CAS: 355-25-9; 1,1,1,2,2,3,3,4,4,4-Decafluorobutane

上下游产品

CAS号357-26-6 °Ctafluoro-1-butene | CAS号71-43-2 苯 | CAS号360-89-4 全氟2-丁烯 | CAS号756-00-3 bis(1,1,2,2,2-p... | CAS号109-69-3 1-氯丁烷 | CAS号598-88-9 1,2-二氯-1,2-二氟乙烯 | CAS号58705-93-4 1,1,1,2,3,3-hex... | CAS号4151-03-5 2-甲基-3-(吡咯烷-1-基)丙酸甲酯 | CAS号22041-21-0 3-吡咯烷丙酸甲酯 | CAS号120-92-3 环戊酮 | CAS号76-19-7 八氟丙烷 | CAS号116-15-4 六氟丙烯 | CAS号76-16-4 六氟乙烷 | CAS号382-21-8 全氟异丁烯 | CAS号354-33-6 五氟乙烷 | CAS号75-10-5 二氟甲烷 | CAS号75-46-7 三氟甲烷

📜全氟丁基磺酰氟置于4-二甲氨基吡啶体系中,化学反应 4.0H,反应生成 全氟正丁烷
参考文献:Amine-Induced Decomposition Of Perfluoroalkanesulfonyl Fluorides
标题:Amine-Induced Decomposition Of Perfluoroalkanesulfonyl Fluorides
摘要:全氟烷基磺酰氟(cnf2N+1So2F)在三级杂芳香族或脂肪族胺的存在下,即使在零下 20 oc 也会缓慢分解,反应生成相应的全氟烷烃(cnf2N+2)和胺-二氧化硫加合物.
DOI:10.1055/s-2008-1067007

专利信息

专利号:EP-0364340-B1
优先权日:1988-10-05
标题:Method for the synthesis of sulfonyl imides
摘要:Method for the synthesis of sulfonylimidides having the formula M((RSO2)2N)y, whrein M is a metal or an ammonium radical quaternary or not, the Rs, which may be identical or similar are organic monovalent radicals, particularly hydrocarbyles and preferably perfluorohydrocarbyles, in C1 to C12, and y is the valence of M. On the one hand, a silazane component selected amongst the silazane compounds M(((R2)3Si)2N)y or the associations of a silazane derivative A((R2)3Si)2N or a fluoride M1Fz of low cross-linking energy is reacted with, on the other hand, at least one sulfonic halogenite component consisting of a sulfonyl fluoride RSO2F or in the association of a sulfonyl chloride RSO2Cl with a fluoride M1Fz, M, R and y having the above-mentionned significations, M1 being selected amongst the Ms and being optionally identical to M, z being the valence of M1 and R2 representing an alkyl in C1 to C4. The imidides obtained for which the R2 are perfluorated radicals and M is an alkaline metal such as Li are usable in association with polyethers for the production of materials of the ionic conduction type for all solid generators in thin films.

专利号:US-11554094-B2
优先权日:2015-06-18
标题 :Synthesis and application of microbubble-forming compounds
发明人：MARX VANESSA M; GRUBBS ROBERT H
权利人:CALIFORNIA INST OF TECHN
摘要:The present disclosure is directed to fatty-acid glycerol ester derivative compounds containing a targeting bisphosphonate group. The disclosure further includes pharmaceutical or biomedical compositions comprising these compounds, and methods of using these compounds and compositions forming microbubbles. The microbubbles have affinity for metal-containing, especially calcium-containing, bodies and/or biological targets. In certain embodiments, these compositions are useful for providing targeted placement of microbubbles capable of cavitation on application of high frequency energy.

专利号:US-5693855-A
优先权日:1995-02-14
标 题 :Process for the synthesis of fluorinated sulfonic acids
发明人：ZAVILLA JOHN; HOMMELTOFT SVEN IVAR
权利人:HALDOR TOPSOE AS
摘要:Process for the preparation of a fluorinated sulphonic acid compound by hydrolysis of a corresponding fluorinated sulphonyl fluoride in the presence of a tertiary amine, comprising steps of n (a) recovering a mixture of a salt of the fluorinated sulphonic acid with the tertiary amine and an ammonium fluoride salt of the tertiary amine; n (b) distilling off the tertiary ammonium fluoride salt and leaving a distillation remanence containing the salt of the fluorinated sulphonic acid with the tertiary amine; and n (c) recovering the fluorinated sulphonic acid compound from the distillation remanence.

专利号:US-8461298-B2
优先权日:2004-11-01
标 题:Compositions and methods for modification of biomolecules
发明人：BERTOZZI CAROLYN R; AGARD NICHOLAS J; PRESCHER JENNIFER A; BASKIN JEREMY MICHAEL
权利人:BERTOZZI CAROLYN R; AGARD NICHOLAS J; PRESCHER JENNIFER A; BASKIN JEREMY MICHAEL; UNIV CALIFORNIA
摘要:The present invention provides modified cycloalkyne compounds; and method of use of such compounds in modifying biomolecules. The present invention features a cycloaddition reaction that can be carried out under physiological conditions. In general, the invention involves reacting a modified cycloalkyne with an azide moiety on a target biomolecule, generating a covalently modified biomolecule. The selectivity of the reaction and its compatibility with aqueous environments provide for its application in vivo (e.g., on the cell surface or intracellularly) and in vitro (e.g., synthesis of peptides and other polymers, production of modified (e.g., labeled) amino acids).

专利号:US-9260371-B2
优先权日:2004-11-01
标题:Compositions and methods for modification of biomolecules
发明人：BERTOZZI CAROLYN RUTH; AGARD NICHOLAS J; PRESCHER JENNIFER A; BASKIN JEREMY MICHAEL; SLETTEN ELLEN MAY
权利人:UNIV CALIFORNIA
摘要:The present invention provides modified cycloalkyne compounds; and method of use of such compounds in modifying biomolecules. The present invention features a cycloaddition reaction that can be carried out under physiological conditions. In general, the invention involves reacting a modified cycloalkyne with an azide moiety on a target biomolecule, generating a covalently modified biomolecule. The selectivity of the reaction and its compatibility with aqueous environments provide for its application in vivo (e.g., on the cell surface or intracellularly) and in vitro (e.g., synthesis of peptides and other polymers, production of modified (e.g., labeled) amino acids).

专利号:US-3928445-A
优先权日:1973-12-26
标 题 :Synthesis of 2-halo-5-cyano alkyl valerate
发明人：ROGIC MILORAD M; MARES FRANTISEK
权利人:ALLIED CHEM
摘要:2-Halo-5-cyano alkyl valerate is produced by halogenating a 2alkoxy-3-oximinocyclohexene or the mineral acid salt thereof with at least one equivalent of chlorine, bromine or iodine; treating the 1,2-dihalo-2-alkoxy-3-oximinocyclohexane intermediate thus formed with an alcohol having 1 to 12 carbon atoms, more preferably with ethanol, methanol, propanol, butanol or isobutanol to form the corresponding 2-halo-6oximinocyclohexanone dialkyl ketal or its mineral acid salt; and ring opening of the ketal using a Beckmann cleavage reaction to form 2-halo-5-cyano alkyl valerate. The novel compound thus formed may be converted by reductive amination to form an alkyl ester of lysine which is subsequently hydrolyzed and neutralized to produce lysine.