CAS: 18204-80-3; 2-Acetoxyethyltrichlorosilane

该化合物是一种有机硅化合物,其特征为:乙酸盐功能组和三氯硅基化合物.该化合物一般是无色的黄色液体,由于三氯硅基,其反应性较高,可随水分的形成形成硅醇组.乙醇,2-(三氯硅基)-,1-乙酸盐经常用于各种用途,包括用作硅酮材料配制中的联结剂和硅酸聚合物合成中的前体.其化学结构允许其参与改变表面或增强粘合性的反应.此外,有机溶剂中的化合物挥发性和溶性使其适合用于涂层和密封剂.在处理该物质时,应当采取安全防范措施,因为其盐分解会危害到盐酸的特性和潜力.

结构式图片

相似化合物

18306-45-1

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

vinyl acetate acetoxyethyl-heptaphenyl°Ctasilsesquioxane

合成工艺路线路线简述

  • 合成目标产物 2-Acetoxyethyltrichlorosilane 主要起始原料 Vinyl Acetate
  • (文献来源)合成步骤主要原料 Vinyl Acetate
📜乙酸乙烯酯置于dihydrogen Hexachloroplatinate,三氯硅烷体系中,用 异丙醇 用作溶剂,化学反应生成2-乙酰氧基乙基三氯硅烷
参考文献:Iii族的有机金属化合物:Xivv.共轭烯烃的水合中的取向.烯丙基有机铝体系的行为
标题:Iii族的有机金属化合物:Xivv.共轭烯烃的水合中的取向.烯丙基有机铝体系的行为
摘要:为了评价在的hydralumination空间和电子因素p π-和d π共轭烯烃,下述化合物已经与二异丁基氢化处理:1,1-二苯基乙烯; 1,1-二苯丙二烯; 1,1-二苯基-1,3-丁二烯; Ena 三乙基乙烯基硅烷;和三苯基乙烯基硅烷.加合物中碳-铝键的位点已通过NMR光谱,D 2水解的组合推论得出o,氧化和碳化.1,1-二苯基乙烯的水合仅得到1,1-二苯基-2-铝乙烷加合物;1,1-二苯基丙烯得到3-铝-1,1-二苯基-和3-铝-3,3-二苯基-丙烯的混合物,其比例随存在的路易斯碱而变化.和1,1-二苯基-1,3-丁二烯与4-铝-1,1-二苯基-1-丁烯和1-铝-1,1-二苯基-2-丁烯的混合物,其组成同时受到动力学和热力学控制.两种乙烯基硅烷都给出了1-甲硅烷基-1-铝-和1-甲硅烷基-2-铝-乙烷与二异丁基氢化铝的混合物.当三乙基(乙烯基)硅烷与三分之一摩尔的三异丁基铝一起加热
Doi:10.1016/s0022-328X(00)93028-6

海关参考信息

专利信息


专利号:US-8859196-B2
优先权日:2002-06-20
标 题:Antireflective coatings for high-resolution photolithographic synthesis of DNA arrays
发明人:TRULSON MARK O; MCGALL GLENN H; SYWE BEI-SHEN; KAJISA LISA T; TRUONG DANA; RAVA RICHARD P; GOLDBERG MARTIN J
权利人:TRULSON MARK O; MCGALL GLENN H; SYWE BEI-SHEN; KAJISA LISA T; TRUONG DANA; RAVA RICHARD P; GOLDBERG MARTIN J; AFFYMETRIX INC
摘要:The present invention provides an array of polymers and methods of forming arrays of polymers by providing a substrate having a first layer including one or more dielectric coatings on a solid support and a second layer including a plurality of polymers disposed on the first layer. The invention also provides methods for forming an array of polymers on a substrate using light-directed synthesis by providing a substrate having a first layer including one or more dielectric coatings on a solid support, derivatizing the first layer by contacting the first layer with a silanation reagent, and a second layer disposed on said first layer wherein the second layer includes functional groups protected with a photolabile protecting group.

专利号:US-8637434-B2
优先权日:1996-04-17
标题 :System for photolithographic synthesis of polymer arrays
发明人:GOLDBERG MARTIN J; DIGGELMAN MARTIN; HUBBELL EARL A; MCGALL GLENN H; NAM NGO; MORRIS MACDONALD S; YAMAMOTO MELVIN; TAN JENNIFER; RAVA RICHARD
权利人:AFFYMETRIX INC
摘要:The present invention provides novel processes for the large scale preparation of arrays of polymer sequences wherein each array includes a plurality of different, positionally distinct polymer sequences having known monomer sequences. The methods of the invention combine high throughput process steps with high resolution photolithographic techniques in the manufacture of polymer arrays.

专利号:US-6508988-B1
优先权日:2000-10-03
标 题 :Combinatorial synthesis system
发明人:VAN DAM R MICHAEL; UNGER MARC A; QUAKE STEPHEN R
权利人:CALIFORNIA INST OF TECHN
摘要:The present invention provides a chemical reaction apparatus for synthesizing an array of compounds and methods for using the same. In particular, the chemical reaction apparatus of the present invention comprises a solid support base, a first elastic member attached to the solid support base, and a first plurality of flow channels between the solid support base and the first elastic member. In addition, the solid support base comprises a functional group within at least a portion of the first plurality of flow channels for attaching compounds thereto. Optionally, the chemical reaction apparatus may further comprise a second plurality of flow channels which are in a different direction than the first plurality of flow channels. Moreover, the chemical reaction apparatus of the present invention can also include a second elastic member attached to the first elastic member. A plurality of pressure channels present in between the first and the second elastic members allows control of fluid flow within the first plurality of flow channels and/or the second plurality of flow channels.

专利号:US-7097809-B2
优先权日:2000-10-03
标 题:Combinatorial synthesis system
发明人:VAN DAM MICHAEL; UNGER MARC A; QUAKE STEPHEN R
权利人:CALIFORNIA INST OF TECHN
摘要:The present invention provides a microfluidic device for synthesizing an array of compounds and methods for using the same. In particular, the microfluidic device of the present invention comprises a solid support base, an elastomeric layer attached to the solid support, and a plurality of flow channels located within the interface between the solid support and the elastomeric layer. In addition, the solid support comprises a functional group for forming a bond with a reactive reagent. In some embodiments, the microfluidic device further comprises a second plurality of flow channels that intersect the first plurality of flow channels. A plurality of control channels are also present in the microfluidic devices of the present invention. The control channels can be actuated to regulate flow of fluids within the flow channel(s).

专利号:US-2003235824-A1
优先权日:2002-06-20
标题 :Antireflective coatings for high-resolution photolithographic synthesis of DNA array

专利号:US-7332273-B2
优先权日:2002-06-20
标题:Antireflective coatings for high-resolution photolithographic synthesis of DNA arrays

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品牌试剂参考报价(招募中)

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✅ COA系统入驻 | 共享模式

合成参考文献


参考文献:10.1007/bf00920862
摘要:Yur'ev VP, Salimgareeva IM, Kaverin VV. The hydeosilylation of functional olefins on nickel catalysts. Russian Chemical Bulletin. 1976 Jul;25(7):1588. doi: 10.1007/bf00920862.
参考文献:10.1007/978-1-4419-9745-6_8
摘要:da Rocha SRP, Bharatwaj B, Saiprasad S. Science and Technology of Pressurized Metered-Dose Inhalers. 2011 May 25. In: Controlled Pulmonary Drug Delivery. : Springer New York; 2011 May 25.
参考文献:10.1007/bf00953362
摘要:Aldoshin SM, Atovmyan LO, Kozina OA. Structure of photochromic l',3', 3'-trimethyl-6-nitro-8-bromospiro (4-azaindoline-2,2'-[2h-1]benzopyran). Russian Chemical Bulletin. 1986 Nov;35(11):2379–81. doi: 10.1007/bf00953362.
参考文献:10.1007/bf00953363
摘要:Voronkov MG, Klyba LV, Vitkovskii VY, Gubanova LI, Chernov NJ, Sorokin MS, Bochkarev VN. Structure of gaseous ω-acyloxyalkyltrihalosilanes. Russian Chemical Bulletin. 1986 Nov;35(11):2381–3. doi: 10.1007/bf00953363.
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