CAS: 138-86-3; Limonene

该化合物是一种无色,挥发性液体,被归类为环状单体,主要见于柑橘和柠檬等柑橘果的皮层,有助于其特性芳香.利蒙尼具有独特的柑橘香味,以其香味闻名,使它在香水,清洁产品和食品调味中成为流行成分.化学上,它以两种对应形式存在:D-利蒙尼,具有甜橙色香味,和L-月内尼,具有香味.利蒙尼还因其潜在的健康利益而得到承认,包括防炎和抗氧化剂特性,在有机溶剂中可溶解,但水溶解性有限.此外,在各种工业应用中,用豪华作为溶剂,被认为是石油溶剂的一种绿色替代品.其低毒性和生物降解性进一步增强了其对消费品和工业工艺的吸引力.

结构式图片

物理性质

MSDS等安全信息

欧盟法规

统一分类与标签欧盟化妆品法规附录三-限用物质清单压力设备指令-第1组危险流体REACH注册ECHA物质欧盟气雾剂指令-标签制度工作场所安全标识要求ECHA物质C&L通报REACH预注册废弃物危险特性清单

上下游产品

CAS号1195-92-2 (+)-柠檬烯氧化物,顺式和反式的混合物 | CAS号61585-35-1 1-methyl-4-isop... | CAS号80-56-8 α-蒎烯 | CAS号2451-01-6 对-薄荷烷-1,8-二醇一水合物 | CAS号79433-08-2 (2Z,6E)-3,7-dim... | CAS号106-24-1 香叶醇; (E)-3,7-二甲... | CAS号79433-10-6 (2Z,6E)-3,7-dim... | CAS号99-49-0 L-香芹酮 | CAS号82096-14-8 trimethyl((4-(p... | CAS号112358-23-3 4-(2-iodopropan... | CAS号562-74-3 4-萜烯醇 | CAS号491-09-8 Piperitenone | CAS号14576-08-0 4-(1-甲氧基-1-甲基乙基... | CAS号26946-66-7 1-methoxy-4-(1-... | CAS号26946-68-9 4-异丙烯基-1-甲氧基-1-甲基环己烷 | CAS号470-82-6 桉叶油醇 | CAS号98-55-5 alpha-松油醇 | CAS号80-53-5 萜品 | CAS号99-49-0 L-香芹酮

合成工艺路线路线简述

  • 106-23-0 = 138-86-3 + 13877-91-3 + 586-67-4 + 500-00-5 + 99-86-5 + 123-35-3
    反应条件:1.1C:Al2O3,S:Co2,S:Me(Ch2)4Me,190°C,190 Atm
    标题:Cyclization Of Citronellal In A Supercritical Solvent In A Flow Reactor In The Presence Of Al2O3
    作者:By Anikeev,V. I. Et Al
    参考文献:Russian Journal Of Physical Chemistry A 日期:2012 卷标:86(12) 页码:1917-1919]

    80-56-8 = 138-86-3 + 673-84-7 + 3949-35-7 + 13877-91-3 + 3757-05-9
    反应条件:1.1
    标题:Flash Vacuum Thermolysis Of Terpenic Compounds In The Pinane Series
    作者:By Lemee,Laurent Et Al
    参考文献:Synthetic Communications 日期:1995 卷标:25(9) 页码:1313-18]

    78-70-6 = 138-86-3 + 13877-91-3 + 123-35-3
    反应条件:1.1C:161337-67-3,0.5 H,110°C,60 Mmhg
    标题:Transition Metal Triflate Catalyzed Conversion Of Alcohols,Ethers And Esters To Olefins
    作者:By Keskivali,J. Et Al
    参考文献:Rsc Advances 日期:2018 卷标:8(27) 页码:15111-15118]

    115-95-7 = 138-86-3 + 99-85-4 + 13877-91-3 + 99-86-5 + 123-35-3
    反应条件:1.10.5 H,453K2.1R:O2,2 H,413K
    标题:Catalytic Reactions Of Linalool And Linalyl Acetate On Wide-Pore Zeolites And Mesoporous Mcm-41
    作者:By Ramishvili,Ts. M. Et Al
    参考文献:Vestnik Moskovskogo Universiteta 日期:2007 卷标:48(4) 页码:223-229]

    = 138-86-3 + 13877-91-3 + 7216-56-0 + 123-35-3
    反应条件:1.1R:Isopentadiene,C:192572-52-4,C:Ni Acetylacetonate,S:Phme,1 H,Rt; -10 - -5°C1.2R:Al(I-Bu)3,30 Min,-10 - -5°C; 30 Min,-10°C1.31 H,-10 - 10°C; 8 H,36-42°C1.4R:HCL,S:H2O,15-20°C
    标题:Pyrylium Salts With Long Alkyl Substituents. 11. Pyridines With Long Alkyl Substituents As Ligands In Oligomerization Of Isoprene
    作者:By Bogatian,Mariana Viorica Et Al
    参考文献:Revue Roumaine De Chimie 日期:2006 卷标:51(7-8) 页码:735-741
📜(R)-氧化柠檬烯 以86%的收率获得
参考文献:Gurudutt K. N.; Ravindranath B.,Tetrahedron Lett.,1980,21,No 12,1173-1174
标题:Gurudutt K. N.; Ravindranath B.,Tetrahedron Lett.,1980,21,No 12,1173-1174

海关参考信息

专利信息


专利号:US-6423877-B1
优先权日:1999-11-15
标题:Synthesis of pseudopterosin compounds
发明人：COREY ELIAS J
权利人:HARVARD COLLEGE
摘要:The present invention is directed to a new synthetic route to pseudopterosin aglycone (3): n a key intermediate for the synthesis of a group of antiinflammatory natural products including pseudopterosin A (1) and E (2). The pathway of synthesis starts with the abundant and inexpensive (S)-(−)-limonene and its long-known cyclic hydroboration product (4) and leads to the chiral hydroxy ketone (6). Conversion of (6) to (10) followed by a novel aromatic annulation produced (15) which underwent highly diastereoselective cyclization to afford the protected pseudopterosin aglycone (16). The naturally occurring pseudopterosins such as (1) and (2) are readily available from this key intermediate.

专利号:WO-2004011474-A1
优先权日:2002-07-31
标题:Universal support media for synthesis of oligomeric compounds
发明人：GUZAEV ANDREI P; MANOHARAN MUTHIAH; RAVIKUMAR VASULINGA T; KUMAR RAJU K
权利人:ISIS PHARMACEUTICALS INC; GUZAEV ANDREI P; MANOHARAN MUTHIAH; RAVIKUMAR VASULINGA T; KUMAR RAJU K
摘要:Compounds for the synthesis of oligomeric compounds, particularly oligonucleotide and oligonucleotide mimetics, are provided. In addition, methods for functionalizing a support medium with a first monomeric subunit and methods for the synthesis of oligomeric compounds utilizing the novel compounds bound to support media are provided.

专利号:US-4140708-A
优先权日:1975-10-16
标 题 :Asymmetric synthesis of optically active prostaglandins
发明人：CHADHA NARESH K; PARTRIDGE JR JOHN J; USKOKOVIC MILAN R
权利人:HOFFMANN LA ROCHE
摘要:An asymmetric synthesis of optically active prostaglandin F 2 α from cyclopentadiene including intermediates in this synthesis.

专利号:US-6653468-B1
优先权日:2002-07-31
标 题 :Universal support media for synthesis of oligomeric compounds
发明人：GUZAEV ANDREI P; MANOHARAN MUTHIAH
权利人:ISIS PHARMACEUTICALS INC
摘要:Compounds for the synthesis of oligomeric compounds, particularly oligonucleotides and oligonucleotide mimetics, are provided. In addition, methods for functionalizing a support medium with a first monomeric subunit and methods for the synthesis of oligomeric compounds utilizing the novel compounds bound to support media are provided.

专利号:US-3933892-A
优先权日:1973-02-12
标题 :Asymmetric synthesis of optically active prostaglandins
发明人：CHADHA NARESH KUMAR; PARTRIDGE JR JOHN JOSEPH; USKOKOVIC MILAN RADOJE
权利人:HOFFMANN LA ROCHE
摘要:An asymmetric synthesis of optically active prostaglandin F 2 .sub.α from cyclopentadiene including intermediates in this synthesis.

专利号:US-7429658-B2
优先权日:2003-09-11
标题 :Synthesis of protected pyrrolobenzodiazepines
发明人：HOWARD PHILIP; MASTERSON LUKE
权利人:SPIROGEN LTD
摘要:A method of synthesis of a N-10 protected PBD compound of formula (I): n nvia an intermediate of formula (II) or formula (V):

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合成参考文献


参考文献:10.1186/2047-783x-14-s4-205
摘要:Rantzsch U, Vacca G, Dück R, Gillissen A. Anti-inflammatory effects of myrtol standardized and other essential oils on alveolar macrophages from patients with chronic obstructive pulmonary disease. European Journal of Medical Research. 2009 Dec 07;14(Suppl 4):205. doi: 10.1186/2047-783x-14-s4-205.
参考文献:10.1111/j.1476-5381.2011.01238.x
摘要:Russo EB. Taming THC: potential cannabis synergy and phytocannabinoid‐terpenoid entourage effects. British J Pharmacology. 2011 Jul 12;163(7):1344–64. doi: 10.1111/j.1476-5381.2011.01238.x.
参考文献:10.1016/j.jbiotec.2011.07.001
摘要:Donsì F, Annunziata M, Vincensi M, Ferrari G. Design of nanoemulsion-based delivery systems of natural antimicrobials: effect of the emulsifier. J Biotechnol. 2012 Jun 30;159(4):342–50. doi: 10.1016/j.jbiotec.2011.07.001.
参考文献:10.1016/j.plaphy.2011.06.008
摘要:Lawo NC, Weingart GJF, Schuhmacher R, Forneck A. The volatile metabolome of grapevine roots: First insights into the metabolic response upon phylloxera attack. Plant Physiology and Biochemistry. 2011 Sep;49(9):1059–63. doi: 10.1016/j.plaphy.2011.06.008.
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