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CAS号124-38-9 二氧化碳 | CAS号106-37-6 对二溴苯 | CAS号615-59-8 2,5-二溴甲苯 | CAS号615-54-3 1,2,4-三溴苯 | CAS号3460-18-2 2,5-二溴硝基苯 | CAS号151-50-8 氰化钾 | CAS号88-65-3 邻溴苯甲酸 | CAS号32937-55-6 1-(2,5-二溴苯基)乙酮 | CAS号552-16-9 2-硝基苯甲酸 | CAS号65-85-0 苯甲酸 | CAS号147034-01-3 2,5-二溴苄醇 | CAS号17680-55-6 7-溴-1,2,3,4-四氢异喹啉 | CAS号19725-82-7 5-溴-2-(羧基甲基)苯甲酸 | CAS号22721-16-0 5-溴-2-(甲基氨基)苯甲酸 | CAS号26819-10-3 3-溴-N-乙基苯甲酰胺 | CAS号89-55-4 5-溴水杨酸 | CAS号585-76-2 3-溴苯甲酸 | CAS号65-85-0 苯甲酸 | CAS号88-65-3 邻溴苯甲酸 | CAS号80031-02-3 N-乙基-2-溴苯甲酰胺2,5-二溴苯乙酮置于sodium Hypobromide体系中,化学反应生成 2,5-二溴苯甲酸
参考文献:The Swamping Catalyst Effect. Ii. Nuclear Halogenation Of Aromatic Aldehydes And Ketones1,2
标题:The Swamping Catalyst Effect. Ii. Nuclear Halogenation Of Aromatic Aldehydes And Ketones1,2
摘要:
DOI:10.1021/jo01104A003
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专利信息
专利号:US-7943723-B2
优先权日:2006-12-21
标 题:Process for the synthesis of ethers of aromatic acids
发明人:RITTER JOACHIM C
权利人:DU PONT
摘要:The inventions disclosed herein include processes for the preparation of an ether of an aromatic acid, processes for the preparation of products into which such an ether can be converted, the use of such processes, and the products obtained and obtainable by such processes. A key feature of the processes described is the use of a solvent comprising an alcohol ROH and an alcoholate RO − M + .
专利号:US-8207374-B2
优先权日:2006-12-21
标 题:Process for the synthesis of ethers of aromatic acids
发明人:RITTER JOACHIM C
权利人:RITTER JOACHIM C; DU PONT
摘要:Ethers of aromatic acids are produced from halogenated aromatic acids in a reaction mixture containing a copper (I) or copper (II) source and a diketone ligand that coordinates to copper.
专利号:US-2011060118-A1
优先权日:2009-09-02
标 题:Process for the synthesis of fluorinated ethers of aromatic acids
发明人:RITTER JOACHIM C; MOLOY KENNETH GENE; POLLINO JOEL M; MAHAJAN DU SURBHI
权利人:DU PONT
摘要:Fluorinated ethers of aromatic acids are produced from halogenated aromatic acids in a reaction mixture containing a copper (I) or copper (II) source and a Schiff base ligand that coordinates to copper. The fluorinated ethers of aromatic acids made using the process described herein can be applied to, e.g., fibers, yarns, carpets, garments, films, molded parts, paper and cardboard, stone, and tile to impart soil, water and oil resistance. By incorporating the fluorinated ethers of aromatic acids, or diesters thereof, into polymer backbones, more lasting soil, water and oil resistance, as well as improved flame retardance, can be achieved.
专利号:US-7985825-B2
优先权日:2006-12-21
标 题 :Process for the synthesis of ethers of aromatic acids
发明人:RITTER JOACHIM C
权利人:DU PONT
摘要:Ethers of aromatic acids are produced from halogenated aromatic acids in a reaction mixture containing a halogenated aromatic acid such as is described by the structure of Formula II n nwherein each X is independently Cl, Br or I; the reaction mixture further comprising;n (i) a polar protic solvent, a polar aprotic solvent or an alcoholic solvent containing the alcoholate RO-M+ (wherein M is Na or K), wherein the polar protic solvent, polar aprotic solvent or alcoholic solvent is either ROH or is a solvent that is less acidic than ROH; (ii) a copper (I) or copper (II) source; and (iii) an amino acid ligand that coordinates to copper, wherein the ligand comprises an amino acid in which the amine nitrogen and the carboxyl carbon are separated by no more than two carbon atoms.
专利号:US-2011060117-A1
优先权日:2009-09-02
标题:Process for the synthesis of fluorinated ethers of aromatic acids
发明人:RITTER JOACHIM C; MOLOY KENNETH GENE; POLLINO JOEL M; MAHAJAN DU SURBHI
权利人:DU PONT
摘要:Fluorinated ethers of aromatic acids are produced from halogenated aromatic acids in a reaction mixture containing a copper (I) or copper (II) source and a diamine ligand that coordinates to copper. The fluorinated ethers of aromatic acids made using the process described herein can be applied to, e.g., fibers, yarns, carpets, garments, films, molded parts, paper and cardboard, stone, and tile to impart soil, water and oil resistance. By incorporating the fluorinated ethers of aromatic acids, or diesters thereof, into polymer backbones, more lasting soil, water and oil resistance, as well as improved flame retardance, can be achieved.
专利号:US-2011060161-A1
优先权日:2009-09-02
标题 :Process for the synthesis of fluorinated ethers of aromatic acids
发明人:RITTER JOACHIM C; MOLOY KENNETH GENE; POLLINO JOEL M; DU SURBHI MAHAJAN
权利人:DU PONT
摘要:Fluorinated ethers of aromatic acids are produced from halogenated aromatic acids in a reaction mixture containing a copper (I) or copper (II) source and a diketone ligand that coordinates to copper. The fluorinated ethers of aromatic acids made using the process described herein can be applied to, e.g., fibers, yarns, carpets, garments, films, molded parts, paper and cardboard, stone, and tile to impart soil, water and oil resistance. By incorporating the fluorinated ethers of aromatic acids, or diesters thereof, into polymer backbones, more lasting soil, water and oil resistance, as well as improved flame retardance, can be achieved.