CAS: 88590-00-5; 2-Phenyl-9H-Carbazole

该化合物其结构特征为:由带有在2位置上附着的一组苯基的碳化二甲醇核心组成;该化合物是carbazole家族的一部分,以其芳香特性和有机电子产品的潜在应用而著称,例如发光二极管和有机太阳能电池;典型的具有良好的热稳定性和光光光发特性,使之适合各种光电子应用;该苯团体的存在增强了其溶性,并改变了其电子特性,这在设备制造方面可能具有优势;此外,2-苯-9H-carbazole可能与其他材料发生有趣的互动,影响其在复合系统中的性能;其合成往往涉及多步的有机反应,并且可以使用NMR光谱和质光谱学等技术定性.

结构式图片

相似化合物

42448-04-4 106851-31-4 56525-79-2

物理性质

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上下游产品

1,4-dibromo-2-nitrobenzene phenylboronic acid N-phenyl-[1,1′-biphenyl]-3-amine 4-(4-bromophenyl)bromobenzene 9-(3-nitrophenyl)-2-phenyl-9H-carbazole 9-(4-bromophenyl)-2-phenyl-9H-carbazole 9-(4-(benzyloxy)phenyl)-2-phenyl-9H-carbazole

合成工艺路线路线简述

  • 5122-94-1 = 88590-00-5
    反应条件:1.1 Reagents: Potassium Carbonate,Triphenylphosphine Catalysts: Palladium Diacetate Solvents: 1,2-Dichlorobenzene; 24 H,180 °C
    标题:One-Pot Synthesis Of Carbazoles Via Tandem C-C Cross-Coupling And Reductive Amination
    作者:Goo,Deuk-Young; Woo,Sang Kook
    参考文献:Organic & Biomolecular Chemistry 日期:2016 卷标:14(1) 页码:122-130]

    60366-15-6 = 88590-00-5
    反应条件:1.1 Reagents: Triphenylphosphine Solvents: 1,2-Dichlorobenzene; 5 H,180 °C
    标题:Reversal Reactivity Of β-Alkylnitroalkenes As 1,3-Binucleophiles: Application To Nitroarenes Using Organocatalysis
    作者:Majee,Debashis; Goud,S. Banuprakash; Guin,Soumitra; Rathor,Shikha S.; Patel,Ashvani K.; Et Al
    参考文献:Asian Journal Of Organic Chemistry 日期:2021 卷标:10(7) 页码:1650-1654]

    = 88590-00-5
    反应条件:1.1 Reagents: Silica Solvents: Acetone,Water; 48 H,28 - 32 °C
    标题:Visible-Light-Promoted Intramolecular C-H Amination In Aqueous Solution: Synthesis Of Carbazoles
    作者:Yang,Lizheng; Zhang,Yipin; Zou,Xiaodong; Lu,Hongjian; Li,Guigen
    参考文献:Green Chemistry 日期:2018 卷标:20(6) 页码:1362-1366]

    = 88590-00-5
    反应条件:1.1 Reagents: Acetic Acid,Manganese Oxide (Mno2) Catalysts: Cupric Acetate Solvents: Dimethylformamide; 1 H,200 °C1.2 Reagents: Ethylenediamine Solvents: Water
    标题:Synthesis Of Carbazoles By Copper-Catalyzed Intramolecular C-H/n-H Coupling
    作者:Takamatsu,Kazutaka; Hirano,Koji; Satoh,Tetsuya; Miura,Masahiro
    参考文献:Organic Letters 日期:2014 卷标:16(11) 页码:2892-2895]

    2243-47-2 + 694-80-4 = 88590-00-5
    反应条件:1.1 Reagents: Cesium Carbonate Catalysts: Palladium Solvents: Dimethyl Sulfoxide; 25 Min,180 °C1.2 Reagents: Ethyl Acetate
    标题:Convenient One-Pot Synthesis Of 9H-Carbazoles By Microwave Irradiation Employing A Green Palladium-Based Nanocatalyst
    作者:Steingruber,H. Sebastian; Mendioroz,Pamela; Volpe,Maria A.; Gerbino,Dario C.
    参考文献:Synthesis 日期:2021 卷标:53(21) 页码:4048-4058]

    76129-23-2 = 88590-00-5
    反应条件:1.1 Reagents: Cupric Acetate,Potassium Carbonate,Bis(Pinacolato)Diborane Catalysts: [(1,2,3,4,5-η)-1,2,3,4,5-Pentamethyl-2,4-Cyclopentadien-1-Yl]Bis(1,1,1-Trifluoro... Solvents: O-Xylene; 24 H,130 °C
    标题:Amino-Directed Rhiii-Catalyzed C-H Activation Leading To One-Pot Synthesis Of N-H Carbazoles
    作者:Jiang,Qibai; Duan-Mu,Dandan; Zhong,Wei; Chen,Hao; Yan,Hong
    参考文献:Chemistry - A European Journal 日期:2013 卷标:19(6) 页码:1903-1907]

    98-80-6 + 3460-18-2 = 88590-00-5
    反应条件:1.1 Reagents: Potassium Carbonate,Triphenylphosphine Catalysts: Palladium Diacetate Solvents: 1,2-Dichlorobenzene; 48 H,180 °C
    标题:Efficient Synthesis Of Aryl-Substituted Carbazoles Via Tandem Double Or Triple Suzuki Coupling And Cadogan Cyclization
    作者:Kim,Hyeong Seok; Goo,Deuk-Young; Woo,Sang Kook
    参考文献:Tetrahedron 日期:2017 卷标:73(11) 页码:1413-1423]

    76129-23-2 = 88590-00-5
    反应条件:1.1 Reagents: Pivalic Acid,1-Methylnaphthalene Catalysts: Cupric Acetate,Iridium,Di-μ-Chlorodichlorobis[(1,2,3,4,5-η)-1,2,3,4,5-Pentamethyl-2,4-Cyclopen... Solvents: N-Methyl-2-Pyrrolidone; 3 H,120 °C; Cooled
    标题:Direct Synthesis Of N-H Carbazoles Via Iridium(Iii)-Catalyzed Intramolecular C-H Amination
    作者:Suzuki,Chiharu; Hirano,Koji; Satoh,Tetsuya; Miura,Masahiro
    参考文献:Organic Letters 日期:2015 卷标:17(6) 页码:1597-1600]

    98-80-6 + 3652-90-2 = 88590-00-5
    反应条件:1.1 Reagents: Tripotassium Phosphate Catalysts: Tris(Dibenzylideneacetone)Dipalladium,2-Dicyclohexylphosphino-2′,6′-Dimethoxybiphenyl Solvents: Toluene; 24 H,90 °C
    标题:Chiral Phosphoric Acid Catalyzed Atroposelective C-H Amination Of Arenes
    作者:Xia,Wang; An,Qian-Jin; Xiang,Shao-Hua; Li,Shaoyu; Wang,Yong-Bin; Et Al
    参考文献:Angewandte Chemie 日期:2020 卷标:59(17) 页码:6775-6779
📜2,5-二溴硝基苯置于2-双环己基膦-2',6'-二甲氧基联苯,Potassium Phosphate,Tris-(Dibenzylideneacetone)Dipalladium(0),亚磷酸三乙酯体系中,用 乙醇,水,甲苯 作为反应溶剂,化学反应 18.0H,反应生成 2-苯基-9H-咔唑
参考文献:一种稳定的有机发光二极管
标题:一种稳定的有机发光二极管
摘要:一种有机发光二极管,其特征是所述的有机发光二极管由一个阴极,一个阳极以及阴极与阳极间的有机半导体层构成.有机半导体层发光层中使用一有机半导体化合物作为主体材料,其通式为:其特征是所述化合物(ⅰ)中的ed1与ed2可以相同或不同,为带n,O,S的芳杂环的电子供应基团,优选基团为含有n原子的咔唑基,取代咔唑基;含有o原子的呋喃基,取代呋喃基,苯并呋喃基,取代苯并呋喃基,噻吩基,取代噻吩基,苯并噻吩基,取代苯并噻吩基,有利于改善电荷注入的平衡性与热稳定性,获得高稳定,高效率及长寿命的发光oled.

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合成参考文献


摘要:Ros, A.; Fernández, R.; Lassaletta, J. M., Science of Synthesis: Catalytic Transformations via CH Activation, (2015) 2, 428.
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