmonella typhimurium YG1026 and YG1021. Mutation Research Letters. 1995 Jan;346(1):57–60. doi: 10.1016/0165-7992(95)90069-1.
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