CAS: 983-80-2; (Z)-1,2-Bis(Diphenylphosphino)Ethene

该化合物是一种可移植磷离心,广泛用于协调化学和同质催化,其硬性(Z)-乙烯骨柱确保精确的几何控制,促进形成稳定的金属综合体,并有明确界定的协调环境,二苯磷各组提供强大的电子刺激特性,加强交叉相交,氢化和水成形反应中的催化活动.这一离心线因其稳定低氧化状态金属中心的能力,改善催化剂寿命和选择性而特别受重视.其对空气敏感的特性要求在惰性条件下处理,但其在不对称合成和过渡性金属催化法方面的一贯性能使得它成为先进的合成应用的首选.

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上下游产品

CAS号156-59-2 顺-1,2-二氯乙烯标准溶液 | CAS号829-85-6 二苯基膦 | CAS号5112-95-8 双(二苯基膦)炔 | CAS号603-35-0 三苯基膦

合成工艺路线路线简述

    📜双(二苯基磷)乙炔置于(Tolane)(Trimethylphosphane)Titanocene 氢气体系中,化学反应生成 顺-1,2-双(二苯基膦)乙烯
    参考文献:Complexes Acetyleniques De Titane(II). Reactivite Vis-A-Vis De L'Hydrogene Moleculaire: Une Nouvelle Approche Du Titanocene
    标题:Complexes Acetyleniques De Titane(II). Reactivite Vis-A-Vis De L'Hydrogene Moleculaire: Une Nouvelle Approche Du Titanocene
    摘要:
    DOI:10.1016/0022-328X(85)80096-6

    海关参考信息

    专利信息


    专利号:US-7750157-B2
    优先权日:2004-06-01
    标 题:Luminescent compounds having a functionalized linker arm used in the bioconjugation and labeling of biomolecules
    发明人:CAPUTO GIUSEPPE; GOBETTO ROBERTO; VISCARDI GUIDO
    权利人:UNIV DEGLI STUDI TORINO
    摘要:The present invention relates to luminescent compounds having a functionalised linker arm, their synthesis and use in bioconjugation and labelling of biomolecules, such as for example nucleosides, nucleotides, nucleic acids (DNA, RNA or PNA) and proteins, as well as their use in the execution of in vitro and in vivo analytic and diagnostic assays.

    专利号:WO-2013038134-A1
    优先权日:2011-09-16
    标题 :Synthesis and anticancer activity of ruthenium (11) cis-cis-1,3,5- triaminocyclohexane complexes
    发明人:GAMBLE AIMEE JOANNA; LYNAM JASON MARTIN; WALTON PAUL HOWARD
    权利人:UNIV YORK; GAMBLE AIMEE JOANNA; LYNAM JASON MARTIN; WALTON PAUL HOWARD
    摘要:There is described a complex of formula I: in which, R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are each, hydrogen, alkyl CI to 20 alkenyl CI to 20, aryl, alkyl(ci t0 20)aryl, alkenyl(Ci t0 20>aryl, heteroaryl, etc.; R 7 , R 8 and R 9 are each, hydrogen or alkyl CI to 20; L 1 , L 2 and L 3 , are each a ligand; in free or in salt form.

    专利号:CN-119931032-A
    优先权日:2023-11-03
    标题:Preparation method of amide COF and application of amide COF in butanone ligature nitrogen synthesis

    专利号:CN-119930465-A
    优先权日:2023-11-03
    标题:Synthesis method of butanone azine

    专利号:CN-110964064-A
    优先权日:2019-12-23
    标 题 :A kind of nickel-iron hydrogenase model compound containing picolinyl PNP ligand and its synthesis method

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    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Banerjee, S.; Ilies, L., Science of Synthesis: Base-Metal Catalysis, (2023) 2, 341.
    摘要:Banerjee, S.; Ilies, L., Science of Synthesis: Base-Metal Catalysis, (2023) 2, 351.
    摘要:Banerjee, S.; Ilies, L., Science of Synthesis: Base-Metal Catalysis, (2023) 2, 361.
    摘要:Yoshikai, N., Science of Synthesis: Base-Metal Catalysis, (2023) 2, 274.
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