CAS: 4795-86-2; (1R,2S,5R)-2,6,6-Trimethylbicyclo[3.1.1]Heptane
- 英文名称(1R,2S,5R)-2,6,6-Trimethylbicyclo[3.1.1]Heptane
- 中文名称(1R,2S,5R)-2,6,6-三甲基双环[3.1.1]庚烷
- IUPAC名称(1R,2S,5R)-2,6,6-trimethylbicyclo[3.1.1]heptane
- 其它别名(1R,2S)-2,6,6-Trimethylbicyclo[3.1.1]Heptane; (1R)-(+)-Cis-Pinane; Pinane, (1R)-(+)-Cis-; [1R-(1Alpha,2Beta,5Alpha)]-2,6,6-Trimethylbicyclo[3.1.1]Heptane; (1R)-(+)-Cis-Pinane, Terpene Standard; Pinane(1S,2S)-2,6,6-Trimethylbicyclo(3.1.1)Heptane; (1R,2R,5R)-Pinane; (1R,5R)-2α,6,6-Trimethylbicyclo[3.1.1]Heptane
- CAS编号4795-86-2
- MFCD编号:MFCD00066420
- EINECS号:225-352-4
- FDA UNII编号:FDS697478P
- 分子式:C10H18分子量:138.25
- 产品CID: 1475348
- 产品分类有机原料→分子砌块→桥环类化合物→其它桥环类化合物
- 相似结构搜索
- 产品信息参考
;;;; - InChIKey: XOKSLPVRUOBDEW-DJLDLDEBSA-N
- InChI=1S/C10H18/c1-7-4-5-8-6-9(7)10(8,2)3/h7-9H,4-6H2,1-3H3/t7-,8+,9+/m0/s1
- 计算化学: 氢键受体数*氢键供体数*可旋转键数*
相似化合物
4747-61-9 473-55-2 1824206-92-9物理性质
MSDS等安全信息
欧盟法规
ECHA物质ECHA物质C&L通报REACH预注册上下游产品
CAS号23516-36-1 (+)-cis-Pinan-2-ol | CAS号7785-53-7 (+)-α-松油醇 | CAS号18492-55-2 cis-pinan-2-ol合成工艺路线路线简述
📜(1R,5R)-(+)-β-Pinene置于tetrahydroquinoline-Pyridine-[pf6]-Iridium(II) Complex 氢气体系中,用 1,2-二氯乙烷 作为反应溶剂,化学反应生成 (1R)-(+)-Cis 蒎烷
参考文献:重新审查了crabtree的催化剂;配体对稳定性和耐久性的影响.
标题:重新审查了crabtree的催化剂;配体对稳定性和耐久性的影响.
摘要:三聚体形成的单膦单胺铱氢化催化剂随时间的失活程度强烈依赖于配体结构.试图对抗该过程的尝试导致观测到抗低聚催化剂.
DOI:10.1039/b711979H
专利信息
专利号:US-4537713-A
优先权日:1981-05-29
标题 :Process for the reduction of reducible groups and its use
发明人：ECKERT HEINER
权利人:ECKERT HEINER
摘要:The invention concerns a process for the reduction of groups containing unsaturated C,C-, C,N-,N,N-,N,O- bonds, especially of NO2-,NO-,NOH-,NR-,CN-,N3-,N2-groups or C=C or C-halogen- or acyl groups with hydrogen on MPc or with a suitable reduction agent on [MPc](-), whereby a platinum metal-phthalocyanine is used as the catalyst. It is possible that by the reversible change (control) of the oxidation phase z of the platinum metal from z>/=2 to z
专利号:US-6989450-B2
优先权日:2000-10-13
标 题:Synthesis of epothilones and related analogs
发明人：AVERY MITCHELL A
权利人:UNIV MISSISSIPPI
摘要:The present invention relates to methods for use in producing epothilones and analogs and derivatives thereof. A general method according to the present invention broadly comprises performing an aldol condensation of a first compound with a second compound thereby to form a third compound selected from the formulas: n n nand stereoisomers thereof, and performing a macrolactonization of the third compound. The present invention also provides chemical compounds, and methods for producing such chemical compounds, that are useful in producing epothilones and analogs and derivatives thereof.
专利号:WO-0230356-A2
优先权日:2000-10-13
标题:Synthesis of epothilones and relates analogs
专利号:EP-1414384-A2
优先权日:2000-10-13
标题:Synthesis of epothilones and relates analogs
专利号:CN-105111051-A
优先权日:2015-09-07
标题:A kind of green solvent for the synthesis of α-asarone and its application method
专利号:EP-1414384-A4
优先权日:2000-10-13
标 题:SYNTHESIS OF EPOTHILONES AND TRANSFORMATION ANALOGUE
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
[参考文献]: A Von Matt, Et Al. Selective Boron-Containing Thrombin Inhibitors--X-Ray Analysis Reveals Surprising Binding Mode. Bioorg Med Chem. 2000 Sep;8(9):2291-303.[参考文献]: Achim Stolle, Et Al. Thermal Isomerization Of (+)-Cis- And (-)-Trans-Pinane Leading To (-)-Beta-Citronellene And (+)-Isocitronellene. Chemistry. 2008;14(22):6805-14.
[参考文献]: C C Edsall, Et Al. Acute Toxicities To Larval Rainbow Trout Of Representative Compounds Detected In Great Lakes Fish. Bull Environ Contam Toxicol. 1991 Feb;46(2):173-8.
[参考文献]: E R Leite, Et Al. Synthesis Of Mesoporous Silica With Embedded Nickel Nanoparticles For Catalyst Applications. J Nanosci Nanotechnol. 2002 Feb;2(1):89-94.
[参考文献]: M Carrier, Et Al. Role Of Thromboxane And Angiotensin In Cyclosporine-Induced Renal Vasoconstriction In The Dog. J Heart Lung Transplant. 1993 Sep-Oct;12(5):851-5.
合成参考文献
摘要:Chessum, N.; Couty, S.; Jones, K., Science of Synthesis, (2009) 48, 281.
摘要:Chessum, N.; Couty, S.; Jones, K., Science of Synthesis, (2009) 48, 325.
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