CAS: 154549-38-9; (2,4,6-Triisopropylphenyl)Boronic Acid
该化合物是一种有机体化合物,其特征是附于三异丙基代苯基苯环的碳酸性功能组,该化合物通常显示白色到白晶状,在二氯甲烷和乙醇等有机溶剂中溶解,但因其水溶性异丙基组而较少溶于水,而该物质在水中较易溶解.该碱酸混合物允许参与各种化学反应,特别是铃木混合反应,使其在有机合成和材料科学中具有价值.该化合物的结构有助于其独特的再活动,包括形成与二醇和其他刘易斯基稳定的复合体的能力.此外,异丙醇组提供的立晶体可以影响其在化学转化过程中的再活性和选择性.与许多有机有机物化合物一样,必须谨慎处理该物质,因为复温和空气可能影响到其稳定性和再活性.
- 英文名称(2,4,6-Triisopropylphenyl)Boronic Acid
- 中文名称2,4,6-三异丙基苯硼酸
- IUPAC名称(2,4,6-triisopropylphenyl)boronic acid
- 其它别名(2,4,6-三异丙基苯基)硼酸; 2,4,6-Triisopropylbenzeneboronic Acid (Contains Varying Amounts Of Anhydride)
- CAS编号154549-38-9
- MFCD编号:MFCD02683099
- EINECS号:672-618-4
- 分子式:C15H25BO2分子量:248.17
- 产品CID: 762744
- 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物
相似化合物
363166-79-4 89787-12-2 950778-38-8物理性质
MSDS等安全信息
欧盟法规
C&L通报上下游产品
CAS号21524-34-5 1-溴-2,4,6-三异丙苯合成工艺路线路线简述
📜2-溴-1,3,5-三异丙苯置于正丁基锂,四甲基乙二胺,硼酸三甲酯,盐酸体系中,用 乙醚,正己烷,四氢呋喃 用作溶剂,化学反应 16.33H,以57%的收率获得2,4,6-三异丙基苯硼酸
参考文献:Suzuki Cross-Coupling Reaction Of Sterically Hindered Aryl Boronates With 3-Iodo-4-Methoxybenzoic Acid Methylester
标题:Suzuki Cross-Coupling Reaction Of Sterically Hindered Aryl Boronates With 3-Iodo-4-Methoxybenzoic Acid Methylester
摘要:The Cross-Coupling Reaction Of 3-Iodo-4-Methoxybenzoic Acid Methylester With Sterically Hindered Arylboronic Esters And Especially 5,5-Dimethyl-2-Mesityl-1,3,2-Dioxaborinane,Is Reported. The Optimisation Of The Process In Order To Obtain Biaryls In Good Yield By Using Anhydrous Benzene At Reflux And Sodium Phenoxide In The Presence Of 0.06 Equiv. Of Pd(Pph3)(4) Is Described. (C) 2000 Elsevier Science Ltd. All Rights Reserved.
Doi:10.1016/s0040-4020(00)00928-5
海关参考信息
- 2902600000-乙苯
2902700000-异丙基苯 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:CN-115490730-A
优先权日:2022-09-30
标 题:A class of methods for the synthesis of selenium/sulfur ligands based on chiral BIDIME
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
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主要参考文献
参考标题:Palladium-Catalyzed Tandem C-C Activation/cyclization Induced By Carbopalladation Of Functionalized Nitriles: Synthesis Of Benzo Dipyrromethenes作者:Lepeng Chen,Julin Gong,Yetong Zhang,Yinlin Shao,Zhongyan Chen,Renhao Li,Jiuxi Chen |发布日期:2020.9.4
摘要:A Palladium-Catalyzed Carbon-Carbon Bond Activation-Initiated Reaction Of 2-(3-Phenyloxiran-2-Yl)Benzonitriles With Arylboronic Acids Is Reported. Multiple Chemical Bonds Were Cleavaged And Reconstructed Via β-Carbon Elimination In This Reaction, Enabling The Construction Of Valuable Benzo-Fused Dipyrromethenes That Are Difficult To Prepare By Other Methods. Additionally, A Series Of Benzannulated
合成参考文献
摘要:Guram, A. S.; Milne, J. E.; Tedrow, J. S.; Walker, S. D., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 1, 22.
摘要:Guram, A. S.; Milne, J. E.; Tedrow, J. S.; Walker, S. D., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 1, 68.
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