CAS: 696-71-9; Cyclooctanol

该化合物是一种循环酒精,其分子式为C8H16O,其特点是八人碳环,具有氢氧基组;它是有机合成的多用途中间体,在香气,增塑剂和特殊化学品的生产中特别有用;其循环结构具有稳定性和回活动性,使其对环状开裂和功能化反应具有价值;Cycloctanol还被用作单体或修饰剂;该化合物在普通有机溶剂中表现出中等溶性,在受控制的条件下表现出可预测的再活动性;其明确界定的立体化学和顺从性灵活性进一步提高其在非对称合成和催化应用中的效用.

结构式图片

相似化合物

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合成工艺路线路线简述

    📜环辛烷置于水,双氧水,C17H29F6Fen5O6S2体系中,用 乙腈 作为反应溶剂,化学反应生成 环辛醇
    参考文献:空间位阻对 Fev(O)(Oh) 互变异构体在立体特异性 C-H 羟基化反应中反应性影响的研究
    标题:空间位阻对 Fev(O)(Oh) 互变异构体在立体特异性 C-H 羟基化反应中反应性影响的研究
    摘要:两个新的四齿 N4 配体 (L N4),L N4 = Me2,Me2 Pyztacn (1-(2-(3,5-Dimethyl-1 H-Pyrazol-1-yl)Ethyl)-4,7-Dimethyl-1,4,7-三氮杂环壬烷)和me2,Me Imtacn (1-((1-甲基-1H-咪唑-1-基)甲基)-4,7-二甲基-1,4,7-三氮杂环壬烷)已被合成并它们相应的 Fe(Ii) 配合物 [fe Ii (Me2,Me2 Pyztacn)(Cf 3 So 3) 2],1 Pz和 [fe Ii (Me2,Me Imtacn)(Cf3 So 3) 2],1 Im已被制备和表征.使用过氧化氢作为氧化剂,配合物1 Pz和1 Im以优异的效率催化烷烃 C-H 键的羟基化.c-H 羟基化的高 H/d 动力学同位素效应值,金刚烷氧化中的大归一化叔/仲 C-H (C3/c2)
    DOI:10.1039/d2Dt00725H

    海关参考信息

    专利信息


    专利号:US-10711138-B2
    优先权日:2016-04-08
    标题:Intermediates and procedures for the synthesis of functional materials
    发明人:KIRSCH PEER; GUNST SUSANN
    权利人:MERCK PATENT GMBH
    摘要:The present invention relates to heteroaromatic compounds which have two different reactive groups, their use in the synthesis of asymmetrically substituted compounds, and synthesis processes in which the compounds according to the invention are reacted sequentially with two different compounds, whereby an asymmetrically substituted compound is formed.

    专利号:US-2013338369-A1
    优先权日:2011-03-07
    标 题 :Process for the Synthesis of Aminobiphenylene
    发明人:HEINRICH MARKUS; PRATSCH GERALD
    权利人:HEINRICH MARKUS; PRATSCH GERALD; BASF SE
    摘要:The present invention relates to a process for the synthesis of 2-aminobiphenylene and derivatives thereof by reacting a benzene diazonium salt with an aniline compound under basic reaction conditions.

    专利号:US-4920204-A
    优先权日:1987-11-12
    标题:Ceric hydrocarbyloxy nitrates and their use in organic synthesis
    发明人:GRADEFF PETER S; SCHREIBER FRED G; GROSBOIS JEAN; MAUERMANN HEIKO
    权利人:RHONE POULENC IND
    摘要:Ceric hydrocarbyloxy nitrates having the general formula: x = 1, 2 or 3 are obtained by reaction of ceric ammonium nitrate with x moles of ammonia and an aliphatic, cycloaliphatic or aromatic alcohol having from two to twenty carbon atoms, and are useful in the preparation of ceric hydrocarbyl oxides difficult or expensive of access by other routes, and in synthesis of other organic ceric compounds.

    专利号:US-6166212-A
    优先权日:1999-05-20
    标 题 :Process for the synthesis of N-(hydroxyalkoxy) substituted hindered amine stabilizers
    发明人:GALBO JAMES P; DETLEFSEN ROBERT E; DIFAZIO MICHAEL P; GRACE HENRY C; KUELL CHRISTOPHER
    权利人:CIBA SC HOLDING AG
    摘要:N-(Hydroxyalkoxy) hindered amine stabilizers are prepared by reacting the corresponding N-oxyl compound with a peroxide or organic hydroperoxide and a catalytic amount of a metal salt or metal-ligand complex in an alcohol solvent. These N-(hydroxyalkoxy) hindered amines are particularly useful as stabilizers for polyolefins, thermoplastic polyolefins and automotive coating compositions.

    专利号:US-7910775-B2
    优先权日:2003-04-18
    标题 :Synthesis of 2-Hydroxy-N,N-dimethyl-3-[[2-[[1(R)-(5-methyl-2-furanyl)propyl]amino]-3,4-dioxo-1-cyclobuten-1-yl]amino]benzamide
    发明人:YIN JIANGUO; FU XIAOYONG; ZHANG SHUYI; MCALLISTER TIMOTHY L; KIM-MEADE AGNES S; WINTERS JASON L; SUDHAKAR ANANTHA; SCHUMACHER DORIS P
    权利人:SCHERING CORP
    摘要:Disclosed is a process for making the compound of formula I: n nusing the compounds of formulas II, Q, and XI or XII:n n nwherein A is selected from the group consisting of Br, Cl and I (with Br being preferred); and R represents (C 1 -C 10 )alkyl. Also disclosed are intermediate compounds that are made in the disclosed process.

    专利号:US-5637757-A
    优先权日:1995-04-11
    标 题 :One-pot synthesis of ring-brominated benzoate compounds
    发明人:HILL JOHN E; FAVSTRITSKY NICOLAI A; MAMUZIC RASTKO I; BHATTACHARYA BHABATOSH
    权利人:GREAT LAKES CHEMICAL CORP
    摘要:A method of preparing tetrabromobenzoate compounds from tetrabromophthalic anhydride by reacting tetrabromophthalic anhydride with alcohol in the presence of a decarboxylation catalyst. The reaction may be carried out in an excess of alcohol, or with a near stoichiometric amount of alcohol by performing the reaction in an inert solvent.

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    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Zaidlewicz, M.; Krzemiński, M. P.; Dzieleńdziak, A., Science of Synthesis, (2009) 48, 366.
    摘要:Kostikov, R. R.; Khlebnikov, A. F.; Sokolov, V. V., Science of Synthesis, (2010) 47, 803.
    摘要:Braverman, S.; Cherkinsky, M., Science of Synthesis Knowledge Updates, (2014) 3, 201.
    摘要:Zimmer, R.; Trawny, D., Science of Synthesis Knowledge Updates, (2013) 4, 161.
    摘要:Vandamme, M.; Paquin, J.-F., Science of Synthesis Knowledge Updates, (2016) 1, 403.
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