6973-13-3 = 88-53-9 反应条件:1.1 Reagents: Carbon Monoxide Catalysts: 1,8-Diazabicyclo[5.4.0]Undec-7-Ene,Selenium Solvents: Water; 6 H,6 Mpa,160 °C 标题:Selenium-Catalyzed Reduction To Prepare Clt Acid With Co/h2O By High Pressure Reduction In Aqueous Solution 作者:Wang,Si-Yuan; Qin,Long; Zhang,Chuan-Yang; Wang,Bei-Bei; Liu,Xiao-Zhi 参考文献:Ranliao Yu Ranse 日期:2015 卷标:52(1) 页码:42-44]
6973-13-3 = 88-53-9 反应条件:1.1 Reagents: Hydrogen Catalysts: Alumina,Palladium; 3 H,3 Mpa,100 °C 标题:Influence Of Support Calcination Temperature On The Performance Of Pd/al2O3 Catalyst Used In Liquid-Phase Catalytic Hydrogenation Of 6-Chloro-3-Nitrotoluene-4-Sulfonic Acid 作者:Xu,Le; Hua,Da-Yin; Zhou,Sheng-Hu; Yu,Hong-Bo 参考文献:Huaxue Yanjiu Yu Yingyong 日期:2014 卷标:26(2) 页码:187-193]
6973-13-3 = 88-53-9 反应条件:1.1 Reagents: Carbon Monoxide,Selenium Catalysts: 1,8-Diazabicyclo[5.4.0]Undec-7-Ene Solvents: N,N-Dimethylaniline,Water; 10 H,180 °C 标题:Selenium-Catalyzed Reduction To Prepare Clt Acid With Co/h2O By Atmospheric Pressure Reduction 作者:Wang,Si-Yuan; Bai,Xue-Jing; Wang,Bei-Bei; Zhang,Chuan-Yang; Liu,Xiao-Zhi 参考文献:Ranliao Yu Ranse 日期:2015 卷标:52(2) 页码:26-28]
专利号:US-4719053-A 优先权日:1980-08-01 标题 :Beta-chloroethylsulfonylmethyl-benzoic halides as intermediates 发明人:SCHLAEFER LUDWIG; HAEHNLE REINHARD 权利人:HOECHST AG 摘要:New beta -chloroethylsuflonylmethyl-benzoic acid halides which can serve as fibre-reactive anchors for thesynthesis of novel organic, water-soluble compounds, preferably dyestuffs, having fibre-reactive and fibre-finishing properties, such as preferably dyestuff properties, and containing, as a fibre-reactive group, one or two beta -chloroethylsufonylmethylbenzoic acid amide groups. For the synthesis of these novel fibre-finishing compounds, said new beta -chloroethylsulfonylmethyl-benzoic acid halide compounds are reacted with an organic, water-soluble compound having fibre-finishing properties and continuing one or two amino groups. Also precursors of the fibre-finishing, fibre-reactive compounds, containing said beta -chloroethylsulfonylmethyl-benzxoic acid amid grouping, can be employed for their synthesis. The novel fibre-finishing compounds can be applied onto suitable fibre materials, such as especially cellulose fibre material and natural or synthetic polyamide fibre materials, and fixed on these fibre materials in a manner similar to application and fixation methods usual in the technique for fibre-reactive compounds. The fibre-finished material, such as dyed material, shows very good wet fastnesses.
专利号:US-4118384-A 优先权日:1976-02-21 标题 :Process for preparation of azo dyestuffs by coupling in presence of aromatic sulphonic acid-formaldehyde reaction product 发明人:MOLLS HANS-HEINZ; SCHIWY WILLY; HORNLE REINHOLD; NEBELING REINHARD 权利人:BAYER AG 摘要:Dyestuff dispersions and dyestuff solutions free from salt or at least having a low salt content are obtained in that the diazotization is carried out with addition of free dispersing agent acid to which, after the synthesis, either no basic agents are added or basic agents are added only up to a pH value of 3. The disclosed process gives dyestuff compositions of low salt content and results in readily dispersible dyestuffs when water insoluble dyestuffs are prepared and stable solutions when water soluble dyestuffs are prepared. The process is widely applicable and chemical constitution of the dyestuffs is conventional.
专利号:US-4035350-A 优先权日:1975-01-30 标 题:Process for the preparation of water-soluble azo dyestuffs by reacting an aromatic amine and a coupling component with alkali metal nitrite or alkyl nitrite in the absence of acid 发明人:LANDLER JOSEF; WORFEL ERHARD 权利人:HOECHST AG 摘要:A new and very advantageous Process had been found for the preparation of azo dyestuffs by diazotation and coupling in which the synthesis is carried out without the hitherto usual addition of an acid, with the proviso that at least one of the diazo and coupling components contains at least one acid group. Besides the saving of reaction material and subsequently of alkali for neutralization of the reaction medium and isolation of the dyestuff, highly concentrated solutions of the dyestuff and salt-free or practically salt-free dyestuffs can be obtained, and waste-water is no longer charged with big amounts of salts.
专利号:US-5389524-A 优先权日:1989-07-28 标 题:Method and a system for quantitatively monitoring a chemical component dissolved in a liquid medium 发明人:LARSEN BJORN E H; VINTHER ARNE; MOLLER POUL; THORSSON JORN R; SOEBERG HENRIK; SORENSEN JESPER L; LARSEN LYKKE B 权利人:KOEGE KEMISK VAERK 摘要:PCT No. PCT/DK90/00196 Sec. 371 Date Mar. 24, 1992 Sec. 102(e) Date Mar. 24, 1992 PCT Filed Jul. 30, 1990 PCT Pub. No. WO91/02254 PCT Pub. Date Feb. 21, 1991.A method and apparatus for quantitatively monitoring a chemical component dissolved in a liquid medium utilize the creation, in a measurement cell, of an interface zone between the liquid medium and an analytical reagent or reference solution. The concentration or amount of the chemical component are determined by the measurement of a value of a measurement parameter in the interface zone, and the derivation from that value of the concentration or amount of the component in comparison with a baseline or reference value measured for the reagent or reference solution alone. Matrix effects and ghosting errors are avoided. The method and apparatus can be used advantageously for on-line optimization and control of industrial, chemical and biological processes, such as chemical reactions in progress, coupling reactions for the synthesis of azo compounds, and the monitoring of in vivo or in vitro biological systems as well as for conventional analytical purposes.