CAS: 22737-37-7; [dimethyl-(Trimethylsilyloxyamino)Silyl]Methane

该化合物是一种化学化合物,其独特结构包括氢氧基胺和三甲基硅基化合物,该化合物通常无色可粉黄,在环境条件下以其稳定性而闻名;该化合物经常被用作有机合成的试剂,特别是在保护碳基化合物和形成氨方面;三甲基硅基三甲基羟胺的存在,增强了其在有机溶剂中的再活性和溶解性,使其成为合成化学中的一种宝贵工具.此外,N,O-Bis(三甲基硅基)氢氧基...

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CAS号999-97-3 六甲基二硅氮烷 | CAS号75-77-4 三甲基氯硅烷 | CAS号21023-20-1 N,N,O-三(三甲基硅基)羟胺 | CAS号5577-66-2 N-butyl-1,1,1-t... | CAS号3768-55-6 1,1,1-三甲基-N-苯基哌啶 | CAS号71-36-3 正丁醇 | CAS号119927-52-5 trimethylsilyl ... | CAS号119927-55-8 (E)-O-trimethyl... | CAS号7340-09-2 acetamido acetate | CAS号75732-37-5 (amino-methoxy-...

合成工艺路线路线简述

    📜六甲基二硅氮烷置于盐酸羟胺体系中,用 四氢呋喃,正戊烷 用作溶剂,化学反应 24.0H,以75%的收率获得n,O-双三甲硅基羟胺
    参考文献:Investigation Of Thermally Induced .Alpha.-Deoxysilylation Of Organosilylated Hydroxylamine Derivatives As A General Method For Nitrene Production
    标题:Investigation Of Thermally Induced .Alpha.-Deoxysilylation Of Organosilylated Hydroxylamine Derivatives As A General Method For Nitrene Production
    摘要:
    Doi:10.1021/jo00315A024

    专利信息


    专利号:US-9938282-B2
    优先权日:2014-02-05
    标 题:Expedient synthesis of sitagliptin
    发明人:JANAGANI SATYANARAYANA; THADURI VENKATESHWAR KUMAR; VAMARAJU RAVISANKAR
    权利人:STEREOKEM INC
    摘要:Novel intermediates are disclosed as intermediates for preparation of a Sitagliptin. A novel synthetic method to prepare Sitagliptin using the said intermediates is also disclosed.

    专利号:CA-2947526-A1
    优先权日:2014-02-05
    标题 :Expedient synthesis of sitagliptin

    专利号:US-2017183351-A1
    优先权日:2014-02-05
    标 题:Expedient synthesis of sitagliptin

    专利号:US-2025091984-A1
    优先权日:2022-04-07
    标题:Fragrance and flavor materials
    发明人:DICKERSON THALIA S; TURESKI ROBERT; BLANDINO MAUREEN
    权利人:TAKASAGO PERFUMERY CO LTD
    摘要:The present disclosure is directed to the synthesis and application of novel compounds having unique and desired flavor and/or fragrance characteristics. The compounds of the present disclosure can be employed alone or incorporated as fragrance or flavor compounds in fragrance or flavor compositions. The present disclosure is also directed to consumer products comprising such fragrance or flavor compounds and/or fragrance or flavor compositions.

    专利号:RU-2175316-C2
    优先权日:1995-12-20
    标题 :Aryl-s(o)n-substituted carboxylic-hydroxamic acids and method of their synthesis

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Banert, K., Science of Synthesis Knowledge Updates, (2015) 2, 292.
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