CAS: 73491-36-8; Thallium(1+),Trifluoromethanesulfonate

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CAS号32707-04-3 thallium(I) 2,4... | CAS号358-23-6 三氟甲磺酸酐 | CAS号34684-41-8 N-Hydroxysuccin... | CAS号56059-54-2 N-Methyl-N-thal...

📜Thallium(I) Carbonate置于三氟甲磺酸体系中,用 水 作为反应溶剂,化学反应生成 三氟甲磺酸铊
参考文献:八元的palladacycles对co的反应性是由于将烯基插入具有药用意义的环烷基化伯芳基烷基胺的pd-C键中而产生的.四氢苯甲佐酮,邻官能化苯乙胺,尿素和异氰酸酯的合成
标题:八元的palladacycles对co的反应性是由于将烯基插入具有药用意义的环烷基化伯芳基烷基胺的pd-C键中而产生的.四氢苯甲佐酮,邻官能化苯乙胺,尿素和异氰酸酯的合成
摘要:由高藜芦胺衍生的邻位金属络合物[pd { C,N-C 6 H 2 Ch 2 Ch 2 Nh 2-2,(ome)2-4,5}(μ-Br)] 2(1A)与乙基反应丙烯酸酯,甲基乙烯基酮或2-降冰片烯,反应生成由烯烃插入pd-C键中形成的二聚体复合物[pd { C,N-Ch(R)ch 2 C 6 H 2 Ch 2 Ch 2 Nh 2-2,(ome)2-4,5}(μ-Br)] 2(r = Co 2 Et(2A1),C(o)me(2A2))或[pd { C,N-Ch(c 5 H 8)chc 6 H 2 Ch 2 Ch 2 Nh 2-2,(ome)2-4,5}(μ-Br)] 2(2A3).配合物2A和芬特明同系物2B与co反应反应生成pd(0)和(1)四氢苯并甲酮,是由co插入pd-C键和c-N偶联产生的杂环;(2)非天然氨基酸衍生物,是由co插入和取决于起始环palpalated化合物的
DOI:10.1021/om300593X

专利信息

专利号:US-2017121258-A1
优先权日:2014-04-10
标题 :Synthesis of r-glucosides, sugar alcohols, reduced sugar alcohols, and furan derivatives of reduced sugar alcohols
发明人：SANBORN ALEXANDRA; BINDER THOMAS P
权利人:ARCHER DANIELS MIDLAND CO
摘要:Disclosed herein are methods for synthesizing 1,2,5,6-hexanetetrol (HTO), 1,6 hexanediol (HDO) and other reduced polyols from C5 and C6 sugar alcohols or R glycosides. The methods include contacting the sugar alcohol or R-glycoside with a copper catalyst, most desirably a Raney copper catalyst with hydrogen for a time, temperature and pressure sufficient to form reduced polyols having 2 to 3 fewer hydoxy groups than the starting material. When the starting compound is a C6 sugar alcohol such as sorbitol or R-glycoside of a C6 sugar such as methyl glucoside, the predominant product is HTO. The same catalyst can be used to further reduce the HTO to HDO.

专利号:US-2018258059-A1
优先权日:2014-04-10
标题:Synthesis of r-glucosides, sugar alcohols, reduced sugar alcohols, and furan derivatives of reduced sugar alcohols

专利号:US-2017029393-A1
优先权日:2014-04-10
标 题 :Synthesis of r-glucosides, sugar alcohols, reduced sugar alcohols, and furan derivatives of reduced sugar alcohols

专利号:US-2017044123-A1
优先权日:2014-04-10
标 题:Synthesis of r-glucosides, sugar alcohols, reduced sugar alcohols, and furan derivatives of reduced sugar alcohols

专利号:US-6939969-B2
优先权日:2001-04-02
标 题:Tri-and bidentate amido ligands prepared by palladium0 coupling and metallation thereof to form metal-amido catalysts
发明人：PETERS JONAS C; BROWN STEVEN D; HARKINS SETH B
权利人:CALIFORNIA INST OF TECHN
摘要:This invention provides an amido ligand and its synthesis. Use of the amide ligand in a variety of metal complexes, and transition metals in particular, is also provided.