CAS: 52562-19-3; 2-(Prop-1-En-2-yl)Aniline

该化合物是一种有机化合物,其特点是异丙基化合物组和厌食动物,该化合物一般是无色的,可粉黄液,具有独特的芳香味,由于异丙基化合物组的存在,该化合物具有反应性,可参与各种化学反应,包括聚合物和电益替代.分子的阴性部分有助于其基本性和形成氢联结的潜力,使其成为有机合成的有用中间体.此外,2-异丙基氨可能会表现出有机溶剂溶性以及水中溶性有限溶性等特性,这对许多厌食衍生物来说很常见.应当考虑到安全因素,因为通过皮肤吸入或吸收可能会有害,实验室环境应遵循适当的处理程序.

结构式图片

物理性质

MSDS等安全信息

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

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合成工艺路线路线简述

    📜邻硝基苯乙酮置于铁粉,溶剂黄146体系中,用 四氢呋喃,乙醇 作为反应溶剂,化学反应 2.0H,反应生成 2-异丙烯苯基苯胺
    参考文献:酰胺在环化反应中作为亚氨基自由基的前体
    标题:酰胺在环化反应中作为亚氨基自由基的前体
    摘要:酰胺已成功地用作亚胺基自由基的前体,用于自由基环化.酰胺已通过与光气反应反应生成亚氨酰氯,然后与苯硒化钾反应,已转化为亚氨基酰硒化物.亚胺基硒化物与氢化三丁基锡(bu 3 Snh)作为自由基介体反应,三乙基硼烷或aibn作为引发剂,反应生成亚胺基自由基用于环化反应.酰亚胺基已被环化到烯烃上以产生2,3-取代的吲哚和-喹啉,并且还被吡咯和吲哚上以产生双环和三环杂芳烃.
    DOI:10.1016/j.Tet.2006.10.030

    海关参考信息

    专利信息


    专利号:US-2023348492-A1
    优先权日:2020-05-04
    标题:Photochemical synthesis of marmycin analogues through a new photochemical reaction involving carbonyl compounds
    发明人：SIVAGURU JAYARAMAN; KANDAPPA SUNIL KUMAR; VALLOLI LAKSHMY KANNADI
    权利人:BOWLING GREEN STATE UNIV
    摘要:Photochemical reactivity of carbonyl compounds leading to the synthesis of the Marmycin core is described. The photochemical reactivity involves an excited state reaction that provides convenient access to bicyclic compounds. The disclosed reactivity is a new photochemical pathway involving 1,3-dicarbonyl compounds and amines as well as for enaminones.

    专利号:US-5329022-A
    优先权日:1991-01-16
    标 题:Process for the synthesis of citraconimides
    发明人：TALMA AUKE G; HOOFT HENDRIKA P M; VAN DE BOVENKAMP-BOUWMAN ANNA
    权利人:AKZO AMERICA INC
    摘要:The present invention relates to an improved synthesis method for the making of citraconimides wherein a citraconic anhydride is reacted with 0.5 to 2.0 equivalents of at least one amine salt. This process may be carried out in a solvent and generally leads to excellent yields of the citraconimides with high selectivity and easy purification. The present inventional so relates to a process for the production of citraconic anhydride from itaconic anhydride with an amine or phosphine catalyst and in a cosolvent.

    专利号:EP-0495544-B1
    优先权日:1991-01-16
    标题 :Process for the synthesis of citraconimides
    发明人：TALMA AUKE GERARDUS; HOOFT HENDRIKA PETRONELLA MARI; VAN DE BOVENKAMP
    权利人:AKZO NOBEL NV

    专利号:CA-2059449-C
    优先权日:1991-01-16
    标 题:Process for the synthesis of citroconimides

    专利号:CN-117285453-A
    优先权日:2023-10-10
    标 题 :A method for catalyzing the synthesis of N-substituted-3-methyl indole compounds using nitrogen heterocyclic carbene oxazoline palladium compounds

    专利号:EP-0495544-A1
    优先权日:1991-01-16
    标题 :Process for the synthesis of citraconimides

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    合成参考文献


    摘要:Silva, V. L. M.; Pinto, D. C. G. A.; Santos, C. M. M.; Rocha, D. H. A., Science of Synthesis Knowledge Updates, (2022) 3, 390.
    摘要:Sharma, U.; Kumar, R.; Gupta, S. S.; Chandra, D., Science of Synthesis Knowledge Updates, (2022) 2, 111.
    摘要:Li, J. J., Science of Synthesis: Knowledge Updates, (2025) 2.
    摘要:van der Puyl, V.; Shenvi, R. A., Science of Synthesis: Base-Metal Catalysis, (2023) 2, 651.
    摘要:Yoshikai, N., Science of Synthesis: Hypervalent Halogens in Organic Synthesis, (2025) .
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