CAS: 68418-51-9; 1,4-Phenylenebis((4-Fluorophenyl)Methanone)

该化合物其结构特征为其结构特征,其中间苯基组由两个1-(4)氟苯-甲基苯胺基聚苯乙烯基元素组成,其侧侧侧面为两个1-(4-氟苯基)聚苯乙烯基聚苯乙烯基,该化合物具有典型的氯酮特性,包括碳基功能组,有助于其在有机合成中产生反应和潜在应用;氟原子的存在增强了其电子特性,有可能增加其与生物系统的互动性;该化合物在有机溶剂中可能表现出极大的热稳定性和溶性,使其适合于材料科学和药物的各种应用;该化合物的独特结构还可能具有特定的光学或电子特性,可以在诸如有机发光二极管(OLEDDs)或作为合成较复杂的分子的中间体等先进应用中加以探讨.

结构式图片

欧盟法规

REACH注册ECHA物质C&L通报

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CAS号437-29-6 (p-fluorophenyl)3Bi | CAS号100-20-9 对苯二甲酰氯 | CAS号462-06-6 氟苯

合成工艺路线路线简述

    1,4-二(4-氯苯甲酰基)苯 反应生成 1,4-双(4-氟苯甲酰基)苯
    参考文献:
    标题:

    海关参考信息

    专利信息


    专利号:US-11008273-B2
    优先权日:2019-02-15
    标题 :Process for the manufacture of fluorinated benzenes and fluorinated benzophenones, and derivatives thereof
    发明人:ZHOU CHANGYUE; DU HONGJUN; WU WENTING
    权利人:FUJIAN YONGJING TECH CO LTD
    摘要:The invention relates to a new process for the manufacture or synthesis, respectively, of fluorinated benzenes and fluorinated benzophenones, and derivatives thereof, in particular of fluorobenzenes and derivatives thereof. The present invention particularly pertains to a novel environmentally friendly process for the synthesis of fluorinated benzenes and benzophenones as raw materials for the manufacture of polyaryletherketones (PAEKs).

    专利号:US-9803050-B2
    优先权日:2014-10-08
    标 题:Dispersant for use in synthesis of polyaryletherketones
    发明人:NAIR KAMLESH P
    权利人:TICONA LLC
    摘要:A method for forming a polyaryletherketone is described. More particularly, a reaction mixture is initially supplied to the reactor vessel that contains one or more precursor monomers. A heteroaryl compound is also added to the reaction mixture. The reaction can be carried out according to, e.g., an electrophilic aromatic substitution reaction or a nucleophilic aromatic substitution reaction. The heteroaryl compound can serve as a dispersant to the polymer as it is formed. This minimizes the likelihood of gelling of the product polymer within the reactor vessel and limits the impact of process disruptions on the production of the polyaryletherketone.

    专利号:US-11732090-B2
    优先权日:2016-12-21
    标 题:Poly(ether ketone ketone) polymers, corresponding synthesis methods and polymer compositions and articles made therefrom
    发明人:LOUIS CHANTAL
    权利人:SOLVAY SPECIALTY POLYMERS USA
    摘要:Described herein are PEKK polymers having improved processability and improved crystallinity. It was surprisingly found that PEKK polymers formed using a specifically adapted nucleophilic synthesis route, in which different monomers are added in to the polymerization reaction at different points during the synthesis, had lower glass transition temperatures (“Tgâ€?) and increased crystallinities, relative to PEKK polymers formed using traditional nucleophilic synthesis routes (“traditional PEKK polymersâ€?). Furthermore, compared with PEKK polymers synthesized using an electrophilic synthesis routes, the PEKK polymers described herein and significantly lower halogen content. The synthesis routes includes a first heating of a first monomer blend in a reaction mixture, a subsequent first addition of a second monomer blend to the reaction mixture, and a second heating of the reaction mixture subsequent to the first addition.

    专利号:WO-2018115033-A1
    优先权日:2016-12-21
    标题:Poly(ether ketone ketone) polymers, corresponding synthesis methods and polymer compositions and articles made therefrom
    发明人:LOUIS CHANTAL
    权利人:SOLVAY SPECIALTY POLYMERS USA
    摘要:Described herein are PEKK polymers having improved processability and improved crystallinity. It was surprisingly found that PEKK polymers formed using a specifically adapted nucleophilic synthesis route, in which different monomers are added to the polymerization reaction at different points during the synthesis, had lower glass transition temperatures ('Tg') and increased crystallinities, relative to PEKK polymers formed using traditional nucleophilic synthesis routes ('traditional PEKK polymers'). Furthermore, compared with PEKK polymers synthesized using an electrophilic synthesis routes, the PEKK polymers described herein and significantly lower halogen content. The synthesis routes includes a first heating of a first monomer blend in a reaction mixture, a subsequent first addition of a second monomer blend to the reaction mixture, and a second heating of the reaction mixture subsequent to the first addition.

    专利号:US-12202940-B2
    优先权日:2016-12-21
    标题:Poly (ether ketone ketone) polymers, corresponding synthesis methods and polymer compositions and articles made therefrom
    发明人:LOUIS CHANTAL
    权利人:SOLVAY SPECIALTY POLYMERS USA
    摘要:Described herein are poly(ether ketone ketone) (“PEKKâ€?) polymers having improved processability. It was surprisingly discovered that by selectively controlling the relative amounts of reactants during the synthesis, PEKK polymers having unexpectedly lower melt viscosities can be obtained. More particularly, by selectively controlling the relative amounts of monomers used to form recurring units of the PEKK polymer, in conjunction with selective control of other reaction components, the resulting PEKK polymers had reduced viscosities, relative to PEKK polymers synthesized by using tradition reaction schemes (“traditional PEKK polymersâ€?). By providing PEKK polymers with lower melt viscosities, the PEKK polymers described herein have improved processability.

    专利号:WO-2018115035-A1
    优先权日:2016-12-21
    标 题 :Poly(ether ketone ketone) polymers, corresponding synthesis methods and polymer compositions and articles made therefrom
    发明人:LOUIS CHANTAL
    权利人:SOLVAY SPECIALTY POLYMERS USA; SOLVAY
    摘要:Described herein are poly(ether ketone ketone) ('PEKK') polymers having improved processability. It was surprisingly discovered that by selectively controlling the relative amounts of reactants during the synthesis, PEKK polymers having unexpectedly lower melt viscosities can be obtained. More particularly, by selectively controlling the relative amounts of monomers used to form recurring units of the PEKK polymer, in conjunction with selective control of other reaction components, the resulting PEKK polymers had reduced viscosities, relative to PEKK polymers synthesized by using tradition reaction schemes ('traditional PEKK polymers'). By providing PEKK polymers with lower melt viscosities, the PEKK polymers described herein have improved processability.
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    主要参考文献

    参考标题:A Phosphine-Free, Heterogeneous Palladium-Catalyzed Atom-Efficient Carbonylative Cross-Coupling Of Triorganoindiums With Aryl Halides Leading To Unsymmetrical Ketones
    作者:Shengyong You,Ruian Xiao,Haiyi Liu,Mingzhong Cai
    摘要:The First Phosphine-Free Heterogeneous Palladium-Catalyzed Carbonylative Cross-Coupling Of Aryl Halides With Triorganoindiums Has Been Developed That Proceeds Smoothly Under 1 Or 2.5 Atm Of Carbon Monoxide In Thf At 68 °C And Provides A General And Powerful Tool For The Synthesis Of Various Valuable Unsymmetrical Ketones With High Atom-Economy, Good Yield, And Recyclability Of The Catalyst. Our System

    合成参考文献


    参考文献:10.1007/978-3-642-39429-4_10
    摘要:Kricheldorf H. Hyperbranched Polymers by a2 + bn Polycondensation. 2013 Nov 15. In: Polycondensation.
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