CAS: 6372-40-3; Isopropyldiphenylphosphine

上下游产品

triphenylphosphine isopropyl bromide isopropyl-diphenyl-phosphine oxide 2-iodo-propane1-Isopropylphenylphosphino-2-diphenylphosphinoethan Diphenyl-isopropyl-methyl-phosphonium Ethyl-diphenyl-isopropyl-phosphonium Dichlor(isopropyl)diphenylphosphoran

异丙基二苯基氧膦置于aluminum (Iii) Chloride,四甲基乙二胺,四丁基氯化铵,Tert-Butylammonium Hexafluorophosphate(V)体系中,用 乙腈 作为反应溶剂,以33%的收率获得产物异丙基联苯膦
参考文献:三苯基氧化膦直接和可扩展的电还原为三苯基膦
标题:三苯基氧化膦直接和可扩展的电还原为三苯基膦
摘要:将氧化三苯膦 (Tppo)(一些最常见的合成有机反应的化学计量副产物)直接和可扩展地电还原为三苯膦 (Tpp) 仍然是一个未解决的挑战,它将显着降低与执行所需反应相关的成本和浪费由 Tpp 进行大规模调解.该报告详细介绍了使用铝阳极与支持电解质相结合的将 Tppo 单步还原为 Tpp 的电化学方法,该电解质可从阳极氧化产物中连续再生路易斯酸.产生的路易斯酸在温和的电位下激活 Tppo 进行还原,并促进 Po 通过 Pc 键断裂选择性地形成 Tpp,而不是其他副产物.最后,
DOI:10.1021/jacs.9B12112

专利信息

专利号:WO-2023276983-A1
优先权日:2021-06-28
标题 :Synthesis intermediate for beraprost or optically active form thereof, and method for producing same
发明人：AOYAGI SHIGENOBU; YAMADA RYO
权利人:OUCHI SHINKO CHEMICAL IND CO LTD
摘要:The present disclosure provides: a novel synthesis intermediate for beraprost or an optically active form thereof; and a production method using the synthesis intermediate. More specifically, in the present disclosure, a compound represented by general formula (I) or (II) or an optically active form thereof is used as a synthesis intermediate in the production of beraprost or an optically active form thereof.

专利号:US-9834536-B2
优先权日:2013-04-23
标题:Method for producing catalyst for cyclic carbonate synthesis
发明人：TAKAHASHI TOSHIKAZU; YASUDA HIROYUKI; SAKAKURA TOSHIYASU; YAMAMOTO SHOUJI; NANIKI TAKASHI; FURUKAWA TAKURO
权利人:AIST; MARUZEN PETROCHEM CO LTD
摘要:A method for producing a heterogeneous catalyst for use of synthesizing cyclic carbonates by reacting an epoxide and carbon dioxide in the presence of the catalyst. A method for making a catalyst that includes forming a catalyst precursor then reacting the catalyst precursor with a tertiary phosphine.

专利号:US-5237116-A
优先权日:1989-10-31
标题 :Catalyst and process for coupling organometallic reagents with aryl or vinylic halides
发明人：CORLEY LARRY S
权利人:SHELL OIL CO
摘要:A process and catalyst are disclosed for the catalyzed reaction of an organometallic reagent with a reactive halide in the presence of a diphosphine complex of a nickel carboxylate or sulfonate. The process can be employed in the synthesis of aromatic compounds such as bisbenzocyclobutenes.

专利号:US-10029241-B2
优先权日:2013-04-23
标题:Method for producing catalyst for cyclic carbonate synthesis
发明人：NANIKI TAKASHI; TAKAHASHI TOSHIKAZU; YASUDA HIROYUKI; YAMAMOTO SHOUJI
权利人:MARUZEN PETROCHEM CO LTD; AIST
摘要:A method for easily producing a heterogeneous catalyst having excellent catalytic activity at a low cost is provided. The heterogeneous catalyst is used for the purpose of synthesizing a cyclic carbonate by reacting an epoxide and carbon dioxide. A catalyst obtained by this production method and a method for synthesizing a cyclic carbonate with use of this catalyst are also provided.

专利号:WO-2013065066-A1
优先权日:2011-11-02
标 题 :Processes for preparing 4-oxo-4-[3-(trifluoromethyl)-5,6- dihydro [l,2,41-triazolo[43-a]pyrazin-7(8h)-yl]-l-(2,4,5- trifluorophenyl)butan-2-amine
发明人：PANDEY BIPIN; DAVE MAYANK GHANSHYAMBHAI; KOTHARI HIMANSHU M; SHUKLA BHAVIN SHRIPRASAD; MENDIRATTA SANJEEV KUMAR; JOSHI RUPAL; TRIVEDI UMANG
权利人:CADILA HEALTHCARE LTD; PANDEY BIPIN; DAVE MAYANK GHANSHYAMBHAI; KOTHARI HIMANSHU M; SHUKLA BHAVIN SHRIPRASAD; MENDIRATTA SANJEEV KUMAR; JOSHI RUPAL; TRIVEDI UMANG
摘要:The present invention relates to synthesis of 4-oxo-4-[3-(trifluoromethyl)-5,6- dihydro [l,2,4]-triazolo[4,3-a]pyrazin-7(8H)-yl]-l-(2,4,5-trifluorophenyl)butan-2- amine of Formula (I) either in its racemic (R/S) form or any of its optically active (S) or (R) forms or enantiomeric excess mixture of any of the forms by novel processes. The invention further relates to certain novel intermediates useful in the preparation of compound of Formula (I) and processes for their preparation.

专利号:US-5059572-A
优先权日:1989-10-31
标题 :Catalyst and process for coupling organometallic reagents with aryl or vinylic halides
发明人：CORLEY LARRY S
权利人:SHELL OIL CO
摘要:A process and catalyst are disclosed for the catalyzed reaction of an organometallic reagent with a reactive halide in the presence of a diphosphine complex of a nickel carboxylate or sulfonate. The process can be employed in the synthesis of aromatic compounds such as bisbenzocyclobutenes.