果糖 以87.7%的收率获得果糖二丙酮 参考文献:Structure-sweetness Relationships For Fructose Analogs. Part I. Synthesis And Evaluation Of Sweetness Of 5-Deoxy-D-Threo-Hexulose 标题:Structure-sweetness Relationships For Fructose Analogs. Part I. Synthesis And Evaluation Of Sweetness Of 5-Deoxy-D-Threo-Hexulose 摘要:5-去氧-D-己糖("5-去氧果糖","5-去氧山梨糖")已从d-果糖经过六步制备.2,3-O-异丙基醚基-β-D-果糖吡喃糖与亚磺酰氯反应的关键步骤中,仅产生5-氯-5-去氧-2,3-O-异丙基醚基-α-L-山梨糖吡喃糖.在溶液中,"5-去氧果糖"仅以2C5(D)吡喃状形式存在,并被发现比l-山梨糖甜得多,几乎与d-果糖一样甜.对这种意外的甜味结果进行了评论. Doi:10.1139/v82-258
专利号:FR-2655347-A1 优先权日:1989-12-04 标 题:PROCESS FOR THE SYNTHESIS OF ACETONIDES OF MONOSACCHARIDES AND / OR THEIR FUNCTIONALIZED DERIVATIVES FROM (MONO-, DI-, POLY-) SACCHARIDES.
专利号:WO-9005135-A2 优先权日:1988-11-02 标 题 :Process for the specific synthesis of new dithiocarbamic acid esters by substituting hydroxylated sites on mono- or polyhydroxylated molecules; products obtained by this process and their application
专利号:IE-893771-A1 优先权日:1989-11-27 标题:Process for the specific synthesis of new dithiocarbamic¹acid esters by substitution of hydroxylated sites on mono-or¹polyhydroxylated molecules, products obtained therefrom and¹their applications
专利号:EP-0371837-A2 优先权日:1988-11-02 标 题:Process for the synthesis of esters of dithiocarbamic acids by substitution of hydroxylated positions of mono- or polyhydroxylated molecules, products of this process and their uses
专利号:JP-H04500677-A 优先权日:1988-11-02 标题 :A special method for the synthesis of novel dithiocarbamate esters by replacing the hydroxylated sites of mono- or polyhydroxylated molecules, the products obtained by this method and their applications.
参考标题:Direct Synthesis Of Deuterium-Labeled O-, S-, N-Vinyl Derivatives From Calcium Carbide 作者:Maria S. Ledovskaya,Vladimir V. Voronin,Konstantin S. Rodygin,Alexandra V. Posvyatenko,Ksenia S. Egorova,Valentine P. Ananikov |发布日期:2019.8 摘要:Was Used To Complete The Formation Of The D2C=c(D)-X Fragment (X = O, S, N). Polymerization Of A Selected Trideuterovinylated Compound Showed A Very Promising Potential Of These Substances In The Synthesis Of Labeled Polymeric Materials. Biological Activity Of The Synthesized Trideuterovinyl Derivatives Was Evaluated And The Results Indicated A Significant Increase Of Cytotoxicity Upon Deuteration.
合成参考文献
参考文献:10.1016/s0008-6215(02)00046-0 摘要:Popek T, Lis T. Synthesis and X-ray structures of sulfate esters of fructose and its isopropylidene derivatives. Part 1: 2,3:4,5-di-O-isopropylidene-beta-D-fructopyranose 1-sulfate and 4,5-O-isopropylidene-beta-D-fructopyranose 1-sulfate. Carbohydr Res. 2002 Apr 30;337(9):787–801. doi: 10.1016/s0008-6215(02)00046-0. 摘要:Kleemann, A.; Engel, J.; Kutscher, B.; Reichert, D., Pharmaceutical Substances[Online], Thieme: Stuttgart, (2003). 摘要:Skrydstrup, T., Science of Synthesis, (2002) 4, 273.