CAS: 764-99-8; Diethyleneglycoldivinylether

该化合物是一种高纯度,活性醚化合物,主要用作聚合工艺中的交叉联系剂,其二维乙烯功能使得各种单体能够与各种单体高效共聚,加强形成稳定,交叉连接的聚合物网络.该复合物在普通有机溶剂中表现出极好的溶性,便于将其融入配方.其低粘度和双功能结构使其适合需要受控治疗的应用,如涂层,粘合剂和特殊树脂.该醚联系有助于提高由此产生的聚合物的灵活性和化学抗力.建议在高温条件下进行适当的处理,因为其对湿度敏感,并且有可能发生激进反应.

结构式图片

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

上下游产品

CAS号764-48-7 2-乙烯氧基乙醇 | CAS号110-75-8 乙烯(2-氯乙基)醚 | CAS号74-86-2 乙炔 | CAS号111-46-6 二乙二醇 | CAS号929-37-3 二乙二醇单乙烯基醚 | CAS号106-89-8 环氧氯丙烷 | CAS号111-34-2 乙烯基正丁醚 | CAS号112753-81-8 1-[2-(2-ethenox...

合成工艺路线路线简述

  • 合成目标产物 Diethylene Glycol Divinyl Ether 主要起始原料 Acetylene And Diethylene Glycol
  • 111-46-6 = 764-99-8 + 929-37-3
    反应条件:1.1 Catalysts: Ethanol,2,2′-Oxybis-,Dipotassium Salt; 8 H,175 °C1.2 Reagents: Sulfuric Acid Solvents: Water; Ph 5.5 - 6
    标题:Synthesis Of Diethylene Glycol Vinyl Ether In Bubble Reactor
    作者:Zhao,Fei; Zhang,Yu; Zhang,Ji-Bo; Jiang,Wei
    参考文献:Jilin Huagong Xueyuan Xuebao 日期:2013 卷标:30(3) 页码:6-9]

    111-46-6 = 764-99-8 + 929-37-3
    反应条件:1.1 Catalysts: Ethanol,2,2′-Oxybis-,Potassium Salt; > 0.6 Mpa,175 °C
    标题:Continuous Synthesis Process Of Diethylene Glycol Vinyl Ether
    作者:Zhang,Jibo; Zhang,Yu; Bai,Chunjing
    参考文献:Jilin Huagong Xueyuan Xuebao 日期:2012 卷标:29(3) 页码:20-23]

    111-46-6 = 764-99-8 + 929-37-3
    反应条件:1.1 Reagents: 4-Tert-Butylcatechol Catalysts: Potassium Tert-Butoxide; Rt -> 130 °C; 30 Min,100 - 130 °C1.2 120 H,175 - 180 °C; 30 Min,175 - 180 °C
    标题:Method For Purifying Vinyl Ether Monomers
    参考文献:China]

    111-46-6 = 764-99-8 + 929-37-3
    反应条件:1.1 Catalysts: Potassium Hydroxide; 7 H,19 Bar,155 °C; 155 °C -> Rt
    标题:Process For Preparing Divinyl Ethers By Reacting Diols With Acetylene And Removing Monovinyl Ether From Product Mixture
    参考文献:World Intellectual Property Organization]

    111-46-6 = 764-99-8 + 929-37-3
    反应条件:1.1 Catalysts: Potassium Hydroxide; 7 H,19 Bar,155 °C; 155 °C -> Rt
    标题:Process For Preparing Divinyl Ethers
    参考文献:United States
二乙二醇单乙烯基醚置于氢氧化钾体系中,化学反应生成 二乙二醇二乙烯基醚
参考文献:
标题:
摘要:
DOI:10.1023/a:1019687828252

海关参考信息

专利信息


专利号:US-5073643-A
优先权日:1990-08-30
标 题 :High yield synthesis of hydroxyl-containing cationic photoinitiators
发明人:CRIVELLO JAMES V
权利人:POLYSET CORP
摘要:Synthesis use of a new class of diaryliodonium salt photo and thermal polymerization initiators in which the aryl groups are substituted with alkoxy group bearing hydroxy groups. Good to excellent yields are obtained of diaryliodonium salts in which the aryl groups are substituted with long chain alkoxy groups, which alkoxy groups also possess at least one hydroxyl moiety attached at the 2-position of an alkoxy group. The resultant salts have enhanced solubility when compared with their lower molecular weight counterparts. The hydroxyl groups serve as chain transfer agents; and, in cross linking UV-induced cationic polymerizations, the hydroxyl groups effect marked accelertion on polymerization rates. The salts also have excellent compatability with nonpolar monomers such as epoxidized oil and poly(1,2-butadience oxide) and provide further benefits when they are used along with copper cocatalysts in thermally curable polymer systems. In the latter form of cases, the secondary hydroxyl group serves as a reducing agent for the copper (II) complex.

专利号:US-7728088-B2
优先权日:2002-08-06
标题 :Synthesis of statistical microgels by means of controlled radical polymerisation
发明人:DESTARAC MATHIAS; BAVOUZET BRUNO; TATON DANIEL
权利人:RHODIA OPERATIONS
摘要:The invention relates to a method of preparing statistical microgels. The inventive method comprises a step involving the radical polymerisation of a composition containing: at least one monoethylenically-unsaturated monomer, at least one multiethylenically-unsaturated monomer, a free radical source and a control agent. The invention also relates to first generation microgels thus prepared and all the compounds resulting from said microgels (next-generation microgels).

专利号:US-6384216-B1
优先权日:2000-08-09
标 题 :Purification of alkenyl compounds
发明人:LORENZ RUDOLF ERICH; BOETTCHER ARND; PINKOS ROLF
权利人:BASF AG
摘要:A process for purifying alkenyl compounds having a divalent or trivalent heteroatom in the alpha-position relative to the double bond by distillation comprises carrying out at least two distillations in which the purified alkenyl compounds are obtained from the gas phase by condensation, where the time between the first distillation after the synthesis of the alkenyl compounds and at least one further distillation is at least one day and the purified alkenyl compounds have an APHA color number of <30.

专利号:US-6323360-B1
优先权日:1999-11-19
标 题 :Breakable crosslinkers an use for preparation of polymers using same
发明人:RUCKENSTEIN ELI; ZHANG HONGMIN
权利人:UNIV NEW YORK STATE RES FOUND
摘要:The present invention discloses the synthesis of a novel crosslinker having the following structure: n R 1 is C(R 8 ) (R 9 ) wherein (R 8 ) is H, or an alkyl group having 1-5 carbon atoms, and (R 9 ) is H, or an alkyl group having 1-5 carbon atoms. R 2 is H, or an alkyl group having 1-5 carbon atoms. R 3 is H or an alkyl group having 1-5 carbon atoms. R 4 is an alkyl group having 1-5 carbon atoms. R 5 is H or an alkyl group having 1-5 carbon atoms. R 6 is H or an alkyl group having 1-5 carbon atoms. R 7 is C(R 10 ) (R 11 ) wherein (R 10 ) is H, or an alkyl group having 1-5 carbon atoms, and (R 11 ) is H, or an alkyl group having 1-5 carbon atoms. The crosslinker is stable in a basic environment, but decomposable in an acidic environment.

专利号:WO-2014058755-A1
优先权日:2012-10-10
标题 :Synthesis support resin
发明人:MAIKNER JOHN; MCINTOSH LESTER H
权利人:ROHM & HAAS
摘要:Provided is a support resin suitable for oligonucleotide synthesis comprising structure (II), wherein said particle comprises a crosslinked styrenic polymer, wherein -R 101 is hydrogen or alkyl, wherein -L 102 - and -L 201 - are independent optional linking groups, wherein each of -R 201 , -R 202 , and -R 203 is independently hydrogen or a substituted or unsubstituted hydrocarbyl group, and wherein -L is an functional group that is capable of forming a phosphate linkage with a nucleotide. Also provided is a method of making such a resin.

专利号:US-6136926-A
优先权日:1996-07-22
标 题 :Cross-linkable, olefinic polymers and methods for their synthesis
发明人:RAETZSCH MANFRED; HESSE ACHIM; BUCKA HARMUT; LEISTNER DIRK; IVANCHEV SERGEJ; HEIKIN SAUL; MESH ALLA; PUKSCHANSKI MOISEJ
权利人:BOREALIS GMBH
摘要:Cross-linkable, olefinic polymers synthesized from mixtures of olefinic polymers and ethylenically unsaturated organosilane compounds, which can be grafted, by a 2-step method using thermally decomposing free radical-forming agents by heating the mixtures to a temperature of 30 DEG to 110 DEG C. below the softening temperature or the crystallite melting point of the olefinic polymers used and subsequently heating the mixtures to a reaction temperature of 10 DEG to 60 DEG C. below the softening temperature or the crystallite melting point of the olefinic polymers used. In the alternative, they can be grafted by a method involving the action of ionizing radiation with simultaneous absorption of organosilane compounds and the action of radiation. The method is suitable for producing films, sheets, fibers, panels, coatings, pipes, hollow objects, foamed materials and molded articles.
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合成参考文献


摘要:Compound: Diethylene glycol divinyl ether homopolymer
摘要:Gigiena i Sanitariya. For English translation, see HYSAAV., 42(3)(12), 1977
摘要:American Industrial Hygiene Association Journal., 23(95), 1962 []
摘要:Merino, P., Science of Synthesis, (2007) 29, 717.
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