CAS: 13963-35-4; Phenyl(O-Tolyl)Sulfane

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16704-47-5 2417377-23-0 36943-39-2

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CAS号615-37-2 2-碘甲苯 | CAS号882-33-7 二苯二硫醚 | CAS号108-98-5 硫酚 | CAS号591-50-4 碘苯 | CAS号137-06-4 邻硫甲酚 | CAS号95-46-5 2-溴甲苯 | CAS号4032-80-8 Disulfide,bis(2... | CAS号603-33-8 三苯基铋 | CAS号10050-08-5 三邻甲苯基铋 | CAS号16419-60-6 2-甲基苯硼酸 | CAS号3166-15-2 9H-Thioxanthen-... | CAS号261-31-4 噻吨 | CAS号1527-17-9 2-[2-(苯硫基)苯基]乙酸 | CAS号58844-73-8 2-(benzenesulfo... | CAS号37660-43-8 1-(Bromomethyl)...

S-Phenyl 2-Methylbenzothioate置于chloro(1,5-Cyclooctadiene)Rhodium(I) Dimer体系中,用 甲苯 用作溶剂,化学反应 15.0H,以70%的收率获得2-甲基二苯硫醚
参考文献:Rh(I)-催化的硫酯的分子内脱羰
标题:Rh(I)-催化的硫酯的分子内脱羰
摘要:在催化量的 [rh(Cod)Cl] 2 (2 Mol%)存在下,从硫酯脱羰合成硫醚.该协议代表了第一个 Rh 催化的硫酯脱羰硫醚化,以产生有价值的硫醚.显着的特点包括没有膦配体,无机碱和其他添加剂,以及对芳基氯和芳基溴的优异基团耐受性,这些都是使用其他金属促进脱羰的问题.报告了克级合成,后期药物衍生化和通过 C-S/c-Br 裂解进行的正交位点选择性交叉偶联.
Doi:10.1021/acs.Joc.1C01117

专利信息

专利号:US-8202985-B2
优先权日:2005-10-31
标 题:Monomer compositions for the synthesis of polynucleotides, methods of synthesis, and methods of deprotection
发明人：DELLINGER DOUGLAS J; TIMAR ZOLTAN; SIERZCHALA AGNIESZKA; DELLINGER GERALDINO; CARUTHERS MARVIN H
权利人:DELLINGER DOUGLAS J; TIMAR ZOLTAN; SIERZCHALA AGNIESZKA; DELLINGER GERALDINO; CARUTHERS MARVIN H; AGILENT TECHNOLOGIES INC; UNIV COLORADO
摘要:Nucleotide monomers, polynucleotides, methods of making each, and methods of deprotecting each, are disclosed. An embodiment of the nucleotide monomer, among others, includes a nucleotide monomer having a heterobase protecting group selected from structures I through III as described herein. An embodiment of the polynucleotide, among others, includes a plurality of nucleotide moieties having a heterobase protecting group selected from one of structures I through III as described herein.

专利号:US-7759471-B2
优先权日:2005-10-31
标题 :Monomer compositions for the synthesis of RNA, methods of synthesis, and methods of deprotection
发明人：DELLINGER DOUGLAS J; TIMAR ZOLTAN; SIERZCHALA AGNIESZKA; DELLINGER GERALDINE; CARUTHERS MARVIN H
权利人:AGILENT TECHNOLOGIES INC; UNIV COLORADO
摘要:Nucleotide monomers, polynucleotides, methods of making each, methods of deprotecting each, and the like are disclosed herein.

专利号:US-3979460-A
优先权日:1974-07-01
标 题 :Process for the preparation of an organomercaptophenol from sulfur, a 2,6-disubstituted phenol, and an activated olefin or an epoxy compound
发明人：HAY ALLAN S
权利人:GEN ELECTRIC
摘要:A process for the preparation of an organomercaptophenol is described which comprises the reaction of sulfur with a 2,6-disubstituted phenol carried out in the presence of (1) a base, (2) an activated olefin or an epoxy compound, (3) and a solvent with a high dielectric constant. The organomercaptophenols produced by this process are useful as monomers in the synthesis of esters, carbonates, ethers, epoxy compounds, among many other chemicals synthesized from monohydric phenols. In addition, the oganomercaptophenols are also useful as antioxidants.

专利号:US-4064158-A
优先权日:1974-07-01
标题:Process for the preparation of an organomercaptophenol from sulfur, a 2,6-disubstituted phenol, and an activated olefin or an epoxy compound
发明人：HAY ALLAN S
权利人:GEN ELECTRIC
摘要:A process for the preparation of an organomercaptophenol is described which comprises the reaction of sulfur with a 2,6-disubstituted phenol carried out in the presence of (1) a base, (2) an activated olefin or an epoxy compound, (3) and a solvent with a high dielectric constant. The organomercaptophenols produced by this process are useful as monomers in the synthesis of esters, carbonates, ethers, epoxy compounds, among many other chemicals synthesized from monohydric phenols. In addition, the organomercaptophenols are also useful as antioxidants.

专利号:US-2007100138-A1
优先权日:2005-10-31
标题:Monomer compositions for the synthesis of polynucleotides, methods of synthesis, and methods of deprotection

专利号:US-2007100136-A1
优先权日:2005-10-31
标题:Monomer compositions for the synthesis of RNA, methods of synthesis, and methods of deprotection