CAS: 25423-56-7; 1,4,7,10-Tetrathiacyclododecane

该化合物是一个环状化合物,其特点是环状结构由12个环状结构组成,内含4个硫磺原子和8个甲基(-CH2)组,这种独特的安排具有不同特性,包括高度的灵活性和以金属离子形成稳定的复合体的能力,使其在协调化学方面有用;硫磺原子的存在有助于其在催化和材料科学中的潜在应用,特别是在传感器和纳米材料的开发方面.该化合物一般没有色素,可展示出一个相对较低的熔点.其溶性在极地和非极地溶剂中的溶性各异,使各种化学环境中的多功能性各异.此外,还有1,4,7,10-四环环十二环十二烷作为木化合物的能力,提高了其在金属复合中的重要性,可在各个领域,包括医药化学和环境科学中使用.

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505-29-3 6573-11-1 24194-61-4

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上下游产品

3,6-dithia°Ctan-1,8-dithiol 1,2-bis(2-chloroethylthio)ethane 2,2'-ethane-1,2-diylbissulfanyl-bis-ethanol ethylene dibromide 4)(PPh3)][PF6][RuCl([12]aneS4)(PPh3)][PF6]

合成工艺路线路线简述

    📜3,6-二硫杂-1,8-辛二醇置于盐酸,Caesium Carbonate,硫脲体系中,用 N,N-二甲基甲酰胺 用作溶剂,化学反应 3.0H,反应生成1,4,7,10-四硫环十二烷
    参考文献:Yatsimirskii,K. B.; Pavlishchuk,V. V.; Strizhak,P. E.,Journal Of General Chemistry Of The Ussr,1987,Vol. 57,P. 2453-2457
    标题:Yatsimirskii,K. B.; Pavlishchuk,V. V.; Strizhak,P. E.,Journal Of General Chemistry Of The Ussr,1987,Vol. 57,P. 2453-2457

    海关参考信息

    专利信息


    专利号:US-6143849-A
    优先权日:1996-11-27
    标题:Synthesis of acrylate and alkyl acrylate monomers and polymers of chelators
    发明人:PURANIK DHANANJAY B; CHANG EDDIE L
    权利人:US NAVY
    摘要:Multifunctional chelating groups are covalently bound to acrylate or methylate monomers. These monomers are polymerized. The resulting polymers are highly substituted with chelating groups and are useful for removing metals from fluids such as liquid hydrocarbons. An example of a polymer according to this invention has the following structure: ##STR1## wherein Q is a saturated or unsaturated aliphatic group having 1 to about 200 carbon atoms and is typically an unsubstituted unbranched alkylene, a substituted unbranched alkylene, a substituted branched alkylene, or an unsubstituted branched alkylene, and is an integer having a value of at least 1.

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    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: Ayelet Gafni, Et Al. Complexes Of Macrocycles With Gamma-Cyclodextrin As Deduced From Nmr Diffusion Measurements. J Org Chem. 1997 Jan 10;62(1):120-125.

    合成参考文献


    参考文献:10.1039/b911393b
    摘要:Gianferrara T, Bratsos I, Iengo E, Milani B, Ostrić A, Spagnul C, Zangrando E, Alessio E. Synthetic strategies towards ruthenium-porphyrin conjugates for anticancer activity. Dalton Trans. 2009 Dec 28;(48):10742–56. doi: 10.1039/b911393b.
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