CAS: 83217-89-4; 1Beta-Hydroxy-Beta-Eudesmol

英文名称1Beta-Hydroxy-Beta-Eudesmol
中文名称1beta-羟基-beta-桉叶油醇
IUPAC名称6-(2-hydroxypropan-2-yl)-8a-methyl-4-methylenedecahydronaphthalen-1-ol
其它别名(2R,4Ar,5R,8As)-Decahydro-5-Hydroxy-Alpha,Alpha,4A-Trimethyl-8-Methylene-2-Naphthalenemethanol; 1Beta-Hydroxy-Beta-Eudesmol; (+)-Selin-4-(15)-Ene-1β,11-Diol; 2-Naphthalenemethanol, Decahydro-5-Hydroxy-α,α,4A-Trimethyl-8-Methylene-, (2R,4Ar,5R,8As)-; Eudesma-4(15)-En-1β11-Diol/1Beta-Hydroxy-Beta-Eudesmol; 1β-Hydroxy-β-Eudesmol; (1R,4As,6R,8Ar)-6-(2-Hydroxypropan-2-yl)-8A-Methyl-4-Methylenedecahydronaphthalen-1-Ol; (1S,4Ar,6S,8As)-6-(2-Hydroxypropan-2-yl)-8A-Methyl-4-Methylidene-1,2,3,4A,5,6,7,8-Octahydronaphthalen-1-Ol
CAS编号83217-89-4
MFCD编号:MFCD28100287
分子式:C15H26O2分子量:238.37
产品CID: 1821118
产品分类有机原料→分子砌块→桥环类化合物→其它桥环类化合物

相似结构搜索
InChIKey: MQOLOUZWNJHZLN-UHFFFAOYSA-N
InChI=1S/C15H26O2/c1-10-5-6-13(16)15(4)8-7-11(9-12(10)15)14(2,3)17/h11-13,16-17H,1,5-9H2,2-4H3
计算化学: 氢键受体数2.0氢键供体数2.0可旋转键数1.0

相似化合物

472-15-1 640289-58-3 658062-22-7

MSDS等安全信息

危险描述H303 May be harmful if swallowed+H313 Skin contact may be harmful+H333 Inhalation may be harmful to the body
防范说明P264+P280+P305+P351+P338+P337+P313
安全声明H303+H313+H333

上下游产品

Methyltriphenylphosphonium bromide (S)-isopiperitenone 6-(1'-hydroxyisopropyl)-3-methyl-2-cyclohexenol dec-5-en-4-one7β-(1-hydroxy-1-methylethyl)-1β-hydroxy-10β-methylbicyclo4.4.0dec-5-en-4-one

合成工艺路线路线简述

1779-49-3 = 83217-89-4
反应条件:1.1 Reagents: Sodium Hydride Solvents: Dimethyl Sulfoxide1.2 Solvents: Dimethyl Sulfoxide
标题:Total Synthesis Of (+)-Balanitol And Of (+)-Selin-4-(15)-Ene-1β,11-Diol
作者:Anglea,Timothy A.; Et Al
参考文献:Tetrahedron 日期:1987 卷标:43(23) 页码:5537-43]

473-15-4 = 83217-89-4
反应条件:1.1 Catalysts: Cytochrome Cyp102 Solvents: Water; 4 H,37 °C
标题:Bioconversion Of Substituted Naphthalenes And β-Eudesmol With The Cytochrome P450 Bm3 Variant F87V
作者:Misawa,Norihiko; Et Al
参考文献:Applied Microbiology And Biotechnology 日期:2011 卷标:90(1) 页码:147-157]

= 83217-89-4
反应条件:1.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Methanol2.1 Reagents: Sodium Hydride Solvents: Dimethyl Sulfoxide2.2 Solvents: Dimethyl Sulfoxide
标题:Total Synthesis Of (+)-Balanitol And Of (+)-Selin-4-(15)-Ene-1β,11-Diol
作者:Anglea,Timothy A.; Et Al
参考文献:Tetrahedron 日期:1987 卷标:43(23) 页码:5537-43]

= 83217-89-4
反应条件:1.1 Reagents: Magnesium Silicate Solvents: Ethyl Acetate2.1 Reagents: Sodium Borohydride Solvents: Ethanol2.2 Reagents: Acetone3.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Methanol4.1 Reagents: Sodium Hydride Solvents: Dimethyl Sulfoxide4.2 Solvents: Dimethyl Sulfoxide
标题:Total Synthesis Of (+)-Balanitol And Of (+)-Selin-4-(15)-Ene-1β,11-Diol
作者:Anglea,Timothy A.; Et Al
参考文献:Tetrahedron 日期:1987 卷标:43(23) 页码:5537-43]

117212-63-2 + 485403-17-6 = 83217-89-4
反应条件:1.1 Reagents: Lithium Aluminum Hydride Solvents: Diethyl Ether2.1 Reagents: Dipyridinium Dichromate Solvents: Dichloromethane3.1 Solvents: Pentane4.1 Reagents: Lithium Aluminum Hydride Solvents: Diethyl Ether5.1 Reagents: Oxygen Solvents: Methanol6.1 Reagents: Silica Solvents: Ethyl Acetate7.1 Reagents: Magnesium Silicate Solvents: Ethyl Acetate8.1 Reagents: Sodium Borohydride Solvents: Ethanol8.2 Reagents: Acetone9.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Methanol10.1 Reagents: Sodium Hydride Solvents: Dimethyl Sulfoxide10.2 Solvents: Dimethyl Sulfoxide
标题:Total Synthesis Of (+)-Balanitol And Of (+)-Selin-4-(15)-Ene-1β,11-Diol
作者:Anglea,Timothy A.; Et Al
参考文献:Tetrahedron 日期:1987 卷标:43(23) 页码:5537-43]

16750-82-6 = 83217-89-4
反应条件:1.1 Reagents: M-Chloroperbenzoic Acid Solvents: Chloroform2.1 Reagents: Lithium Aluminum Hydride Solvents: Diethyl Ether3.1 Reagents: Dipyridinium Dichromate Solvents: Dichloromethane4.1 Solvents: Pentane5.1 Reagents: Lithium Aluminum Hydride Solvents: Diethyl Ether6.1 Reagents: Oxygen Solvents: Methanol7.1 Reagents: Silica Solvents: Ethyl Acetate8.1 Reagents: Magnesium Silicate Solvents: Ethyl Acetate9.1 Reagents: Sodium Borohydride Solvents: Ethanol9.2 Reagents: Acetone10.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Methanol11.1 Reagents: Sodium Hydride Solvents: Dimethyl Sulfoxide11.2 Solvents: Dimethyl Sulfoxide
标题:Total Synthesis Of (+)-Balanitol And Of (+)-Selin-4-(15)-Ene-1β,11-Diol
作者:Anglea,Timothy A.; Et Al
参考文献:Tetrahedron 日期:1987 卷标:43(23) 页码:5537-43]

= 83217-89-4
反应条件:1.1 Reagents: Sodium Borohydride Solvents: Ethanol1.2 Reagents: Acetone2.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Methanol3.1 Reagents: Sodium Hydride Solvents: Dimethyl Sulfoxide3.2 Solvents: Dimethyl Sulfoxide
标题:Total Synthesis Of (+)-Balanitol And Of (+)-Selin-4-(15)-Ene-1β,11-Diol
作者:Anglea,Timothy A.; Et Al
参考文献:Tetrahedron 日期:1987 卷标:43(23) 页码:5537-43]

= 83217-89-4
反应条件:1.1 Reagents: Silica Solvents: Ethyl Acetate2.1 Reagents: Magnesium Silicate Solvents: Ethyl Acetate3.1 Reagents: Sodium Borohydride Solvents: Ethanol3.2 Reagents: Acetone4.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Methanol5.1 Reagents: Sodium Hydride Solvents: Dimethyl Sulfoxide5.2 Solvents: Dimethyl Sulfoxide
标题:Total Synthesis Of (+)-Balanitol And Of (+)-Selin-4-(15)-Ene-1β,11-Diol
作者:Anglea,Timothy A.; Et Al
参考文献:Tetrahedron 日期:1987 卷标:43(23) 页码:5537-43]

= 83217-89-4
反应条件:1.1 Reagents: Oxygen Solvents: Methanol2.1 Reagents: Silica Solvents: Ethyl Acetate3.1 Reagents: Magnesium Silicate Solvents: Ethyl Acetate4.1 Reagents: Sodium Borohydride Solvents: Ethanol4.2 Reagents: Acetone5.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Methanol6.1 Reagents: Sodium Hydride Solvents: Dimethyl Sulfoxide6.2 Solvents: Dimethyl Sulfoxide
标题:Total Synthesis Of (+)-Balanitol And Of (+)-Selin-4-(15)-Ene-1β,11-Diol
作者:Anglea,Timothy A.; Et Al
参考文献:Tetrahedron 日期:1987 卷标:43(23) 页码:5537-43]

= 83217-89-4
反应条件:1.1 Reagents: Lithium Aluminum Hydride Solvents: Diethyl Ether2.1 Reagents: Oxygen Solvents: Methanol3.1 Reagents: Silica Solvents: Ethyl Acetate4.1 Reagents: Magnesium Silicate Solvents: Ethyl Acetate5.1 Reagents: Sodium Borohydride Solvents: Ethanol5.2 Reagents: Acetone6.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Methanol7.1 Reagents: Sodium Hydride Solvents: Dimethyl Sulfoxide7.2 Solvents: Dimethyl Sulfoxide
标题:Total Synthesis Of (+)-Balanitol And Of (+)-Selin-4-(15)-Ene-1β,11-Diol
作者:Anglea,Timothy A.; Et Al
参考文献:Tetrahedron 日期:1987 卷标:43(23) 页码:5537-43]

17082-61-0 + 71697-77-3 = 83217-89-4
反应条件:1.1 Solvents: Pentane2.1 Reagents: Lithium Aluminum Hydride Solvents: Diethyl Ether3.1 Reagents: Oxygen Solvents: Methanol4.1 Reagents: Silica Solvents: Ethyl Acetate5.1 Reagents: Magnesium Silicate Solvents: Ethyl Acetate6.1 Reagents: Sodium Borohydride Solvents: Ethanol6.2 Reagents: Acetone7.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Methanol8.1 Reagents: Sodium Hydride Solvents: Dimethyl Sulfoxide8.2 Solvents: Dimethyl Sulfoxide
标题:Total Synthesis Of (+)-Balanitol And Of (+)-Selin-4-(15)-Ene-1β,11-Diol
作者:Anglea,Timothy A.; Et Al
参考文献:Tetrahedron 日期:1987 卷标:43(23) 页码:5537-43]

87859-10-7 + 71697-78-4 = 83217-89-4
反应条件:1.1 Reagents: Dipyridinium Dichromate Solvents: Dichloromethane2.1 Solvents: Pentane3.1 Reagents: Lithium Aluminum Hydride Solvents: Diethyl Ether4.1 Reagents: Oxygen Solvents: Methanol5.1 Reagents: Silica Solvents: Ethyl Acetate6.1 Reagents: Magnesium Silicate Solvents: Ethyl Acetate7.1 Reagents: Sodium Borohydride Solvents: Ethanol7.2 Reagents: Acetone8.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Methanol9.1 Reagents: Sodium Hydride Solvents: Dimethyl Sulfoxide9.2 Solvents: Dimethyl Sulfoxide
标题:Total Synthesis Of (+)-Balanitol And Of (+)-Selin-4-(15)-Ene-1β,11-Diol
作者:Anglea,Timothy A.; Et Al
参考文献:Tetrahedron 日期:1987 卷标:43(23) 页码:5537-43]

52154-82-2 + 22972-51-6 = 83217-89-4
反应条件:1.1 Reagents: Chromium Trioxide,Sulfuric Acid Solvents: Diethyl Ether,Acetone,Water2.1 Reagents: M-Chloroperbenzoic Acid Solvents: Chloroform3.1 Reagents: Lithium Aluminum Hydride Solvents: Diethyl Ether4.1 Reagents: Dipyridinium Dichromate Solvents: Dichloromethane5.1 Solvents: Pentane6.1 Reagents: Lithium Aluminum Hydride Solvents: Diethyl Ether7.1 Reagents: Oxygen Solvents: Methanol8.1 Reagents: Silica Solvents: Ethyl Acetate9.1 Reagents: Magnesium Silicate Solvents: Ethyl Acetate10.1 Reagents: Sodium Borohydride Solvents: Ethanol10.2 Reagents: Acetone11.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Methanol12.1 Reagents: Sodium Hydride Solvents: Dimethyl Sulfoxide12.2 Solvents: Dimethyl Sulfoxide
标题:Total Synthesis Of (+)-Balanitol And Of (+)-Selin-4-(15)-Ene-1β,11-Diol
作者:Anglea,Timothy A.; Et Al
参考文献:Tetrahedron 日期:1987 卷标:43(23) 页码:5537-43

📜3-甲基-6-(1-甲基乙烯基)-2-环己烯-1-酮置于palladium On Activated Charcoal 盐酸,Sodium Hydroxide,Sodium Tetrahydroborate,Lithium Aluminium Tetrahydride,重铬酸吡啶,Florisil,氢气,Sodium Hydride,间氯过氧苯甲酸体系中,用甲醇,乙醇,二氯甲烷,氯仿,乙酸乙酯,正戊烷作为反应溶剂,-45.0~80.0 °C,101.33 Kpa 条件下,反应 106.92H,反应生成 (2R,4Ar,5R,8As)-十氢-5-羟基-Alpha,Alpha,4A-三甲基-8-亚甲基-2-萘甲醇
参考文献:Total Synthesis Of (+)-Balanitol And Of (+)-Selin-4-(15)-Ene-1β,11-Diol
标题:Total Synthesis Of (+)-Balanitol And Of (+)-Selin-4-(15)-Ene-1β,11-Diol
摘要:
DOI:10.1016/s0040-4020(01)87735-8