CAS: 4499-83-6; P-Sexiphenyl

该化合物是一种由6个联苯环组成,在准构件中相连的奥离子芳香烃,这种硬性线性结构具有高热稳定性和极佳的电子特性,使其成为有机电子和光电子中的宝贵材料,其扩展的 & conjuggation系统有利于高效的电荷运输,有利于应用诸如有机光排放二极管,现场效应晶体管和光伏装置等应用,此外,p-exibenne表现出强大的荧光性,可以作为研究大型聚苯乙烯系统的示范化合物,其明确界定的分子结构和合成再生性可进一步加强其在基础研究和先进材料开发中的效用.

结构式图片

上下游产品

biphenyl [1,1';4',1'']terphenyl 4-bromo-p-terphenyl 4-iodo-biphenyl

合成工艺路线路线简述

    📜4-溴对三联苯置于2,2'-联吡啶,Bis(1,5-Cyclooctadiene)Nickel (0),1,5-Cis,Cis-Cyclooctadiene体系中,用 N,N-二甲基甲酰胺 作为反应溶剂,化学反应 40.0H,以34%的收率获得产物对六联苯
    参考文献:Easy Synthesis Of Phenyl Oligomers Using A Ni Complex
    标题:Easy Synthesis Of Phenyl Oligomers Using A Ni Complex
    摘要:本文介绍了以 4-溴对三联苯和 4-溴对四联苯为起始原料,使用镍络合物,在双吡啶存在下,以 Dmf 作为反应溶剂,分别合成对六联苯和对八联苯的过程.结果表明,这种合成方法不仅提高了产率,而且易于制备和纯化这些亚苯基低聚物.
    DOI:10.1039/b400236A

    海关参考信息

    专利信息


    专利号:US-2025009786-A1
    优先权日:2021-09-30
    标 题 :Automated synthesis of polymeric dual drugs
    发明人:MATRAY TRACY; VANBRUNT MICHAEL; MCCUTCHEON JOHN MICHAEL
    权利人:SONY GROUP CORP
    摘要:Compounds useful as biologically active compounds with or without fluorescent or colored dyes are disclosed. In some embodiments, the compounds have the following structure (I): (I) or a stereoisomer, tautomer or salt thereof, wherein R1, R2, R3, R4, R5, R6, R7, L1, L2, L3, L4, L5, L6, L7, L8, L9, L10, L11, M1, M2, M3, l, m, n, p, and q are as defined herein. Additional compound, methods of preparation, pharmaceutical compositions, and methods of treatment related to compounds of Structure (I) are also provided.

    专利号:WO-2023052971-A1
    优先权日:2021-09-30
    标题 :Automated synthesis of polymeric dual drugs

    专利号:EP-4408473-A1
    优先权日:2021-09-30
    标 题:Automated synthesis of polymeric dual drugs

    专利号:CN-118159296-A
    优先权日:2021-09-30
    标题:Automated Synthesis of Polymeric Double Drugs

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题:Iodine-Promoted Metal-Free Aromatization: Synthesis Of Biaryls, OligoP-Phenylenes And A-Ring Modified Steroids
    作者:Victoriano Domingo,Consuelo Prieto,Alexis Castillo,Lucia Silva,José F. Quílez Del Moral,Alejandro F. Barrero |发布日期:2015.10.12
    摘要:Efficient Procedures Based On The Use Of Iodine For The Synthesis Of Biaryls From Arylcyclohexenols Or Arylcyclohexanols Using Sub-Stoichiometric/catalytic Iodine And Dimethyl Sulfoxide (Dmso) As Oxidant. Heteroarylcyclohexanols Also Produced The Corresponding Biaryl Products. It Was Proven That Biphenyl Can Also Be Efficiently Obtained When The Quantity Of Iodine Was Reduced To 0.05 Equiv. The Method

    合成参考文献

    合成方法参考DOI号:10.1002/adsc.201500303
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