CAS: 49540-00-3; Mercury(Ii) Trifluoromethanesulfonate

该化合物是有机汞化合物,其特点是汞中心与三氟甲烷硫酸化合物结合成三氟甲烷混合物,该化合物一般是白色至浅黄色固体,以其在水和有机溶剂等极地溶剂中的高溶性而著称,由于存在汞离子,该化合物具有重要的反应性能,可参与各种化学反应,包括与离心和红氧化工艺的协调.三氟甲烷混合物有助于其稳定性和溶解性,同时也具有独特的电子特性.汞(II)三氟乙烷硫酸盐经常被用作有机合成的试剂或催化剂,特别是在涉及核循环替代的反应中.然而,由于与汞化合物相关的毒性,处理需要严格的安全措施来减轻接触风险.

英文名称Mercury(Ii) Trifluoromethanesulfonate
中文名称三氟甲烷磺酸汞
IUPAC名称mercury(2+);bis(trifluoromethanesulfonate)
其它别名三氟甲磺酸汞; 三氟甲烷磺酸汞ⅱ; Mercurytrifluoromethanesulfonatemercurytriflatepowder
CAS编号49540-00-3
MFCD编号:MFCD00144746
EINECS号:627-708-8
分子式:CHF3HgO3S
分子量:350.66
产品CID: 1481770
产品分类有机原料→通用试剂→无机盐→过渡金属盐

相似结构搜索
InChIKey: BPVYMDMPLCOQPJ-UHFFFAOYSA-L
1S/2CHF3O3S.Hg/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2…
计算化学: 氢键受体数3.0氢键供体数0.0可旋转键数0.0

相似化合物

34946-82-2 2923-28-6 88189-03-1

物理性质

熔点>350 °C
沸点162 °C at 760mmHg
闪点°C
PSA:57.2
LogP:0.0489
蒸汽压1.14 mmHg at 25 °C
溶解性It Is Soluble In H2O And Ch3Cn, Fairly Soluble In Ch3No2 And Ch2Cl2, Insoluble In Hexane, Ether, And Toluene.
敏感性易受潮
外观形态白色粉末
储存条件2-8°C, protect from light, stored under nitrogen
产品应用该化合物用于刘易斯酸催化不对称反应的金属来源.

MSDS等安全信息

GHS象形图
GHS符号GHS06 & GHS08 & GHS09;
注释: Skull and crossbones & Health hazard & Environment
危险类别急性毒性类别2(吸入)
急性毒性类别1(经皮)
急性毒性类别2(经口)
特定目标器官毒性-重复接触类别2
水生急性毒性类别1
水生慢性毒性类别1
警示词Danger(危险)
危险描述H330 |吸入致命.
H310 |皮肤接触致命.
H300 |吞咽致命.
H373 |长期或反复接触可能损害器官.
H400 |对水生生物毒性极大.
H410 |对水生生物毒性极大并具有长期持续影响.
防范说明P260-P262-P264-P270-P271-P273-P280-P284-P302+P352-P304+P340-P330-P361+P364-P391-P405-P501
危险等级6.1
UN编号2025.0
危险品标志T+,N,T,C
风险等级Corrosive/Toxic
包装等级Ⅱ
安全声明13-28-36-45-60-61
危险类别码26/27/28-33-50/53
WGK Germany3

欧盟法规

C&L通报

上下游产品

trifluorormethanesulfonic acid mercury(II) oxide dihydrogen peroxide mercury bis(trifluoromethanethiolate)phosgene trifluoromethylsulfonic anhydride carbonyl dibromide trifluoromethanesulfonic acid trichlormethylester

合成工艺路线路线简述

专利信息

专利号:US-4769451-A
优先权日:1985-08-15
标题:Synthesis of carbapenems using n-substituted azetidinones
发明人：DEXTRAZE PIERRE
权利人:BRISTOL MYERS CO
摘要:A novel process is disclosed for converting known 3,4-disubstituted azetidinones to carbapenems. The process proceeds through novel N-substituted intermediates and then cyclizes to the 4-position of the azetidinone to form the carbapenem.

专利号:US-4973687-A
优先权日:1985-08-15
标题:Synthesis of carbapenems using N-substituted azetidinones
发明人：DEXTRAZE PIERRE
权利人:BRISTOL MYERS CO
摘要:This invention provides novel azetidinone intermediates having the formulas: ##STR1## wherein R 1 is hydrogen, or a conventional hydroxy-protecting groups; R 2 , R 4 , and R 5 are independently selected from the group consisting of hydrogen; substituted and unsubstituted: alkyl, alkenyl, and alkynyl having from 1-10 carbon atoms; cycloalkyl, cycloalkylalkyl, and alkylcycloalkyl having 3-6 carbon atoms in the cycloalkyl ring and 1-6 carbon atoms in the alkyl moieties; spirocycloalkyl having 3-6 carbon atoms; phenyl; aralkyl, aralkenyl, and aralkynyl wherein the aryl moiety is phenyl and the aliphatic portion has 1-6 carbon atoms; or various heterocyclic moieties; and R 6 is methanesulfonyl or p-toluenesulfonyl; which are useful in the preparation of carbapenem antibiotics.

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