CAS: 51064-65-4; ((4R,5R)-2,2-Dimethyl-1,3-Dioxolane-4,5-Diyl)Bis(Methylene) Bis(4-Methylbenzenesulfonate)
该化合物是化学化合物,其特征是二氧醇环状结构,有助于其稳定性和反应性.两个甲醇组的存在增强了其在极地溶剂中的溶解性,而全氟辛烷磺酸组则增加了其反应,使其在各种化学反应中,特别是在有机合成中有所作用.该化合物一般没有色素,可粉黄黄色液体或固体,视其形态和纯度而定.其分子结构包括多种功能组,可促进与其他分子的相互作用,使其成为合成化学中的多用途再生剂.其立体化学学学显示的4,5R,5R)提出了原子的具体空间安排,可影响化合物在生物系统中的再活性和相互作用.应参考安全数据来处理,因为磺化合物可能表现出不同程度的毒性和环境影响.
- 英文名称((4R,5R)-2,2-Dimethyl-1,3-Dioxolane-4,5-Diyl)Bis(Methylene) Bis(4-Methylbenzenesulfonate)
- 中文名称1,4-甲苯磺酰基-2,3-异亚丙基苏糖醇
- IUPAC名称((4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene) bis(4-methylbenzenesulfonate)
- 其它别名1,3-Dioxolane-4,5-dimethanol,2,2-dimethyl-, bis(4-methylbenzenesulfonate), (4R,5R)- (9CI); 1,3-Dioxolane-4,5-dimethanol, 2,2-dimethyl-, bis(4-methylbenzenesulfonate),(4R-trans)-; (+)-1,4-Di-O-p-toluenesulfonyl-2,3-O-isopropylidene-D-threitol; (4R,5R)-4,5-Bis[[[(4-methylphenyl)sulfonyl]oxy]methyl]-2,2-dimethyl-[1,3]dioxolane; 1,4-Di-O-p-toluenesulfonyl-2,3-O-isopropylidene-D-threitol; 1,4-Di-O-tosyl-2,3-O-isopropylidene-D-threitol; 1,4-Ditosyl-2,3-O-isopropylidene-D-threitol; 2,3-Isopropylidene-D-threitol-1,4-ditosylate
- CAS编号51064-65-4
- MFCD编号:MFCD00063235
- EINECS号:256-943-5
- 分子式:C21H26O8S2分子量:470.56
- 产品CID: 1499236
- 产品分类生物化工 → 糖类化合物 → 单糖
物理性质
MSDS等安全信息
上下游产品
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📜3,4-Di-O-Isopropylidene-D-Mannitol置于吡啶,Sodium Tetrahydroborate,Sodium Periodate体系中,化学反应 5.0H,反应生成 1,4-甲苯磺酰基-2,3-异亚丙基苏糖醇
参考文献:Holy,Antonin,Collection Of Czechoslovak Chemical Communications,1982,Vol. 47,# 1,P. 173-189
标题:Holy,Antonin,Collection Of Czechoslovak Chemical Communications,1982,Vol. 47,# 1,P. 173-189
海关参考信息
- 2902300000-甲苯
2905122000-异丙醇
2905310000-1,2-乙二醇
2905320000-1,2-丙二醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-5886190-A
优先权日:1993-10-04
标 题:Rapid synthesis and use of 18F-fluoromisonidazole and analogs
发明人：WALLACE SIDNEY; YANG DAVID J; CHERIF ABDALLAH
摘要:The present invention involves a rapid synthesis of 18F-FMISO and analogs thereof. New precursors such as 1-(2'-nitro-1'-imidazolyl)-2-0-acetyl-3-0-tosylpropanol, glycerol-1,3-ditosylate-2-0-acetylate, 1-(2'-nitro-1'-imidazolyl)-2,3-0-diacetyl-4-0-tosylbutanol and threitol 1,4-di-tosylate-2,3-0-diacetylate, are also important aspects of the invention. A further aspect of the invention is the development of a hydrophilic PET ligand to image tumor hypoxia. Erythrotosyl analogue of 2-nitroimidazone (Ts-ETNIM) was prepared from a mixture of 2-nitromidazole, ditosylthreitol and cesium carbonate at 60 DEG C. for 1 hr. Ts-ETNIM was isolated at 70% yield. [18F]fluoroerythronitroimidazole (FETNIM) was then prepared from Ts-ETNIM and K18F/kryptofix TM . The yield for [18F]FETNIM was 26-30% (60 min, decay corrected). Results of biodistribution and PET studies indicate that [18F]FETNIM has the potential to detect tumor hypoxia and is indicated to be less neurotoxic.
专利号:US-2007249590-A1
优先权日:2005-10-28
标 题:Substituted indolo[2,3-a]pyrrolo[3,4-c]carbazole compounds useful in treating kinase disorders
发明人：WILSON LAWRENCE J; MURRAY WILLIAM V; YANG SHYH-MING; YANG CANGMING; WANG BINGBING
权利人:WILSON LAWRENCE J; MURRAY WILLIAM V; YANG SHYH-MING; YANG CANGMING; WANG BINGBING
摘要:The present invention is directed to substituted indolo[2,3-a]pyrrolo[3,4-c]carbazole compounds of formula (I): n nand forms thereof and their synthesis and use as protein kinase inhibitors and interactions thereof.
专利号:WO-9509844-A1
优先权日:1993-10-04
标 题 :Rapid synthesis and use of 18f-fluoromisonidazole and analogs
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
参考文献:10.1021/ic011239z
摘要:Herd O, Hoff D, Kottsieper KW, Liek C, Wenz K, Stelzer O, Sheldrick WS. Water-soluble phosphines. 17.(1) novel water-soluble secondary and tertiary phosphines with disulfonated 1,1'-biphenyl backbones and dibenzophosphole moieties. Inorg Chem. 2002 Oct 07;41(20):5034–42. doi: 10.1021/ic011239z.
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