CAS: 79538-32-2; 2,3,5,6-Tetrafluoro-4-Methylbenzyl 3-[(1Z)-2-Chloro-3,3,3-Trifluoroprop-1-En-1-Yl]-2,2-Dimethylcyclopropanecarboxylate

该化合物是一种合成除虫菊酯,其有效抗多种害虫的用途为人所知,其特点是它对哺乳动物和鸟类毒性低,因此在农业和住宅虫害控制应用中成为首选,四氟氯菊酯行为扰乱昆虫...

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  • 68127-98-0 + 79538-03-7 = 79538-32-2
    反应条件:1.1 3 H,45 °C; 2 H,95 °C; 95 °C -> 60 °C
    标题:Process For The Manufacture Of Tefluthrin
    作者:Anonymous
    参考文献:Research Disclosure 日期:2004 卷标:478]

    68127-98-0 + 79538-03-7 = 79538-32-2
    反应条件:1.1 Solvents: Toluene; 5 H,20 - 25 °C
    标题:Improved Synthesis Of Tefluthrin
    作者:He,Shu-Ze
    参考文献:Xiandai Nongyao 日期:2015 卷标:14(2) 页码:28-30

海关参考信息

专利信息


专利号:US-2016073631-A1
优先权日:2013-03-04
标 题 :Process for the preparation of dihydropyrrole derivatives
发明人:EL QACEMI MYRIEM; SMITS HELMARS; CASSAYRE JEROME YVES; MULHOLLAND NICHOLAS PHILLIP; RENOLD PETER; GODINEAU EDOUARD; PITTERNA THOMAS
权利人:SYNGENTA PARTICIPATIONS AG; SYNGENTA LTD
摘要:The present invention provides stereoselective processes for the preparation of compounds of formula (I) n n n n n n n n n n n n wherein n P is phenyl, naphthyl, a 6-membered heteroaryl group containing one or two nitrogen atoms as ring members, or a 10-membered bicyclic heteroaryl group containing one or two nitrogen atoms as ring members, and wherein the phenyl, naphthyl and heteroaryl groups are optionally substituted; n R 1 is chlorodifluoromethyl or trifluoromethyl; n R 2 is optionally substituted aryl or optionally substituted heteroaryl; n n is 0 or 1; n including the process comprising n (a-i) reacting a compound of formula II n n n n n n n n n n n n n n n n wherein P, R 1 and R 2 are as defined for the compound of formula I; n with nitromethane in the presence a chiral catalyst to give a compound of formula III n n n n n n n n n n n n n n n n wherein P, R 1 and R 2 are as defined for the compound of formula I; and n (a-ii) reductively cyclising the compound of formula III to give the compound of formula I. n n n n n The invention also provides intermediates useful for processes for the synthesis of compounds of formula (I).

专利号:US-2007232495-A1
优先权日:2006-03-24
标题:Compositions and methods to add value to plant products, increasing the commercial quality, resistance to external factors and polyphenol content thereof
发明人:NAPPA ALVARO O; LORENZINI FELIPE C; SANHUEZA ANDRES L
权利人:NAPPA ALVARO O; LORENZINI FELIPE C; SANHUEZA ANDRES L
摘要:The invention is related to compositions and methods that naturally protect plant tissues against ultraviolet radiation and temperature, thus giving protection against sunburn to plants, plant parts, fruits and/or flowers during their development. The invention is also related to compositions and methods to naturally improve the color of plants, plant parts, fruits and/or flowers by inducing the natural synthesis of flavonoids and anthocyanins present in plants. Likewise, the present invention is directed to improving the nutritional value of plants, plant parts, fruits and/or flowers by increasing the normal levels of polyphenolic compounds, especially flavonoids, present therein. Additionally, the present invention is related to compositions and methods that give more resistance to plants, plant parts, fruits and/or flowers against pathogens as bacteria and fungi. Finally, the present invention is related to plants, plant parts, fruits, flowers and/or propagating material treated with the compositions described in the present document.

专利号:US-2011230343-A1
优先权日:2008-10-24
标题 :Method for the Manufacture of Microparticles Comprising an Effect Substance
发明人:SCHROERS MICHAEL; DYLLICK-BRENZINGER RAINER; MERK MICHAEL; BARG HEIKO
权利人:BASF SE
摘要:A subject matter of the present invention is a process for the preparation of effect compound-comprising microparticles M comprising A) the formation of a crude suspension of microparticles A by means of enzymatic polyester synthesis in an inverse miniemulsion comprising enzyme, effect compound and polyester monomers; and B) the polymerization of wall monomers from the group consisting of ethylenically unsaturated monomers, polyisocyanates and polyepoxides in the crude suspension of microparticles A. Furthermore, the present invention relates to microparticles M which can be obtained by means of the process according to the invention and also to an agrochemical formulation comprising microparticles M. In addition, the present invention relates to the use of microparticles M prepared according to the invention as component in colorants, cosmetics, drugs, biocides, plant protection agents, fertilizers, additives for food or animal fodder, or auxiliaries for polymers, paper, textiles, leather, detergents or cleaners. Finally, the invention also relates to a method for combating undesirable plant growth, to a method for combating undesirable insect or acarid infestation on plants and/or for combating phytopathogenic fungi, and to seeds treated with the agrochemical formulation.

专利号:TW-I491356-B
优先权日:2010-02-23
标题:Synthesis of 2-ethyl-3,7-dimethyl-6-(4-(trifluoromethoxy)phenoxy) quinolin-4-ylmethyl carbonate and a method for producing the same Crystallization of the pesticide composition

专利号:US-2009280986-A1
优先权日:2008-05-09
标 题 :Ft naphtha and ft diesel as solvents or carriers for pesticides and/or herbicides
发明人:SHEPPARD RICHARD O
权利人:RENTECH INC
摘要:A pesticide or herbicide formulation comprising an effective amount of a pesticide or herbicide in a carrier or solvent fluid, wherein the carrier or solvent fluid comprises a Fischer-Tropsch hydrocarbon produced via Fischer-Tropsch conversion of synthesis gas. A method of producing a pesticide or herbicide formulation by combining an amount of an herbicide or pesticide and a biodegradable solvent to form a pesticide or herbicide solution. A method of producing a pesticide or herbicide formulation by converting synthesis gas into Fischer-Tropsch products in the presence of a Fischer-Tropsch catalyst and combining at least one Fischer-Tropsch product with a pesticide or herbicide to create the formulation.

专利号:US-2015250175-A1
优先权日:2012-10-01
标 题:Pesticidally active mixtures comprising anthranilamide compounds
发明人:KOERBER KARSTEN; WACH JEAN-YVES; KAISER FLORIAN; POHLMAN MATTHIAS; DESHMUKH PRASHANT; CULBERTSON DEBORAH L; ROGERS W DAVID; GUNJIMA KOSHI; DAVID MICHAEL; BRAUN FRANZ JOSEF; LANGEWALD JUERGEN
权利人:BASF SE
摘要:The present invention relates to pesticidal mixtures comprising as active compoundsn 1) at least one pesticidally active anthranilamide compound of formula (I) nn n n n n n n n n n wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 and k are as defined in the description;n nandn 2) at least one pesticidally active compound II selected from a group M comprising acteylcholine esterase inhibitors, GABA-gated chloride channel antagonists, sodium channel modulators, nicotinic acteylcholine receptor agonists/antagonists, allosteric nicotinic acetylcholine receptor activitaors, chloride channel activators, juvenile hormone mimics, homopteran feeding blockers, mit grow inhibitors, inhibitors of mitochondrial bATP synthase, uncouplers of the oxidative phosphorylation, inhibitors of the chitin biosynthesis, moulting disruptors, ecdyson receptor agonists, octamin receptor agonists, inhibitors of the MET, voltage-dependent sodium channel blockers, inhibitors of the lipid synthesis, ryanodine receptor modulators and other compounds as defined in the description, in synergistically effective amounts. nn The invention relates further to methods and use of these mixtures for combating and controlling insects, acarids or nematodes in and on plants, and for protecting such plants being infested with pests, especially also for protecting plant propagation material, such as seeds.

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主要参考文献


1: Effects of the β1 Auxiliary Subunit on Modification of Rat Nav1.6 Sodium Channels Expressed in HEK293 Cells by the Pyrethroid Insecticides Tefluthrin and Deltamethrin Bingjun He, David M. Soderlund Toxicol Appl Pharmacol. Author manuscript; available in PMC 2017 Jan 15.Published in final edited form as: Toxicol Appl Pharmacol. 2016 Jan 15;
291: 58–69. Published online 2015 Dec 19. doi: 10.1016/j.taap.2015.12.007 6 Sodium Channels Expressed in Human Embryonic Kidney (HEK293) Cells by the Pyrethroid Insecticides Tefluthrin and Deltamethrin Bingjun He, David M. Soderlund Toxicol Appl Pharmacol. Author manuscript; available in PMC 2012 Dec 15.Published in final edited form as: Toxicol Appl Pharmacol. 2011 Dec 15; 257(3): 377–387. Published online 2011 Sep 29. doi: 10.1016/j.taap.2011.09.021 6 sodium channels by the pyrethroid insecticides S-bioallethrin, tefluthrin and deltamethrin Samantha J. McCavera, David M. Soderlund Neurotoxicology. Author manuscript; available in PMC 2013 Jun 1.Published in final edited form as: Neurotoxicology. 2012 Jun; 33(3): 384–390. Published online 2012 Mar 28. doi: 10.1016/j.neuro.2012.03.007 3 Voltage-Gated Sodium Channels Differ in Inactivation Properties and Sensitivity to the Pyrethroid Insecticide Tefluthrin Jianguo Tan, David M. Soderlund Neurotoxicology. Author manuscript; available in PMC 2010 Jan 1.Published in final edited form as: Neurotoxicology. 2009 Jan; 30(1): 81–89. Published online 2008 Nov 5. doi: 10.1016/j.neuro.2008.10.008 6 Sodium Channels Jianguo Tan, David M. Soderlund Toxicol Appl Pharmacol. Author manuscript; available in PMC 2011 Sep 15.Published in final edited form as: Toxicol Appl Pharmacol. 2010 Sep 15; 247(3): 229–237. Published online 2010 Jul 17. doi: 10.1016/j.taap.2010.07.001 PMCID: PMC2929565

合成参考文献


摘要:Pesticide Manual., 9(791), 1991
摘要:U.S. Environmental Protection Agency/Office of Prevention, Pesticides, and Toxic Substances. Reigart, J.R., Roberts, J.R. Recognition and Management of Pesticide Poisonings. 5th ed. 1999. EPA Document No. EPA 735-R-98-003, and available in electronic format at:
摘要:U.S. Environmental Protection Agency/Office of Prevention, Pesticides, and Toxic Substances. Reigart, J.R., Roberts, J.R. Recognition and Management of Pesticide Poisonings. 5th ed. 1999. EPA Document No. EPA 735-R-98-003, and available in electronic format at:
摘要:Zhou JL et al; Wat Res 31: 75-84 (1997)
摘要:USEPA; Fact Sheet: Review of the Relationship between Pyrethrins, Pyrethroid Exposure and Asthma and Allergies. (June 2009). Available from, as of November 18, 2009: https://www.epa.gov/oppsrrd1/reevaluation/paw-factsheet.html
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