CAS: 1799-90-2; Bis(Perfluorophenyl)Zinc

该化合物是一种有机金属化合物,由两个与锌中心捆绑在一起的五氟联苯组组成,这种高活性试剂主要用于有机合成和催化,特别是交叉反应和碳-氟联结的形成,其用电子卸载的五氟联苯离心管提高了其刘易斯酸性,使其在温和条件下有效地促进转化.该化合物因其在溶解和与一系列基质的兼容性方面具有稳定性而受到重视,在氟芳芳气系统中提供了精确的控制.它通常用于建造复杂的氟化结构的学术和工业研究中.由于空气和湿度的敏感性,在惰性条件下的正确处理是必不可少的.

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1078-58-6

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Bromo-bis-(pentafluorphenyl)-thallium(III) zinc tris(pentafluorophenyl)borate diethylzincpentafluorphenylbrom(V)tetrafluorid 6F4(B(C(C6F5)2)21,2-C6F4(B(C(C6F5)2)2 tris(pentafluorophenyl)borate bis(pentafluorophenyl)boron chloride

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    专利信息


    专利号:US-2017081347-A1
    优先权日:2014-04-14
    标题:Functionalized azaborine compounds and azaborine-containing biarylcarboxamides, and compositions and methods thereof
    发明人:LIU SHIH-YUAN; ZHAO PENG; BROWN ALEC NATHANIEL
    权利人:THE TRUSTEES OF BOSTON COLLEGE
    摘要:The invention provides novel azaborine compounds, methods for their syntheses and functionalization, and various applications thereof. For example, novel azaborine-containing biarylcarboxylic acids and biarylcarboxamides are disclosed herein, which provide the opportunity to be used as therapeutic agents in different diseases. The novel azaborine-containing compounds show unique physical and biological properties when compared to their corresponding all-carbon compounds. Also, disclosed herein are substituted 1,2-dihydro-1,2-azaborine compounds and methods for making the same including methods for the preparation of various substituted azaborines including alkyl, alkenyl, aryl, nitrile, heteroaryl, and fused ring substituents in the presence of B—H, B—Cl, B—O and N—H bonds from Br-substituted azaborines as well as the synthesis of new fused BN-heterocycles.

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